In:
Revista de Chimie, Revista de Chimie SRL, Vol. 70, No. 11 ( 2019-12-15), p. 3893-3898
Abstract:
In this paper we report the preparation of two (h3-allyl)carbonylnitrosyltriphenylphosphine iron complexes i.e.(p-allyl)carbonylnitrosyltriphenylphosphine iron (1) and (2-methyl-p-allyl) carbonylnit rosyltriphenylphosphine iron (2). These complexes (1) and (2) were prepared by reacting (p-allyl)dicarbonylnitrosyl iron and (2-methyl-p-allyl)dicarbonylnitrosyl iron with triphenylphosphine under inert atmospheric conditions. Both the resulting complexes were sufficiently and well characterized by IR, 1H NMR, 13C NMR, ESI/MS, HRMS and single crystal XRD. Triphenylphosphine ligand was found to be strong sigma donor and replaced carbonyl ligand readily. XRD revealed that the geometry of iron in both complexes is distorted octahedral.
Type of Medium:
Online Resource
ISSN:
0034-7752
,
2668-8212
DOI:
10.37358/RC.19.11.7666
Language:
English
Publisher:
Revista de Chimie SRL
Publication Date:
2019
detail.hit.zdb_id:
2488208-2
Permalink