In:
Green Chemistry, Royal Society of Chemistry (RSC), Vol. 24, No. 19 ( 2022), p. 7368-7375
Abstract:
A novel nickel( i ) complex (di(2,2′-(1-phenyl-1 H -1,2,4-triazole-3,5-diyl)dipyridine))(dibromine) nickel( i )bromide ([Ni-N4]Br) exhibited extremely high efficiency toward the (de)hydrogenative alkylation of amines and alkyl heteroarenes by alcohols. The catalytic performance can be attributed to the functionalized nitrogen ligand, which adopts a cationic coordination mode and the facile dissociation of coordinated water. This sustainable transformation is applicable to various alcohols, featuring good functional group tolerance with high selectivity under solvent free conditions. The synthetic strategy provides a green and efficient method for the construction of functionalized amines and unsaturated N-heteroaromatic derivatives.
Type of Medium:
Online Resource
ISSN:
1463-9262
,
1463-9270
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1485110-6
detail.hit.zdb_id:
2006274-6
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