In:
Energy & Environmental Science, Royal Society of Chemistry (RSC), Vol. 16, No. 6 ( 2023), p. 2483-2493
Abstract:
The electrocatalytic nitrate reduction reaction (NtrRR) has recently become an emerging technology that can convert nitrate pollutants into high-value added ammonia products in a mild manner. However, it is highly challenging to develop NtrRR electrocatalysts with high activity, selectivity, and stability given the sluggish kinetics and diverse pathways of the NtrRR. Herein, we develop a Ru/β-Co(OH) 2 heterostructure catalyst derived from in situ reconstruction of Ru-doped Co metal nanosheets with an ultralow Ru/Co ratio of 3.08 at%. The synergy and strong interactions between interfacial Ru and Co sites weaken the d–p orbital hybridization ability with *NH 3 intermediates, which thus lowers the barrier of the potential determining step. As a result, the catalyst delivers an industrial-level current density of −500 mA cm −2 at a positive potential of only 0.01 V vs. the reversible hydrogen electrode, along with a high ammonia Faradaic efficiency of 98.78%. Meanwhile, it can purify the nitrate sewage and reduce the nitrate concentration to 13–31 ppm. Furthermore, the assembled Zn-nitrate flow battery also delivers a decent power density of 29.87 mW cm −2 and a high ammonia yield of up to 0.38 mmol h −1 cm −2 with excellent stability. This work suggests an effective strategy for designing high-performance electrocatalysts through interface engineering by rational reconstruction.
Type of Medium:
Online Resource
ISSN:
1754-5692
,
1754-5706
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
2439879-2
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