In:
Environmental Science: Water Research & Technology, Royal Society of Chemistry (RSC), Vol. 8, No. 7 ( 2022), p. 1444-1457
Abstract:
Mineral fouling is a major hindrance to high recovery effluent nanofiltration, with calcium phosphate (Ca-P) and calcium carbonate (CaCO 3 ) the most prevalent mineral foulants. In this study, we used a novel combination of real-time in-line microscopy, electrical impedance spectroscopy (EIS), post SEM analysis, and filtration metrics (water flux and rejection) to study mineral fouling mechanisms of Ca-P and CaCO 3 salts in synthetic effluent nanofiltration. We used nanofiltration (NF) polyelectrolyte multilayer (PEM) membranes, prepared by static layer-by-layer (LbL) coating of a cationic polymer – polydiallyl dimethylammonium chloride, and anionic polymer – poly styrenesulfonate (six bi-layer) on a polyethersulfone (PES) ultrafiltration (UF) membrane. Increasing permeate recovery over filtration time was simulated by adding CaCl 2 with NaHCO 3 or NaH 2 PO 4 /Na 2 HPO 4 . Using the novel combination of methods, we delineated the mechanisms governing fouling development with time for both CaCO 3 and Ca-P. For CaCO 3 , a transition from heterogeneous precipitation on the membrane surface (scaling) to particulate fouling due to bulk precipitation was identified. For Ca-P, a transition from fouling by amorphous particles to fouling by crystalline particles was identified; and this phase-change was captured in real-time images using an in-line microscope. We also found that for similar precipitation potentials measured by weight, Ca-P fouling was more detrimental to water flux (86% decrease) compared to CaCO 3 (20% decrease) due to the voluminous amorphous phase. We established in-line microscopy as a new useful method to study mineral fouling, as it gives invaluable information on the suspended particles in real-time. Combining it with EIS gives complementary information on mineral accumulation on the membrane surface. Insight from this study and further use of these methods can guide future strategies towards higher effluent recovery by membrane filtration.
Type of Medium:
Online Resource
ISSN:
2053-1400
,
2053-1419
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
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