Description: Fluxes of lithogenic material and fluxes of three palaeo-productivity proxies (organic carbon, biogenic opal and alkenones) over the past 100 000 years were determined using the 230Th-normalization method in three sediment cores from the Subantarctic South Atlantic Ocean. Features in the lithogenic flux record of each core correspond to similar features in the record of dust deposition in the EPICA Dome C ice core. Biogenic fluxes correlate with lithogenic fluxes in each sediment core. Our preferred interpretation is that South American dust, most probably from Patagonia, constitutes a major source of lithogenic material in Subantarctic South Atlantic sediments, and that past biological productivity in this region responded to variability in the supply of dust, probably due to biologically available iron carried by the dust. Greater nutrient supply as well as greater nutrient utilization (stimulated by dust) contributed to Subantarctic productivity during cold periods, in contrast to the region south of the Antarctic Polar Front (APF), where reduced nutrient supply during cold periods was the principal factor limiting productivity. The anti-phased patterns of productivity on opposite sides of the APF point to shifts in the physical supply of nutrients and to dust as cofactors regulating productivity in the Southern Ocean.

Description: Sedimentary proxies used to reconstructmarine productivity suffer fromvariable preservation and are sensitive to factors other than productivity. Therefore, proxy calibration is warranted. Here we map the spatial patterns of two paleoproductivity proxies, biogenic opal and barium fluxes, from a set of core-top sediments recovered in the Subarctic North Pacific. Comparisons of the proxy data with independent estimates of primary and export production, surface water macronutrient concentrations, and biological pCO2 drawdown indicate that neither proxy shows a significant correlation with primary or export productivity for the entire region. Biogenic opal fluxes, when corrected for preservation using 230Th-normalized accumulation rates, show a good correlation with primary productivity along the volcanic arcs (τ =0.71, p = 0.0024) and with export productivity throughout the western Subarctic North Pacific (τ = 0.71, p = 0.0107). Moderate and good correlations of biogenic barium flux with export production (τ = 0.57, p = 0.0022) and with surface water silicate concentrations (τ =0.70, p = 0.0002) are observed for the central and eastern Subarctic North Pacific. For reasons unknown, however, no correlation is found in the western Subarctic North Pacific between biogenic barium flux and the reference data. Nonetheless, we show that barite saturation, uncertainty in the lithogenic barium corrections, and problems with the reference data sets are not responsible for the lack of a significant correlation between biogenic barium flux and the reference data. Further studies evaluating the factors controlling the variability of the biogenic constituents in the sediments are desirable in this region.

Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25‐50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s‐1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.