In:
CrystEngComm, Royal Society of Chemistry (RSC), Vol. 24, No. 38 ( 2022), p. 6628-6641
Abstract:
In this work, we present eight oxamato complexes of formula ( n -Bu 4 N)[M(HL) 4 (DMSO)]· n H 2 O (M = Y 3+ , La 3+ , Nd 3+ , Ho 3+ ) with either _HClppa (= N -(4-chlorophenyl)oxamic acid) or _HFppba (= N -(4-fluorophenyl)oxamic acid) as the HL ligands, n = 2 (_HFppa) or 3 (_HClppa), besides the coordinated dimethylsulfoxide (DMSO) molecule, and tetrabutylammonium ( n -Bu 4 N + ) as counterions. All compounds were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The analysis shows that all mononuclear compounds, with two oxygen atoms from each oxamic acid ligand and a DMSO molecule coordinated to the metal ion, result in a MO 9 sphere of coordination. The dc magnetic properties of complexes Nd_HClppa, Nd_HFppa, Ho_HClppa, and Ho_HFppa reveal their paramagnetism. The ac magnetic measurements indicate the existence of slow relaxation of the magnetization for Ho 3+ and Nd 3+ compounds at low temperatures, suggesting that Ho 3+ complexes are single-ion magnets (SIMs) while Nd 3+ compounds are field-induced SIMs. Ab initio calculations were performed to determine the crystal-field parameters, which were subsequently used to obtain the best-fit curves of dc magnetic data and simulate susceptibility curves. The latter was consistent with experimental results for each compound, although small differences between compounds with the same lanthanide were not reproduced when all compounds were considered.
Type of Medium:
Online Resource
ISSN:
1466-8033
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2025075-7
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