In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 57, No. 79 ( 2021), p. 10250-10253
Abstract:
The first example of Rh-substituted organic–inorganic hybrid arsenotungstate [H 2 N(CH 3 ) 2 ] 8 {[Na(H 2 O) 4 ]NaAs 2 W 22 (CH 3 COO) 2 O 76 Rh 2 (N(CH 3 ) 2 ) 2 }·H 2 O (1) synthesised in an aqueous solution by the conventional method is reported. Two [Rh(N(CH 3 ) 2 )] 3+ fragments are imbedded into the vacancy of the [NaAs 2 W 22 (CH 3 COO) 2 O 76 ] 15− unit by Rh–As bonds [2.439(1) Å], which are observed in POM chemistry for the first time.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
1472881-3
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