In:
Chemical Science, Royal Society of Chemistry (RSC), Vol. 13, No. 25 ( 2022), p. 7604-7609
Abstract:
A copper-catalyzed three-component carboboration of acetylene with B 2 Pin 2 and Michael acceptors is reported. In this reaction, a cheap and abundant C2 chemical feedstock, acetylene, was used as a starting material to afford cis -alkenyl boronates bearing a homoallylic carbonyl group. The reaction was robust and could be reliably performed on the molar scale. Furthermore, the resulting cis -alkenyl boronates could be converted to diverse functionalized molecules with ease.
Type of Medium:
Online Resource
ISSN:
2041-6520
,
2041-6539
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2559110-1
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