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  • 1
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract The iron-bearing phases in nodules from two regions (the Pacific Ocean — Clarion-Clipperton, and the Indian Ocean — Central plain) have been studied by Mössbauer Spectroscopy. The major compounds are established to be Fe(OH)3, (FeOOH·H2O) and FeCO3. The value of the recoilless absorption probability f′ is measured for Fe(OH)3. Meisel's method for quantitative determination of iron containing compounds has been adapted for the case of nodule samples. By taking into account the f′ values, the error of quantitative determination is considerably reduced. The Fe2+ distribution in the nonequivalent M1 and M2 positions of pyroxene has been studied. It is shown that the pyroxene crystals in the silicate material originated as a result of rapid cooling of the magma in ocean water.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6036
    Keywords: PACS. 63.20.Dj Phonon states and bands, normal modes, and phonon dispersion - 76.80.+y Mössbauer effect; other -ray spectroscopy - 39.30.+w Spectroscopic techniques
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: Mössbauer studies were performed on single crystals of guanidinium nitroprusside with different orientations of their principal crystallographic axes (a, b, c) with respect to the incident radiation. The markedly anisotropic Lamb-Mössbauer factor f LM , i.e. f LM (a) = 0.118(8), f LM (b) = 0.174(8), f LM (c) = 0.202(8) is in contrast to that of nitroprussides with inorganic anions. The observed anisotropy is ascribed to the anisotropic vibrational mean-square displacement of the nitroprusside anions as a whole which is due to the specific packing of both, anions and cations, as well as the very weak chemical bonding between the ions, typical only for guanidinium nitroprusside. The vibrational anisotropy of iron atoms in barium nitroprusside that has been observed by X-ray structural investigations has a different origin and therefore does not result in an anisotropic Lamb-Mössbauer factor. We have also investigated metastable states in guanidinium nitroprusside that have been populated by means of incoherent irradiation from light-emitting diodes. With a specific orientation of the guanidinium nitroprusside single crystal a population of the metastable states up to 26% could be achieved. Populations of comparable size on lithium, sodium and potassium nitroprussides have only been reached using coherent laser irradiation.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 80 (1993), S. 170-172 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied mechanics and technical physics 12 (1971), S. 42-49 
    ISSN: 1573-8620
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Experiments are described on the collisionless propagation of heat in a plasma along the magnetic field. Thermal waves can be propagated in a medium whose thermal conductivity is a power function of the temperature. In a collisionless plasma, where the mean free path of particles is much greater than all typical lengths, in particular the length of the equipment, the heat must be propagated by a different method. Experiments to study this phenomenon showed that heat is propagated along the magnetic field with velocity exceeding that of ion-acoustic velocity (I. A. Velocity), and that the spatial width of the thermal disturbance is much less than the mean free path. Heat is propagated because hot electrons are replaced by cold [1]. Noise was observed experimentally in the vicinity of the ion plasma frequency and an estimate of its intensity was obtained. Theoretical discussion showed that the I. A. Velocity instability which develops at the wave front leads to collective friction of the cold electrons with the ions and makes it possible to find the effective collision frequency. It was also shown theoretically that, in accordance with experiment, noise is localized near ωpi, and the level agrees with that obtained experimentally. The phenomenon can be pictured as follows: hot electrons expanding into the region occupied by cold electrons and ions create an electric field. Cold electrons, accelerating in this field, oscillate the I. A. Velocity. This instability leads to heating of the electrons and the appearance of collective friction which forms the heat front.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied mechanics and technical physics 25 (1984), S. 878-880 
    ISSN: 1573-8620
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The vibrational relaxation of a nonequilibrium molecular gas (TV〉T) plays an important role in the physics of gas lasers, laser chemistry [1], and plasma chemistry [2]. This paper is devoted to an analysis of the dynamics of V-T relaxation with spatially inhomogeneous perturbations of the translational temperature taken into account.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Atomic energy 81 (1996), S. 559-565 
    ISSN: 1573-8205
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 137 (1989), S. 397-404 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Mössbauer analysis of rust samples obtained in the presence and absence of a magnetic field shows that there is a difference in the qualitative and quantitative composition of the corrosion products. The effect of magnetic field depends on the orientation of the coupons in the magnetic field and its intensity.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 128 (1988), S. 207-213 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Wellhead equipment corrosion samples including internal surface of choke were analyzed by means of Mössbauer spectroscopy and X-ray diffractometry. The samples include some impurities of quartz, dolomite and calcite. The resulted analysis shows some iron oxides and oxyhydroxides as surface equipment corrosion products.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 6 (1986), S. 97-107 
    ISSN: 1572-8986
    Keywords: Rotating plasma ; plasma centrifuge ; isotope separation ; hydrogen ; water dissociation ; quenching ; plasma-chemical reactor simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Investigations on separating hydrogen isotopes have been carried out in a system with plasma rotating in crossed E × B fields— a plasma centrifuge. The processing of chemical reactions in the plasma phase in a strong centrifugal field was simulated. High radial separation factors (up to 140) have been obtained for the decomposition of water vapor with simultaneous separation of hydrogen and oxygen. Because of spatial separation of the dissociation products there was no need for their special quenching.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The recoilless absorption probability factor,f′, and recoilless reemission,f″, both measured on Na2[Fe(CN)5NO]·2 H2O single crystals using the “black” filter technique, were found to be different. Unexpectedly, the results found weref″〉f′. In the calculation off″, selfabsorption in the scatterer, non-ideality of the “black” filter and the influence of non-resonant scattering processes have all been taken into account. By varying the scattering geometry for the incoming and outgoing γ-beam relative to the crystallographic axes only a change in the reemitted valuesf″ a, f″b, f″c could be detected because of the long lifetime of the excited nucleus (∼10−7 s) relative to the lattice vibration frequencies (∼1012 Hz).
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