In:
Journal of Chemical Research, SAGE Publications, Vol. 41, No. 6 ( 2017-06), p. 315-320
Abstract:
A highly efficient heterogeneous copper-catalysed cascade reaction of aryl iodides with acetamidine hydrochloride was achieved in DMF in the presence of 10 mol% of an MCM-41-immobilised L-proline-copper(I) complex (MCM-41-L-proline-CuI) with Cs 2 CO 3 as base, yielding a variety of primary arylamines in good to excellent yields. The new heterogeneous copper complex can be easily prepared from commercially readily available and inexpensive reagents, recovered by a simple filtration of the reaction solution and used at least seven more times without any decrease in activity.
Type of Medium:
Online Resource
ISSN:
1747-5198
,
2047-6507
DOI:
10.3184/174751917X14931195075580
Language:
English
Publisher:
SAGE Publications
Publication Date:
2017
detail.hit.zdb_id:
3010810-X
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