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  • 1
    Online Resource
    Online Resource
    Singapore :Springer Singapore Pte. Limited,
    Keywords: Botanical chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (318 pages)
    Edition: 1st ed.
    ISBN: 9789811566073
    Series Statement: Environmental and Microbial Biotechnology Series
    DDC: 579
    Language: English
    Note: Intro -- Preface -- Contents -- 1: Application of Microbial Biosurfactants in the Food Industry -- 1.1 Surfactants in the Food Industry -- 1.1.1 Food Additives -- 1.1.2 Biosurfactants as Food Preservatives -- 1.1.2.1 Emulsifying Agents -- 1.1.2.2 Antibiofilm Agents -- 1.1.2.3 Antimicrobial Agents -- 1.1.2.4 Antioxidant Agents -- 1.1.3 Industrial Prospects -- References -- 2: Microbial Biosurfactants for Contamination of Food Processing -- 2.1 Introduction -- 2.1.1 Food Contamination -- 2.1.2 Contamination in Food Processing -- 2.2 Microbial Biosurfactants Use in Food Processing -- 2.2.1 Glycolipids -- 2.2.2 Lipopeptides -- 2.3 Application of Microbial Surfactants in Food Processing -- 2.3.1 Biofilm Control -- 2.3.2 Food Preservatives -- 2.4 Concluding Remarks -- References -- 3: Antioxidant Biosurfactants -- 3.1 Introduction -- 3.2 Sources of Biosurfactants -- 3.2.1 Plant-Based Biosurfactants -- 3.2.1.1 Saponins -- Structure, Properties, and Types of Saponins -- Saponins as a Biosurfactants -- 3.2.2 Microbe-Based Biosurfactants -- 3.2.2.1 Types of Microbial Surfactants -- Glycolipids -- Rhamnolipids -- Sophorolipids -- Trehalolipids -- Succinoyl Trehalolipids -- Cellobiose Lipids -- Mannosylerythritol Lipids -- Xylolipids -- Mannose Lipids -- Lipopeptides or Lipoprotein -- Bacillus-Related Lipopeptides -- Surfactin -- Fengycin -- Iturin -- Kurstakins -- Lichenysins -- Pseudomonas-Related Lipopeptides -- Actinomycetes-Related lipopeptides -- Fungal-Related Lipopeptides -- Phospholipids, Fatty Acids (Mycolic Acids), and Neutral Lipids -- Polymeric Surfactants -- Particulate Surfactants -- 3.3 Factors Affecting Biosurfactant Production -- 3.3.1 pH and Temperature -- 3.3.2 Aeration and Agitation -- 3.3.3 Effect of Salt Salinity -- 3.3.4 Optimization of Cultivation Medium -- 3.3.4.1 Effect of Carbon Source -- 3.3.4.2 Effect of Nitrogen Source. , 3.3.4.3 Effect of Carbon to Nitrogen (C/N) Ratio -- 3.4 Screening of Microorganisms for Biosurfactant Production -- 3.4.1 Oil Spreading Assay -- 3.4.2 Drop Collapse Assay -- 3.4.3 Blood Agar Method/Hemolysis Assay -- 3.4.4 Hydrocarbon Overlay Agar -- 3.4.5 Bacterial Adhesion to Hydrocarbon (BATH) Assay -- 3.4.6 CTAB Agar Plate Method/Blue Agar Assay -- 3.4.7 Phenol: Sulfuric Acid Method -- 3.4.8 Microplate Assay -- 3.4.9 Penetration Assay -- 3.4.10 Surface/Interface Activity -- 3.4.11 Emulsification Activity -- 3.5 Antioxidant Properties of Biosurfactant -- 3.6 Conclusion -- References -- 4: Classification and Production of Microbial Surfactants -- 4.1 Introduction -- 4.1.1 Global Biosurfactant Market -- 4.2 Types of Biosurfactants -- 4.2.1 Glycolipids -- 4.2.1.1 Rhamnolipids -- 4.2.1.2 Sophorolipids -- 4.2.1.3 Trehalolipids -- 4.2.2 Lipoproteins and Lipopeptides -- 4.2.3 Fatty Acids -- 4.2.4 Phospholipids -- 4.2.5 Polymeric Biosurfactants -- 4.3 Factors Influencing Biosurfactant Productivity -- 4.3.1 Nutritional Factors -- 4.3.1.1 Carbon Source -- 4.3.1.2 Low-Cost and Waste Substrates -- 4.3.1.3 Nitrogen Source -- 4.3.1.4 Minerals -- 4.3.2 Environmental Factors -- 4.3.3 Cultivation Strategy -- 4.3.3.1 Solid-State Fermentation (SSF) -- 4.3.3.2 Submerged Fermentations (SmF) -- References -- 5: Microbial Biosurfactants and Their Potential Applications: An Overview -- 5.1 Introduction -- 5.2 Classes of Biosurfactants -- 5.2.1 Glycolipids -- 5.2.2 Lipopolysaccharides -- 5.2.3 Lipopeptides and Lipoproteins -- 5.2.4 Phospholipids -- 5.2.5 Fatty Acids -- 5.3 Microbial Production of Biosurfactants -- 5.4 Genes Involved in the Production of Microbial Biosurfactants -- 5.5 Applications -- 5.5.1 In Petroleum Industry -- 5.5.1.1 Mechanism of MEOR -- 5.5.2 Biosurfactant-Mediated Bioremediation -- 5.5.3 In Food Industry -- 5.5.4 In Agriculture. , 5.5.5 In Cosmetics -- 5.5.6 Biosurfactant in Nanotechnology -- 5.5.7 Biosurfactants as Drug Delivery Agents -- 5.5.8 Antimicrobial Activity of Biosurfactants -- 5.5.9 Biosurfactant as Anti-Adhesive Agent -- 5.5.10 In Fabric Washing -- 5.6 Conclusions -- References -- 6: Biodegradation of Hydrophobic Polycyclic Aromatic Hydrocarbons -- 6.1 Introduction -- 6.2 Health Related to PAHs -- 6.2.1 Consequences of Consistent of PAH Exposure by Human -- 6.2.2 Problems Associated with PAHs Via Cytochrome P450 -- 6.3 Biodegradation of PAHs -- 6.3.1 Challenges of Limited Aqueous Solubility in Water -- 6.3.2 Biodegradation Pathway of PAHs -- 6.3.2.1 Naphthalene -- 6.3.2.2 Pyrene -- 6.3.2.3 Fluoranthene -- 6.4 Biosurfactants -- 6.4.1 Biosurfactants -- 6.4.1.1 Glycolipid -- Rhamnolipids -- Cellobiose Lipids -- Sophorolipids -- Trehalolipids -- Mannosylerythritol Lipid -- 6.4.1.2 Lipopeptides -- 6.4.1.3 Phospholipids -- 6.4.2 Polymeric Biosurfactants -- 6.5 Enhanced Biodegradation of PAHs by Biosurfactant -- 6.5.1 Biodegradation in Micelles -- 6.5.2 Biosurfactant Acting as Bioemulsifier -- 6.6 Conclusions -- References -- 7: Surfactin: A Biosurfactant Against Breast Cancer -- 7.1 Introduction -- 7.2 Biosurfactants and Its Types -- 7.2.1 Glycolipids -- 7.2.1.1 Rhamnolipids -- 7.2.1.2 Sophorolipids -- 7.2.1.3 Trehalolipids -- 7.2.2 Lipopeptides -- 7.2.3 Fatty Acids -- 7.2.4 Phospholipids -- 7.2.5 Polymeric Biosurfactant -- 7.3 Surfactin: Structure, Membrane Interaction, Biosynthesis, and Regulation -- 7.3.1 Structure -- 7.3.2 Membrane Interaction -- 7.3.3 Biosynthesis -- 7.3.4 Regulation -- 7.4 Surfactin and Breast Cancer -- 7.5 Conclusion -- References -- 8: Anti-Cancer Biosurfactants -- 8.1 Introduction -- 8.2 Biosurfactants Classification and Structure -- 8.2.1 Mannosylerythritol Lipids (MELs) -- 8.2.2 Succinoyl Trehalose Lipids (STLs) -- 8.2.3 Sophorolipids. , 8.2.4 Rhamnolipids (RLs) -- 8.2.5 Myrmekiosides -- 8.2.6 Cyclic Lipopeptides (CLPs) -- 8.2.6.1 Amphisin, Tolaasin, and Syringomycin CLPs -- 8.2.6.2 Iturin and fengycin CLPs -- 8.2.6.3 Surfactin CLP -- 8.2.7 Rakicidns and Apratoxins -- 8.2.8 Serrawettins -- 8.2.9 Monoolein -- 8.2.10 Fellutamides -- 8.3 Biosurfactants Production -- 8.3.1 Factors Involved in Biosurfactants Production -- 8.3.1.1 Source of Carbon -- 8.3.1.2 Source of Nitrogen -- 8.3.1.3 Effect of Ions -- 8.3.1.4 Physical Factors -- 8.4 Anti-Cancer Activity of Biosurfactants -- 8.4.1 Breast Cancer -- 8.4.2 Lung Cancer -- 8.4.3 Leukemia -- 8.4.4 Melanoma -- 8.4.5 Colon Cancer -- 8.5 Biosurfactants as Drug Delivery System (DDS) -- 8.5.1 Liposomes -- 8.5.2 Niosomes -- 8.5.3 Nanoparticles -- 8.6 Conclusions and Future Challenges -- References -- 9: Biosurfactants for Oil Pollution Remediation -- 9.1 Introduction -- 9.2 Oil Pollution and Its Remediation -- 9.2.1 Oil Pollution -- 9.2.2 Oil Remediation in Polluted Environments -- 9.3 Biosurfactants -- 9.3.1 Synthesis of Biosurfactants -- 9.3.2 Biosurfactant Role in Oil Degradation -- 9.4 Application of Biosurfactants Used for Oil Remediation -- 9.4.1 Oil-Polluted Soil Bioremediation -- 9.4.2 Bioremediation of Marine Oil Spills and Petroleum Contamination -- 9.4.3 Cleaning of Oil Tanks and Pipelines -- 9.4.4 Bioremediation of Heavy Metals and Toxic Pollutants -- 9.5 Conclusion -- References -- 10: Potential Applications of Anti-Adhesive Biosurfactants -- 10.1 Introduction -- 10.2 Biosurfactants That Display Anti-Adhesive Activity -- 10.3 Biofilms and the Adhesion Process: Mechanisms and Effects -- 10.4 Applications of Biosurfactants as Anti-Adhesive Agents -- 10.4.1 Anti-Adhesive Applications in the Biomedical Field -- 10.4.2 Anti-Adhesive Applications in the Food Industry Surfaces -- 10.5 Future Trends and Conclusions -- References. , 11: Applications of Biosurfactant for Microbial Bioenergy/Value-Added Bio-Metabolite Recovery from Waste Activated Sludge -- 11.1 Introduction -- 11.2 Applications of Surfactants for Value-Added Bio-Metabolites Recovery from WAS -- 11.3 Applications of Surfactants for Energy Recovery from WAS -- 11.4 Applications of Surfactants for Refractory Organic Decontamination from WAS -- 11.4.1 PAHs Decontamination -- 11.4.2 Dye Decontamination -- 11.4.3 PCB Decontamination -- 11.5 Applications of Surfactants for WAS Dewatering -- 11.6 Applications of Surfactants for Heavy Metal Removal from WAS -- 11.7 State-of-the-Art Processes to Promote Organics Biotransformation from WAS -- 11.7.1 Co-Pretreatment -- 11.7.2 Interfacing AD with Bioelectrochemical Systems -- 11.7.3 Optimizing Process Conditions -- 11.8 Conclusion -- References -- 12: Application of Microbial Biosurfactants in the Pharmaceutical Industry -- 12.1 Introduction -- 12.2 Mechanism of Interaction of Biosurfactants -- 12.3 Physiochemical Properties -- 12.3.1 Surface Tension -- 12.3.2 Biosurfactant and Self-Assembly -- 12.3.3 Emulsification Activity -- 12.4 Application of Biosurfactants in Pharmaceutical Industry -- 12.4.1 Biosurfactant as an Antitumor/AntiCancer Agent -- 12.4.2 Biosurfactants as Drug Delivery Agents -- 12.4.3 Wound Healing and Dermatological Applications -- 12.4.4 Potential Antimicrobial Application -- 12.4.5 Other Applications in the Pharmaceutical Field -- 12.5 Applications of Surfactin in Pharmaceutical Industry -- 12.6 Concluding Remarks -- References -- 13: Antibacterial Biosurfactants -- 13.1 Introduction -- 13.2 Glycolipids -- 13.2.1 Rhamnolipids -- 13.2.2 Sophorolipids -- 13.2.3 Trehalose Lipids -- 13.3 Lipopeptides -- 13.4 Phospholipids -- 13.5 Antibacterial Activity -- 13.6 Polymeric Surfactants -- 13.7 Fatty Acids -- 13.7.1 Bio-Sources of Fatty Acids. , 13.7.2 Role of Fatty Acids as Antimicrobials.
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  • 2
    Keywords: Organic compounds-Synthesis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (590 pages)
    Edition: 1st ed.
    ISBN: 9780323996440
    DDC: 620.1180286
    Language: English
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  • 3
    Keywords: Environmental engineering. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (300 pages)
    Edition: 1st ed.
    ISBN: 9780128219010
    DDC: 541.39
    Language: English
    Note: Intro -- Green Sustainable Process for Chemical and Environmental Engineering and Science: Green Inorganic Synthesis -- Copyright -- Contents -- Contributors -- Chapter 1: Microwave-assisted green synthesis of inorganic nanomaterials -- Description -- Key features -- 1. Introduction -- 2. Technical aspects of microwave technique -- 2.1. Principles and heating mechanism of microwave method -- 2.2. Green solvents for microwave reactions -- 2.3. Microwave versus conventional synthesis -- 2.4. Microwave instrumentation -- 2.5. Advantages and limitations -- 3. MW-assisted green synthesis of inorganic nanomaterials -- 3.1. Metallic nanostructured materials -- 3.2. Metal oxides nanostructured materials -- 3.3. Metal chalcogenides nanostructured materials -- 3.4. Quantum dot nanostructured materials -- 4. Conclusions and future aspects -- 4.1. Challenges and scope to further study -- References -- Chapter 2: Green synthesis of inorganic nanoparticles using microemulsion methods -- Description -- Key features -- 1. Introduction -- 2. Fundamental aspects of microemulsion synthesis -- 2.1. Microemulsion and types -- 2.2. Micelles, types, and formation mechanism -- 2.3. Hydrophilic-lipophilic balance number -- 2.4. Surfactants and types -- 2.5. Advantages and limitations of microemulsion synthesis of nanomaterials -- 3. Microemulsion-assisted green synthesis of inorganic nanostructured materials -- 3.1. General mechanism microemulsion method for nanomaterial synthesis -- 3.2. Preparation of metallic and bimetallic nanoparticles -- 3.3. Metal oxide synthesis by microemulsion -- 3.4. Synthesis of metal chalcogenide nanostructured materials -- 3.5. Synthesis of inorganic quantum dots -- 4. Conclusions, challenges, and scope to further study -- References -- Chapter 3: Synthesis of inorganic nanomaterials using microorganisms -- 1. Introduction. , 2. Green approach for synthesis of nanoparticles -- 3. General mechanisms of biosynthesis -- 4. Optimization of nanoparticles biosynthesis -- 4.1. Effect of the temperature -- 4.2. Effect of pH -- 4.3. Effect of metal precursor concentration -- 4.4. Effect of culture medium composition -- 4.5. Effect of biomass quantity and age -- 4.6. Synthesis time -- 5. Biosynthesis of metal oxide nanoparticles -- 5.1. Bacteria-mediated synthesis -- 5.2. Fungi-mediated synthesis -- 5.3. Yeast-mediated synthesis -- 5.4. Algae- and viruses-mediated synthesis -- 6. Biosynthesis of metal chalcogenide nanoparticles -- 7. Final considerations -- References -- Chapter 4: Challenge and perspectives for inorganic green synthesis pathways -- 1. Introduction -- 2. Synthesis methods -- 2.1. Physical synthesis -- 2.1.1. Advantages -- 2.1.2. Inconvenient -- 2.2. Chemical synthesis -- 2.2.1. Advantages -- 2.2.2. Inconvenient -- 2.3. Green synthesis of inorganic nanomaterials and application -- 3. Challenge and perspectives -- 4. Conclusion -- References -- Chapter 5: Synthesis of inorganic nanomaterials using carbohydrates -- 1. Introduction -- 1.1. Types of nanomaterials -- 1.2. Approaches for the synthesis of inorganic nanomaterials -- 1.3. Characterization of inorganic nanomaterials -- 1.4. What are carbohydrates? -- 1.4.1. Types of carbohydrates -- Monosaccharides -- Oligosaccharides -- Polysaccharides -- 2. Synthesis of inorganic nanomaterials using carbohydrates -- 2.1. Synthesis of metal nanomaterials using carbohydrates -- 2.2. Synthesis of metal oxide-based nanomaterials using carbohydrates -- 2.3. Synthesis of nanomaterials using polysaccharides extracted from fungi and plant -- 3. The advantages and disadvantages of inorganic nanomaterials -- 4. Conclusion and future scope -- References -- Chapter 6: Fundamentals for material and nanomaterial synthesis. , 1. Introduction -- 2. Fundamental synthesis for materials -- 2.1. Solid-state synthesis -- 2.2. Chemical vapor transport -- 2.3. Sol-gel process -- 2.4. Melt growth (MG) method -- 2.5. Chemical vapor deposition -- 2.6. Laser ablation methods -- 2.7. Sputtering method -- 2.8. Molecular beam epitaxy method -- 3. Fundamental synthesis for nanomaterials -- 3.1. Top-down and bottom-up approaches -- 3.1.1. Ball milling (BL) synthesis process -- 3.1.2. Electron beam lithography -- 3.1.3. Inert gas condensation synthesis method -- 3.1.4. Physical vapor deposition methods -- 3.1.5. Laser pyrolysis methods -- 3.2. Chemical synthesis methods -- 3.2.1. Sol-gel method -- 3.2.2. Chemical vapor deposition method -- 3.2.3. Hydrothermal synthesis -- 3.2.4. Polyol process -- 3.2.5. Microemulsion technique -- 3.2.6. Microwave-assisted (MA) synthesis -- 3.3. Bio-assisted (B-A) methods -- 4. Conclusion -- References -- Chapter 7: Bioinspired synthesis of inorganic nanomaterials -- 1. Introduction -- 1.1. Nanomaterials and current limitations -- 1.2. Bioinspired synthesis -- 2. General mechanism of interaction -- 3. Bioinspired synthesis of inorganic nanomaterials -- 3.1. Microorganisms-mediated synthesis -- 3.2. Plant-mediated synthesis -- 3.2.1. Root extract assisted synthesis -- 3.2.2. Leaves extract assisted synthesis -- 3.2.3. Shoot-mediated synthesis -- 3.3. Protein templated synthesis -- 3.4. DNA-templated synthesis -- 3.5. Butterfly wing scales-templated synthesis -- 4. Applications of bioinspired nanomaterials -- 5. Conclusions -- References -- Chapter 8: Polysaccharides for inorganic nanomaterials synthesis -- 1. Introduction -- 2. Polysaccharides -- 2.1. Types of polysaccharides -- 2.1.1. Cellulose -- 2.1.2. Starch -- 2.1.3. Chitin -- 2.1.4. Chitosan -- 2.1.5. Properties of polysaccharides for bioapplications -- 3. Nanomaterials -- 3.1. Types of nanomaterials. , 3.1.1. Organic nanomaterials -- Carbon nanotubes -- Graphene -- Fullerenes -- 3.1.2. Inorganic nanomaterials -- Magnetic nanoparticles -- Metal nanoparticles -- Metal oxide nanoparticles -- Luminescent inorganic nanoparticles -- 3.2. Health effects of nanomaterials -- 4. Polysaccharide-based nanomaterials -- 4.1. Cellulose nanomaterials -- 4.1.1. Preparation of cellulose nanomaterials -- 4.1.2. Structure of cellulose nanomaterials -- 4.2. Chitin nanomaterials -- 4.2.1. Preparation of chitin nanomaterials -- 4.2.2. Structure and properties of chitin nanomaterials -- 4.3. Starch nanomaterials -- 4.3.1. Preparation of starch nanomaterials -- 4.3.2. Structure and properties of starch nanomaterials -- 5. Preparation of polysaccharide-based inorganic nanomaterials -- 5.1. Bulk nanocomposites -- 5.2. Composite nanoparticles -- 6. Applications of polysaccharide-based inorganic nanomaterials -- 6.1. Biotechnological applications -- 6.1.1. Bioseparation -- 6.1.2. Biolabeling and biosensing -- 6.1.3. Antimicrobial applications -- 6.2. Biomedical applications -- 6.2.1. Drug delivery -- 6.2.2. Digital imaging -- 6.2.3. Cancer treatment -- 6.3. Agricultural applications -- 7. Characterization of polysaccharide-based nanomaterials -- 7.1. Spectroscopy -- 7.1.1. Infrared (IR) spectroscopy -- 7.1.2. Surface-enhanced Raman scattering (SERS) -- 7.1.3. UV-visible absorbance spectroscopy -- 7.2. Microscopy -- 7.2.1. Scanning electron microscopy (SEM) -- 7.2.2. Transmission electron microscopy (TEM) -- 7.3. X-ray methods -- 7.4. Thermal analysis -- 8. Future prospects -- 9. Concluding remarks -- References -- Chapter 9: Supercritical fluids for inorganic nanomaterials synthesis -- 1. Introduction -- 2. The supercritical fluid as a substitute technology -- 2.1. What is supercritical fluid? -- 2.2. Supercritical antisolvent precipitation. , 2.3. Supercritical-assisted atomization -- 2.4. Sol-gel drying method -- 3. Synthesis in supercritical fluids -- 3.1. Route of supercritical fluids containing nanomaterials synthesis -- 3.2. Sole supercritical fluid -- 3.3. Mixed supercritical fluid -- 4. Theory of the synthesis of supercritical fluids containing nanomaterials -- 4.1. Supercritical fluids working process -- 4.2. Origin of nanoparticles -- 4.3. The rapid expansion of supercritical solutions -- 5. Conclusion -- References -- Chapter 10: Green synthesized zinc oxide nanomaterials and its therapeutic applications -- 1. Introduction -- 2. Green synthesis -- 3. ZnO NPs characterization -- 4. ZnO NPs synthesis by plant extracts -- 5. ZnO NPs synthesis by bacteria and actinomycetes -- 6. ZnO NPs synthesis by algae -- 7. ZnO NPs synthesis by fungi -- 8. NPs synthesis by virus -- 9. ZnO NPs synthesis with alternative green sources -- 10. Therapeutic applications -- 11. Conclusions -- References -- Chapter 11: Sonochemical synthesis of inorganic nanomaterials -- 1. Background -- 2. Inorganic nanomaterials in sonochemical synthesis -- 3. Applications -- 4. Final comments -- References -- Index.
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  • 4
    Keywords: Organic compounds-Synthesis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (412 pages)
    Edition: 1st ed.
    ISBN: 9780128198490
    DDC: 547/.2
    Language: English
    Note: Intro -- Green Sustainable Process for Chemical and Environmental Engineering and Science: Organic Synthesis in Water and Supercriti... -- Copyright -- Contents -- Contributors -- Chapter 1: Polymer synthesis in water and supercritical water -- 1. Introduction -- 1.1. Water in industries -- 1.2. Supercritical fluids -- 1.3. Properties of water and supercritical water -- 2. Polymerization in water medium -- 2.1. Emulsion polymerization -- 2.2. Photoactivated polymerization -- 2.3. Dispersion polymerization -- 2.4. Controlled/``living´´ radical polymerization -- 2.5. Radical polymerization -- 2.6. Oxidative polymerization -- 2.7. Solution polymerization -- 2.8. Enzyme-catalyzed polymerization -- 3. Supercritical water in polymer technology -- 3.1. Supercritical water in lignocellulosic polymers -- 3.1.1. Cellulose -- 3.1.2. Hemicellulose -- 4. Conclusion -- Acknowledgment -- References -- Chapter 2: Ring-opening reactions in water -- 1. N-nucleophiles -- 1.1. Aliphatic and aromatic amines -- 1.1.1. Racemic synthesis of β-amino alcohols -- 1.1.2. Enantioselective synthesis of β-amino alcohols -- 1.2. Azidolysis -- 2. O-nucleophiles -- 3. S-nucleophile -- 4. C-nucleophiles -- 5. Se-nucleophile -- 6. H-nucleophiles -- References -- Chapter 3: Cycloaddition reactions in water -- 1. Introduction -- 2. ``In-water´´ cycloaddition reactions -- 2.1. [4+2] Cycloaddition (Diels-Alder) reactions -- 2.2. Hydrophobicity effect on rate enhancement in water -- 2.2.1. Structure facilitated hydrophobic effect -- 2.3. Hydrogen-bonding effect on rate enhancement -- 2.4. Endo- vs exo-selectivity in intermolecular D-A reactions -- 2.5. Inverse electron demand D-A reactions in water -- 2.6. Asymmetric Diels-Alder reactions in water -- 2.7. Application to the total synthesis of natural products -- 2.8. Intramolecular Diels-Alder reactions in water. , 2.9. Aqueous intramolecular D-A reaction in the total synthesis -- 2.10. [3+2] Cycloaddition reactions in water -- 2.11. [4+3] Cycloaddition reaction -- 2.12. [2+2+2] Cycloadditions -- 2.13. [5+2] Cycloadditions -- 3. Cycloaddition reactions ``on-water´´ -- 4. Concluding remarks -- Acknowledgments -- References -- Chapter 4: Hydrogenation reactions in water -- 1. Introduction -- 2. Types of hydrogenation -- 2.1. Catalytic hydrogenation -- 2.2. Transfer hydrogenation -- 2.3. Asymmetric hydrogenation -- 2.4. Asymmetric transfer hydrogenation -- 2.5. Electrocatalytic hydrogenation -- 2.6. Selective hydrogenation -- 2.6.1. Chemoselective hydrogenation -- 2.6.2. Diastereoselective hydrogenation -- 2.6.3. Regioselective hydrogenation -- 2.7. Other hydrogenation -- 3. Water as hydrogen donor -- 3.1. Synthesis of aliphatic compounds -- 3.2. Synthesis of aromatic compounds -- 3.3. Synthesis of carbonyl compounds -- 3.4. Synthesis of alcohols, ethers, sugars, nitro and nitril compounds -- 3.5. Synthesis of bio-oils, fossil fuel, and cellulose -- 4. Water as solvent -- 4.1. Synthesis of aliphatic compounds -- 4.2. Synthesis of aromatic compounds -- 4.3. Synthesis of carbonyl compounds -- 4.4. Synthesis of alcohols, ethers, sugars, nitro, and nitril compounds -- 5. Conclusion -- References -- Chapter 5: Magnetically separable nanocatalyzed synthesis of bioactive heterocycles in water -- 1. Introduction -- 2. Synthesis of nitrogen-containing heterocycles -- 2.1. Synthesis of N-substituted pyrroles -- 2.2. Synthesis of 1,4-dihydropyridines -- 2.3. Synthesis of hexahydroquinoline carboxylates -- 2.4. Synthesis of quinolines -- 2.5. Synthesis of acridine-1,8(2H,5H)-diones -- 2.6. Synthesis of benzo[d]imidazoles -- 2.7. Synthesis of imidazo[1,2-a]pyridines -- 2.8. Synthesis of quinoxalines -- 2.9. Synthesis of 1,2,3-triazoles. , 2.10. Synthesis of pyrimido[4,5-b]quinoline and indeno fused pyrido[2,3-d]pyrimidines -- 2.11. Synthesis of pyrido[2,3-d:6,5-d]dipyrimidines -- 2.12. Synthesis of spiropyrazolo pyrimidines -- 2.13. Synthesis of spiro[indoline-3,5-pyrido[2,3-d]pyrimidine] derivatives -- 2.14. Synthesis of 2-amino-tetrahydro-1H-spiro[indoline-3,4-quinoline] derivatives -- 2.15. Synthesis of spiro[indoline-3,2-quinoline] derivatives -- 3. Synthesis of oxygen-containing heterocycles -- 3.1. Synthesis of 4-methylcoumarins -- 3.2. Synthesis of 2-amino-3-cyano-4H-chromenes -- 3.3. Synthesis of 2-amino-4H-chromen-4-yl phosphonates -- 3.4. Synthesis of tetrahydro-1H-xanthen-1-one -- 3.5. Synthesis of pyran annulated scaffolds -- 4. Synthesis of nitrogen as well as oxygen-containing heterocycles -- 4.1. Synthesis of furo[3,4-b]quinoline derivatives -- 4.2. Synthesis of spiro[furo[3,4:5,6]pyrido[2,3-d]pyrimidine-5,3-indoline] derivatives -- 4.3. Synthesis of spirooxindole derivatives -- 4.4. Synthesis of pyrrole fused heterocycles -- 4.5. Synthesis of pyrano[2,3-c]pyrazoles -- 4.6. Synthesis of tetrahydropyrano[3,2-c]quinolin-5-ones -- 4.7. Synthesis of chromeno[1,6]naphthyridines -- 4.8. Synthesis of 1H-naphtho[1,2-e][1,3]oxazine derivatives -- 5. Conclusions -- Acknowledgments -- References -- Chapter 6: Stereoselective organic synthesis in water: Organocatalysis by proline and its derivatives -- 1. Introduction -- 2. Reactions in homogeneous solution or micellar media -- 2.1. Aldol reaction -- 2.2. Knoevenagel condensation -- 2.3. Michael addition -- 2.4. Mannich reaction -- 2.5. Diels-Alder reaction -- 2.6. α-Aminoxylation -- 2.7. Asymmetric hydrogenation -- 3. Reactions catalyzed by solid-supported proline derivatives -- 3.1. Reactions catalyzed by silica-supported proline species -- 3.2. Reactions catalyzed by polymer-supported proline species -- 4. Summary and outlook. , References -- Chapter 7: CN formation reactions in water -- 1. Introduction -- 2. Homogeneous catalysts -- 3. Heterogeneous catalysts -- 4. Conclusions -- Acknowledgments -- References -- Chapter 8: Regioselective synthesis in water -- 1. Introduction -- 2. Metal catalyzed regioselective organic synthesis in water -- 3. Regioselective organo-catalytic reactions in aqueous media -- 4. A catalyst-free regioselective reaction in aqueous media -- References -- Chapter 9: Aqueous polymerizations -- 1. Introduction -- 2. Polymerization: Fundamentals and methods -- 2.1. Fundamentals of polymerization -- 2.2. Methods of polymerization: Solution polymerization -- 2.3. Methods of polymerization: Dispersion polymerization and polycondensation -- 2.4. Methods of polymerization: Suspension polymerizations and polycondensations -- 2.5. Emulsion polymerization and polycondensation -- 3. Free-radical polymerizations -- 4. Ionic polymerizations -- 4.1. Cationic polymerization -- 4.2. Anionic polymerization -- 5. Controlled radical polymerizations -- 5.1. Reversible addition-fragmentation chain-transfer polymerizations -- 5.2. Nitroxide-mediated polymerization -- 6. Metal-mediated polymerizations -- 6.1. Atom transfer radical polymerization -- 6.2. Ring-opening metathesis polymerization -- 7. Polycondensation -- 8. Conclusions -- Acknowledgments -- References -- Chapter 10: Microwave- and ultrasound-assisted heterocyclics synthesis in aqueous media -- 1. Introduction -- 2. Microwave-assisted heterocyclics synthesis in water -- 3. Ultrasound-assisted heterocyclics synthesis in water -- 4. Conclusion and future prospects -- References -- Chapter 11: Recent advances on carbon-carbon bond forming reactions in water -- 1. Introduction -- 2. Carbon-carbon coupling reactions -- 3. Couplings in water are biphasic -- 4. Heterogeneous catalysis. , 5. Factors affecting CC coupling reactions in water -- 5.1. Catalyst -- 5.2. Bimetallic catalysts -- 5.3. Base and concentration effect -- 5.4. Light water/heavy water -- 5.5. Energy source -- 5.6. Additives and transfer agents -- 6. Specific CC coupling reactions -- 6.1. Mizoroki-Heck reaction -- 6.2. Hiyama reaction -- 6.3. Suzuki-Miyaura reaction -- 6.4. Sonogashira-Hagihara reaction -- 6.5. Stille reaction -- 6.6. Negishi reaction -- 7. Applications in synthesis -- 7.1. Derivatization of biomolecules -- 7.2. Bioactive molecules -- 8. Conclusions -- References -- Index.
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  • 5
    Keywords: Nanotechnology-Health aspects. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (446 pages)
    Edition: 1st ed.
    ISBN: 9780323951722
    DDC: 615.1
    Language: English
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  • 6
    Online Resource
    Online Resource
    Singapore :Springer Singapore Pte. Limited,
    Keywords: Microbial biotechnology. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (734 pages)
    Edition: 1st ed.
    ISBN: 9789811622250
    Series Statement: Environmental and Microbial Biotechnology Series
    Language: English
    Note: Intro -- Contents -- About the Editors -- 1: Application of Endophyte Microbes for Production of Secondary Metabolites -- 1.1 Introduction -- 1.2 Origin and Evolution of Endophytes -- 1.3 Endophyte Diversity -- 1.4 Close Relationship Between Endophytes and Medicinal Herbs -- 1.5 Endophytes and Secondary Metabolites -- 1.6 Terpenoids -- 1.7 Phenolics -- 1.8 Flavonoids -- 1.9 Alkaloids -- 1.10 Glycosides -- 1.11 Saponins -- 1.12 Polyketides -- 1.13 Coumarins -- 1.14 Steroids -- 1.15 Conclusion and Perspectives -- References -- 2: Application of Microbes in Synthesis of Electrode Materials for Supercapacitors -- 2.1 Introduction -- 2.1.1 Basics of Supercapacitors -- 2.1.2 Electrode Materials for Supercapacitors -- 2.1.3 Why Microbes in Energy Storage Devices? -- 2.2 Different Microbes Commonly Used in EES -- 2.2.1 Bacteria -- What so Special About Bacterial Cellulose? -- 2.2.2 Viruses -- 2.2.3 Fungi -- 2.3 Microbes as Bio-templates for Energy Storage Materials -- 2.3.1 Bacteria as Bio-templates -- 2.3.2 Fungi as Bio-templates -- 2.3.3 Viruses as Bio-templates -- 2.4 Microbe-Based Carbon Materials as Supporting Matrix -- 2.5 Microbe-Derived Carbons for Energy Storage Applications -- 2.5.1 Bacteria-Derived Carbons for Energy storage applications -- 2.5.2 Fungi-Derived Carbons for Energy Storage Applications -- 2.5.3 Microbe-Derived Carbon-Based Nanocomposites as Energy Storage Materials -- 2.6 Conclusion and Future Prospects -- References -- 3: Application of Microbes in Climate-Resilient Crops -- 3.1 Introduction -- 3.2 Heat Stress Tolerance -- 3.3 Cold Stress Tolerance -- 3.4 Submergence Stress Tolerance -- 3.5 Salinity and Drought Stress Tolerance -- 3.6 Conclusion and Future Perspectives -- References -- 4: Application of Microbes in Biotechnology, Industry, and Medical Field -- 4.1 Overview of Microorganisms -- 4.1.1 Prokaryotic Microorganisms. , Bacteria -- Archaea -- 4.1.2 Eukaryotic Microorganisms -- Protist -- Fungi -- Virus -- 4.2 Principles -- 4.2.1 Screening for Microbial Products -- Screening Methods -- 4.2.2 Microbial Bioprocess -- Optimization -- Sustainable Technologies -- 4.2.3 Enzymology -- 4.2.4 Gene Manipulation -- Recombinant DNA Technology -- 4.3 Applications -- 4.3.1 Industry -- Food-Fermented Foods -- Improvement of Food Quality -- Improvement Efficiency and Productivity of Process -- Food Additives -- Agroindustry -- Pest in Crops -- Crop Yield and Product Quality -- Construction -- Chemical Industry -- Cleaning -- Bioremediation -- Chemical-Based Cleaning Products -- 4.3.2 Environment -- Wastewater Treatment -- Solid Hazardous Treatment -- Composting -- Anaerobic Digestion -- Metal Recovery -- Microbial Biofuels -- Biomethanol -- Bioethanol -- Butanol -- Biodiesel -- Medical Biotechnology -- 4.4 Conclusions -- References -- 5: Applications of Microbes for Energy -- 5.1 Introduction -- 5.2 Microbes for Energy Applications -- 5.2.1 Microbes for Fuel Cells -- 5.2.2 Microbes for Hydrogen Production -- 5.2.3 Microbes for Methane Production -- 5.2.4 Microbes for Ethanol Production -- 5.2.5 Microbes for Biodiesel Production -- 5.2.6 Microbes for Electrosynthesis -- 5.2.7 Microbes for Energy Storage -- 5.3 Conclusion and Future Remarks -- References -- 6: Applications of Microbes in Electric Generation -- 6.1 Introduction -- 6.2 Different BFC Types -- 6.2.1 DET-BFC -- 6.2.2 MET-BFC -- 6.2.3 EBFC -- 6.2.4 MFC -- 6.3 Electrocatalytic Nanomaterials for EBFC -- 6.3.1 Carbon Materials -- 6.3.2 Metal Nanoparticles -- 6.3.3 Composite Materials -- 6.4 Electrocatalytic Nanomaterials for MFC -- 6.4.1 Electrocatalytic Nanomaterials for MFC Anode -- Carbon Nanomaterials -- Metal Nanomaterials -- Conductive Polymers -- 6.4.2 Electrocatalytic Nanomaterials for MFC Cathode. , Noble Metal-Based Materials -- Non-noble Metal-Based Materials -- 6.5 Summary and Prospect -- References -- 7: Application of Microbes in Household Products -- 7.1 Introduction -- 7.2 Household Products -- 7.2.1 Cleaning Product -- 7.2.2 Cosmeceutical -- 7.2.3 Textiles -- 7.2.4 Others -- 7.3 Benefits and Challenges -- 7.4 Conclusion -- References -- 8: Electricity Generation and Wastewater Treatment with Membrane-Less Microbial Fuel Cell -- 8.1 Introduction -- 8.2 Electricity Generation -- 8.2.1 Anode and Cathode Electrodes -- Cathode Electrode -- Anode Electrode -- 8.2.2 Effect of Operating Temperature -- 8.2.3 Effect of pH -- 8.2.4 Effect of Substrate Pretreatment -- 8.2.5 Effect of Reactor Design -- 8.2.6 Effect of Electrode Surface Area and Electrode Spacing -- 8.2.7 Effect of Substrate Conductivity -- 8.3 Water Treatment (Substrate) -- 8.4 Conclusion -- References -- 9: Microbes: Applications for Power Generation -- 9.1 Introduction -- 9.2 Reduction of the Environmental and Air Pollution -- 9.2.1 Natural Aerosols from Vegetation -- 9.2.2 Landfill Gas -- 9.2.3 Biogas -- Using Leachate of the Waste -- 9.2.4 Biodiesel -- 9.2.5 Bioethanol -- Using Celluloses -- Using Starch -- Using Sugar -- 9.2.6 Sewer -- 9.3 Energy Efficiency -- 9.3.1 Microorganisms -- 9.3.2 Microbial Fuel Cells -- Using Natural Fermentation -- Using Biomass -- Using Domestic Wastewater -- Using Industrial Wastewater -- Using Sewage -- Using Crop Residue -- Using Mud -- Using Biogas Slurry -- 9.3.3 Newer Microbial Fuel Cells -- Using Electronophore (Traditional) -- Using Biochar (Latest) -- 9.3.4 Biogas -- Using Sewage -- Using Animal Waste -- Using Animal Manure -- 9.3.5 Biohydrogen -- 9.4 Availability -- 9.4.1 Biomass -- 9.5 Clean Energy -- 9.5.1 Algae -- 9.5.2 Microbial Biophotovoltaic Cells -- Using Algae -- Using Cyanobacteria -- Using Plant Rhizodeposition. , 9.6 Sustainability -- 9.6.1 Biomass -- Crop Residue -- 9.6.2 Camphor -- 9.7 Conclusion -- 9.8 Future Approach -- References -- 10: Applications of Microbes in Food Industry -- 10.1 Introduction -- 10.2 Applications of Microorganisms in Food Industry -- 10.2.1 Baking Industry Applications -- 10.2.2 Alcohol and Beverage Industry Applications -- 10.2.3 Enzyme Production and Its Applications -- 10.2.4 Production of Amino Acids -- 10.2.5 Microbial Detergents as Food Stain Removers -- 10.2.6 Dairy Industry Applications -- 10.2.7 Pigment Production -- 10.2.8 Organic Acid Production -- 10.2.9 Aroma and Flavouring Agents Production -- 10.2.10 Miscellaneous Applications -- Xanthan Gum Production -- Ripening Process -- Food Grade Paper Production -- Single-Cell Protein -- Applications in Other Foods -- 10.3 Summary -- References -- 11: Applications of Microbes in Human Health -- 11.1 Introduction -- 11.2 Human Microbiome -- 11.3 Probiotics -- 11.4 Properties of Probiotics -- 11.5 Probiotics Mechanism of Action -- 11.6 Oral Probiotics -- 11.6.1 Probiotics in Preventing Dental Caries Progression -- 11.6.2 Probiotics in Prevention of Gingival Inflammation -- 11.6.3 Probiotics in Prevention of Periodontal Diseases -- 11.7 Probiotics in Halitosis -- 11.7.1 Probiotics in Oral Mucositis -- 11.7.2 Benefits of Probiotics in General Health -- 11.7.3 Anti-Inflammatory Property -- 11.8 Antimicrobial Properties -- 11.9 Antioxidant Properties -- 11.10 Anticancer Properties -- 11.10.1 Probiotics in Treatment of Upper Respiratory Tract Infections -- 11.10.2 Probiotics in Treatment of Urogenital Infections -- 11.10.3 Probiotics in Improvement of Intestinal Health -- 11.10.4 Probiotics in Treatment of Chemotherapy and Radiotherapy Induced Diarrhea -- 11.10.5 Probiotics in Treatment of Anemia -- 11.11 Treatment and Prevention of Obesity -- 11.12 Probiotics as Immunomodulator. , 11.13 Conclusion -- References -- 12: Applications of Microbes in Soil Health Maintenance for Agricultural Applications -- 12.1 Introduction -- 12.2 Microbial Sources -- 12.2.1 Microalgae and Cyanobacteria -- 12.2.2 Fungi -- 12.2.3 Bacteria -- 12.3 Applications of Microbes -- 12.3.1 Plant Growth Regulators -- 12.3.2 Volatile Organic Compounds (VOCs) -- 12.3.3 Biotic Elicitors -- 12.3.4 Bioremediation -- 12.3.5 Biocontrol -- 12.3.6 Different Types of Microbes -- 12.4 Healthy Soil and Eco-Friendly Environment -- 12.4.1 Biofertilizers -- 12.4.2 Biopesticides -- 12.4.3 Bioherbicides -- 12.4.4 Bioinsecticides -- 12.5 Microbiome and Sustainable Agriculture -- 12.5.1 Benefits of Mycorrhizal Fungi -- 12.5.2 Soil and Environmental Health -- 12.6 Conclusion -- References -- 13: Co-functional Activity of Microalgae: Biological Wastewater Treatment and Bio-fuel Production -- 13.1 Introduction -- 13.2 Wastewater Treatment Using Microalgae -- 13.2.1 Wastewater Composition -- 13.2.2 Nutrient Removal -- Influence of Additives in Wastewater on Nutrient Removal by Microalgae -- 13.2.3 Heavy Metal Removal -- 13.3 Microalgae Cultivation and Harvesting -- 13.3.1 Open Ponds -- 13.3.2 Closed System (Photobioreactor PBRs) -- 13.3.3 Hybrid System -- 13.3.4 Harvesting Techniques -- 13.4 Bio-refinery -- 13.5 Bio-fuel Production Using Microalgae -- 13.5.1 Thermochemical Conversion -- 13.5.2 Biochemical Conversion/Fermentation -- 13.5.3 Chemical Reaction/Transesterification -- 13.5.4 Direct Combustion -- 13.6 Sustainability of Energy from Microalgae -- 13.7 Conclusions -- References -- 14: Microalgae Application in Chemicals, Enzymes, and Bioactive Molecules -- 14.1 Introduction -- 14.2 Microalgae-Based Products -- 14.2.1 Chemical Products -- 14.2.2 Bioactive Molecules -- 14.3 Microalgae Enzymes -- 14.4 Industrial Applications of Microalgae. , 14.5 Conclusions and Future Perspectives.
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    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Electronic books.
    Description / Table of Contents: Surveys recent advances in conducting polymers and their composites. Chapters address synthetic approaches, and applications in all types of electrochemical energy storage devices and next-generation devices. Evaluates the execution of these materials as electrodes in electrochemical power sources.
    Type of Medium: Online Resource
    Pages: 1 online resource (353 pages)
    Edition: 1st ed.
    ISBN: 9780429510885
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- Contributors -- Editors -- Chapter 1. Polythiophene-Based Battery Applications -- 1.1 Introduction -- 1.2 Synthesis -- 1.2.1 Electrochemical Polymerization -- 1.2.2 Chemical Synthesis -- 1.3 Battery Applications of PTs -- 1.3.1 PTs as Cathodic Materials -- 1.3.1.1 PTs as Active Materials -- 1.3.1.2 PTs as Binder -- 1.3.1.3 PTs as Conduction-Promoting Agents -- 1.3.2 PTs as Air Cathode -- 1.3.2.1 Li-Air Batteries -- 1.3.2.2 Aluminum-Air Battery -- 1.3.2.3 Zinc-Air Battery -- 1.3.3 PTs as Anodic Materials -- 1.3.3.1 PTs as Active Materials for Anode -- 1.3.3.2 PTs as Binders -- 1.3.3.3 PTs as Conduction Promoting Agents (CPAs) -- 1.3.4 PTs as Battery Separators -- 1.3.4.1 Li-Ion Batteries -- 1.3.4.2 Li-S Batteries -- 1.3.4.3 Li-O2 Batteries -- 1.3.5 PTs as Electrolytes -- 1.3.6 PTs as Coin-cell Cases -- 1.3.7 PTs as Li-O2 Catalyst -- 1.4 Conclusion -- References -- Chapter 2. Synthetic Strategies and Significant Issues for Pristine Conducting Polymers -- 2.1 Introduction -- 2.2 Conduction Mechanism -- 2.3 Synthesis of Conducting Polymers -- 2.3.1 Synthesis through Polymerization -- 2.3.1.1 Chain-Growth Polymerization -- 2.3.1.2 Step-Growth Polymerization -- 2.3.2 Synthesis by Doping with Compatible Dopants -- 2.3.2.1 Types of Doping Agents -- 2.3.2.2 Doping Techniques -- 2.3.2.3 Mechanism of Doping -- 2.3.2.4 Influence of Doping on Conductivity -- 2.3.3 Electrochemical Polymerization -- 2.3.4 Photochemical Synthesis -- 2.4 Various Issues for Synthesis -- 2.4.1 Vapor-Phase Polymerization -- 2.4.2 Hybrid Conducting Polymers -- 2.4.3 Nanostructure Conducting Polymers -- 2.4.4 Narrow Bandgap Conducting Polymers -- 2.4.5 Synthesis in Supercritical CO2 -- 2.4.6 Biodegradability and Biocompatibility of Conducting Polymers -- 2.5 Applications. , 2.6 Future Scope for Applications -- 2.7 Conclusions -- Abbreviations -- References -- Chapter 3. Conducting Polymer Derived Materials for Batteries -- 3.1 Introduction -- 3.2 Theory -- 3.3 Discussion on Conducting Polymer-Derived Materials -- 3.3.1 PEDOT Derivatives -- 3.3.1.1 Structural Properties -- 3.3.1.2 Electrochemical Studies of PEDOT and Its Derivatives -- 3.3.1.3 Magnetic Properties -- 3.3.2 PPy for the Energy-Storage Devices -- 3.3.2.1 Structural Property of PPy -- 3.3.2.2 Electrochemical Properties of Polypyrrol -- 3.3.2.3 Magnetic Properties -- 3.3.3 PANI for Battery Application -- 3.3.3.1 Structural Properties -- 3.3.3.2 Electrochemical Properties of PANI for Battery Electrode -- 3.3.3.3 Magnetic Properties of PANI -- 3.4 Summary and Conclusions -- References -- Chapter 4. An Overview on Conducting Polymer-Based Materials for Battery Application -- 4.1 Introduction -- 4.2 Principle of Conducting Polymer Battery -- 4.3 Assortment of Conducting Polymer Electrodes for Battery Application -- 4.4 Mechanism of Conducting Polymers in Rechargeable Batteries -- 4.5 Organic Conducting Polymer for Lithium-ion Battery -- 4.5.1 Types of Organic Conducting Polymers -- 4.6 Synthesis of Conducting Polymer -- 4.6.1 Hard-template Method -- 4.6.2 Soft-template Method -- 4.6.3 Template-free Technique -- 4.6.4 Self-Assembly or Interfacial -- 4.6.5 Electrospinning -- 4.7 Characterization -- 4.7.1 Surface Characterization by AFM and AFMIR -- 4.7.2 Transmission Electron Microscopy -- 4.7.3 Electrochemical Characterization -- 4.8 Applications of Various Conducting Polymers in Battery -- 4.8.1 Polyacetylene Battery -- 4.8.2 Polyaniline Batteries -- 4.8.3 Poly (p-phenylene) Batteries -- 4.8.4 Heterocyclic Polymer Batteries -- 4.9 Summary and Outlook -- References -- Chapter 5. Polymer-Based Binary Nanocomposites -- 5.1 Introduction -- 5.2 Binary Composites. , 5.3 Nanostructured CPs -- 5.4 Strategies to Improve Performance -- 5.4.1 Low-dimensional Capacitors -- 5.4.2 Hybrid Capacitors -- 5.4.2.1 Hybrid Electrode Material -- 5.5 CP/Carbon-based Binary Composite -- 5.6 CP/Metal Oxides Binary Composites -- 5.7 CP/Metal Sulfides Binary Complexes -- 5.8 Other Cp-supported Binary Complexes -- 5.9 Conclusion -- References -- Chapter 6. Polyaniline-Based Supercapacitor Applications -- 6.1 Introduction -- 6.2 Polyaniline (PANI) and Its Application Potential -- 6.3 Supercapacitors -- 6.3.1 PANI in Supercapacitors -- 6.3.2 PANI and Carbon Composites -- 6.3.3 PANI/Porous and Carbon Composites -- 6.3.4 PANI/Graphene Composites -- 6.3.5 PANI/CNTs Composites -- 6.3.6 Polyaniline Activation/Carbonization -- 6.3.7 Composites of Polyaniline with Various Conductive Polymer Blends -- 6.3.8 Composites of Polyaniline with Transition Metal Oxides -- 6.3.9 Composites of Polyaniline Core-Shells with Metal Oxides -- 6.3.10 PANI-modified Cathode Materials -- 6.3.11 PANI-modified Anode Materials -- 6.4 Redox-active Electrolytes for PANI Supercapacitors -- 6.5 Examples of Various Polyaniline-based Supercapacitor -- 6.5.1 Composites of Polyaniline Doped with CoCl2 as Materials for Electrodes -- 6.5.2 Composites of Polyaniline Nanofibers with Graphene as materials for electrodes -- 6.5.3 Composites of Polyaniline (PANI) with Graphene Oxide as Electrode Materials -- 6.5.4 Hybrid Films of Manganese Dioxide and Polyaniline as Electrode Materials -- 6.5.5 Composites of Activated Carbon/Polyaniline with Tungsten Trioxide as Electrode Materials -- 6.5.6 PANI- and MOF-based Flexible Solid-state Supercapacitors -- 6.5.7 Polyaniline-based Nickel Electrodes for Electrochemical Supercapacitors -- 6.5.8 Hydrogel of Ultrathin Pure Polyaniline Nanofibers in Supercapacitor Application -- Conclusion -- Acknowledgements -- References. , Chapter 7. Conductive Polymer-derived Materials for Supercapacitor -- 7.1 Introduction -- 7.2 Types of Supercapacitor -- 7.3 Parameters of Supercapacitors -- 7.4 Conducting Polymers (CPs) as Electrode Materials -- 7.4.1 Class of Conducting Polymer as Supercapacitor Electrode -- 7.5 Polyaniline (PANI)-based Electrode -- 7.6 Polypyrrole (PPy)-based Electrode -- 7.7 Polythiophene (PTh)-based Electrode -- 7.8 Conclusions -- Acknowledgement -- References -- Chapter 8. Conducting Polymer-Metal Based Binary Composites for Battery Applications -- 8.1 Conducting polymer (CPs) -- 8.2 Conducting polymers conductivity -- 8.3 Conducting polymer composites -- 8.3.1 Metal center nanoparticles -- 8.3.2 Metal nanoparticles -- 8.4 Conducting Polymer Based Binary Composites -- 8.4.1 Metal Matrix Composites (MMC) -- 8.4.2 Poly (Thiophene) composite -- 8.4.3 Poly (Para-Phenylene Vinylene) composite -- 8.4.4 Poly (Carbazole) composite -- 8.4.5 Vanadium oxide based conducting composite -- 8.4.6 PANI-V2O5 composite -- 8.4.7 Poly(N-sulfo propyl aniline)-V2O5 composite -- 8.5 Conducting polymer composite battery applications -- 8.5.1 Conducting polymer composite for Lithium-ion (Li+) based battery -- 8.5.2 Conducting polymer composites for Sodium-ion (Na+) based Battery -- 8.5.3 Conducting Polymer composite for Mg-Ion (Mg+2) Based Battery -- 8.6 Conducting polymer based composites for electrode materials -- References -- Chapter 9. Novel Conducting Polymer-Based Battery Application -- 9.1 Conducting Polymers (CPs) -- 9.1.1 Poly(Acetylene) -- 9.1.2 Poly(Thiophene) -- 9.1.3 Poly(Aniline) -- 9.1.4 Poly(Pyrrole) -- 9.1.5 Poly(Paraphenylene) and Poly(Phenylene) -- 9.2 Battery Applications of Conducting Polymers -- 9.2.1 Lithium Sulfide batteries -- 9.2.2 Binder for Lithium sulfide battery cathode -- 9.2.3 Sulfur encapsulation for electrode materials. , 9.2.4 Sulfur Encapsulation through Conductive Polymers -- 9.2.5 Conducting polymer anodes for Lithium sulfide battery -- 9.2.6 Conducting polymer as materials interlayer -- 9.3 Li+-ion-based Battery Applications of Conducting Polymers -- 9.4 Na+- ion-based Battery Applications of Conducting Polymers -- 9.5 Mg+2-ion-based Battery Applications of Conducting Polymers -- References -- Chapter 10. Conducting Polymer-Carbon-Based Binary Composites for Battery Applications -- Abbreviations -- 10.1 Introduction -- 10.2 Batteries -- 10.2.1 Types of Batteries -- 10.2.2 Electrode Materials -- 10.3 Conducting Polymer-Carbon-Based Binary Composite in Battery Applications -- 10.3.1 Polyaniline PANI-Carbon-Based Composite -- 10.3.2 Polypyrrole (PPy)-Carbon-Based Composite -- 10.3.3 Poly(3,4-ethylenedioxythiophene) (PEDOT)-Carbon-Based Composite -- 10.3.4 Others Conducting Polymer-Carbon-Based Composite -- 10.4 Conclusions -- Acknowledgements -- References -- Chapter 11. Polyethylenedioxythiophene-Based Battery Applications -- 11.1 Chemistry of PEDOT -- 11.1.1 PEDOT Synthesis and Morphology -- 11.1.1.1 Synthetic Techniques to Achieve Desired Morphologies -- 11.1.2 PEDOT-Based Nanocomposites -- 11.2 PEDOT-Based Polymers in Lithium-Sulfur Batteries -- 11.3 Lithium-Air Battery Based on PEDOT or PEDOT:PSS -- 11.3.1 PEDOT-Based Nanocomposites for Li-O2 Batteries -- 11.3.2 PEDOT:PSS-Based Li-O2 Battery Cathodes -- 11.4 Lithium and Alkali Ion Polythiophene Batteries -- 11.4.1 Cathodes -- 11.4.1.1 Cathode Binders and Composites -- 11.4.2 Anodes -- 11.4.2.1 Anode Binders and Composites -- 11.4.3 All-Polythiophene and Metal-Free Batteries -- References -- Chapter 12. Polythiophene-Based Supercapacitor Applications -- 12.1 Introduction -- 12.2 Properties of Polythiophene (PTh) -- 12.3 Synthesis of Polythiophene -- 12.4 Charge Storage in Polythiophene Electrochemical Capacitors. , 12.5 Polythiophene Electrode Fabrication.
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  • 8
    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Porous materials. ; Electronic books.
    Description / Table of Contents: Internationally assembled experts in the field describe developments and advances in synthesis, tuning parameters, and applications of porous polymers. Chapter topics span basic studies, novel issues, and applications addressing all aspects in a one-stop reference on porous polymers.
    Type of Medium: Online Resource
    Pages: 1 online resource (277 pages)
    Edition: 1st ed.
    ISBN: 9781000567168
    DDC: 547/.7
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- Editors -- Contributors -- Chapter 1: Introduction to Porous Polymers -- 1.1 Introduction -- 1.2 Types of Porous Polymers -- 1.3 Synthetic Methods for Porous Polymer Network -- 1.4 Conclusion -- References -- Chapter 2: Hyper-crosslinked Polymers -- 2.1 Introduction -- 2.1.1 Overview -- 2.1.2 Porous Polymer -- 2.1.3 Crosslinking -- 2.2 Hyper-crosslinked Polymers -- 2.3 Synthesis Methods of HCPs -- 2.3.1 Post-crosslinking Polymer Precursors -- 2.3.2 Direct One-Step Polycondensation -- 2.3.3 Knitting Rigid Aromatic Building Blocks by External Crosslinkers -- 2.4 Structure and Morphology of HCPs -- 2.4.1 Nanoparticles -- 2.4.2 Hollow Capsules -- 2.4.3 2D Membranes -- 2.4.4 Monoliths -- 2.5 HCPs Properties -- 2.5.1 Polymer Surface -- 2.5.1.1 Hydrophilicity -- 2.5.1.2 Hydrophobicity -- 2.5.1.3 Amphiphilicity -- 2.5.2 Porosity and Surface Area -- 2.5.3 Swelling Behavior -- 2.5.4 Thermomechanical Properties -- 2.6 Functionalization of HCPs -- 2.7 Characterization of HCPs -- 2.7.1 Compositional and Structural Characterization -- 2.7.2 Morphological Characterization -- 2.7.3 Porosity and Surface Area Analysis -- 2.7.4 Other Analysis -- 2.8 Applications -- 2.8.1 Storage Capacity -- 2.8.1.1 Storage of Hydrogen -- 2.8.1.2 Storage of Methane -- 2.8.1.3 CO 2 Capture -- 2.8.2 Environmental Remediation -- 2.8.3 Heterogeneous Catalysis -- 2.8.4 Drug Delivery -- 2.8.5 Sensing -- 2.8.6 Other Applications -- 2.9 Conclusion -- References -- Chapter 3: Porous Ionic Polymers -- 3.1 Introduction: A Distinctive Feature of the Porous Structure of Ionic Polymers -- 3.2 Ionic Polymers in Dry State -- 3.3 Ionic Polymers in Swollen State: Hsu-Gierke Model -- 3.4 Modifications of Hsu-Gierke Model: Hydration of Ion Exchange Polymers. , 3.5 Methods for Research of Porous Structure of Ionic Polymers -- 3.5.1 Nitrogen Adsorption-Desorption -- 3.5.2 Mercury Intrusion -- 3.5.3 Adsorption-Desorption of Water Vapor -- 3.5.4 Differential Scanning Calorimetry -- 3.5.5 Standard Contact Porosimetry -- 3.6 Conclusions -- References -- Chapter 4: Analysis of Qualitative and Quantitative Criteria of Porous Plastics -- 4.1 Introduction -- 4.2 Sorting of Porous Polymers -- 4.2.1 Macroporous Polymers -- 4.2.2 Microporous Polymers -- 4.2.3 Mesoporous Polymers -- 4.3 Methodology -- 4.3.1 AHP Analysis -- 4.4 Conclusions -- References -- Chapter 5: Novel Research on Porous Polymers Using High Pressure Technology -- 5.1 Background -- 5.2 Porous Polymers Based on Natural Polysaccharides -- 5.3 Parameters Involved in the Porous Polymers Processing by High Pressure -- 5.4 Supercritical Fluid Drying for Porous Polymers Processing -- 5.5 Porous Polymers for Foaming and Scaffolds by Supercritical Technology -- 5.6 Supercritical CO 2 Impregnation in Porous Polymers for Food Packaging -- 5.7 Synthesis of Porous Polymers by Supercritical Emulsion Templating -- 5.8 Porous Polymers as Supports for Catalysts Materials by Supercritical Fluid -- 5.9 Porous Metal-Organic Frameworks Polymers by Supercritical Fluid Processing -- 5.10 Concluding Remarks -- Acknowledgments -- References -- Chapter 6: Porous Polymer for Heterogeneous Catalysis -- 6.1 Introduction -- 6.2 Stability and Functionalization of POPs -- 6.3 Strategies for Synthesizing POP Catalyst -- 6.3.1 Co-polymerization -- 6.3.1.1 Acidic and Basic Groups -- 6.3.1.2 Ionic Groups -- 6.3.1.3 Ligand Groups -- 6.3.1.4 Chiral Groups -- 6.3.1.5 Porphyrin Group -- 6.3.2 Self-polymerization -- 6.3.2.1 Organic Ligand Groups -- 6.3.2.2 Organocatalyst Groups -- 6.3.2.3 Ionic Groups -- 6.3.2.4 Chiral Ligand Groups -- 6.3.2.5 Porphyrin Groups. , 6.4 Applications of Various Porous Polymers -- 6.4.1 CO 2 Capture and Utilization -- 6.4.1.1 Ionic Liquid/Zn-PPh 3 Integrated POP -- 6.4.1.1.1 Mechanism of the Cycloaddition Reaction -- 6.4.1.2 Triphenylphosphine-based POP -- 6.4.2 Energy Storage -- 6.4.3 Heterogeneous Catalysis -- 6.4.3.1 Cu(II) Complex on Pyridine-based POP for Nitroarene Reduction -- 6.4.3.2 POP-supported Rhodium for Hydroformylation of Olefins -- 6.4.3.3 Ni(II)-metallated POP for Suzuki-Miyaura Crosscoupling Reaction -- 6.4.3.4 Ru-loaded POP for Decomposition of Formic Acid to H 2 -- 6.4.3.5 Porphyrin-based POP to Support Mn Heterogeneous Catalysts for Selective Oxidation of Alcohols -- 6.4.3.5.1 Mechanism of the Oxidation of Alcohols by TFP-DPMs -- 6.4.4 Photocatalysis -- 6.4.4.1 Conjugated Porous Polymer Based on Phenanthrene Units -- 6.4.4.2 (dipyrrin)(bipyridine)ruthenium(II) Visible Light Photocatalyst -- 6.4.4.3 Carbazole-based CMPs for C-3 Functionalization of Indoles -- 6.4.4.3.1 Mechanism of C-3 Formylation of N-methylindole by CMP-CSU6 Polymer Catalyst -- 6.4.4.3.2 The Mechanism for C-3 Thiocyanation of 1H-indole -- 6.4.5 Electrocatalysis -- 6.4.5.1 Redox-active N-containing CPP for Oxygen Reduction Reaction (ORR) -- References -- Chapter 7: Triazine Porous Frameworks -- 7.1 Introduction -- 7.2 Synthetic Procedures of CTFs and Their Structural Designs -- 7.2.1 Ionothermal Trimerization Strategy -- 7.2.2 High Temperature Phosphorus Pentoxide (P 2 O 5)-Catalyzed Method -- 7.2.3 Amidine-based Polycondensation Methods -- 7.2.4 Superacid Catalyzed Method -- 7.2.5 Friedel-Crafts Reaction Method -- 7.3 Applications of CTFs -- 7.3.1 Adsorption and Separation -- 7.3.1.1 CO 2 Capture and Separation -- 7.3.1.2 The Removal of Pollutants -- 7.3.2 Heterogeneous Catalysis -- 7.3.3 Applications for Energy Storage and Conversion -- 7.3.3.1 Metal-Ion Batteries -- 7.3.3.2 Supercapacitors. , 7.3.4 Electrocatalysis -- 7.3.5 Photocatalysis -- 7.3.6 Other Applications of CTFs -- References -- Chapter 8: Advanced Separation Applications of Porous Polymers -- 8.1 Introduction -- 8.2 Advanced Separation Applications -- 8.3 Separation through Adsorption -- 8.4 Water Treatment -- 8.5 Conclusion -- Abbreviations -- References -- Chapter 9: Porous Polymers for Membrane Applications -- 9.1 Introduction -- 9.2 Introduction to Synthesis of Porous Polymeric Particles -- 9.3 Preparation of Porous Polymeric Membrane -- 9.4 Morphology of Membrane and Its Parameters -- 9.5 Emerging Applications of Porous Polymer Membranes -- 9.6 Polysulfone and Polyvinylidene Fluoride Used as Porous Polymers for Membrane Application -- 9.6.1 Polysulfone Membranes -- 9.6.2 Polyvinylidene Fluoride Membranes -- 9.7 Use of Porous Polymeric Membranes for Sensing Application -- 9.8 Use of Porous Polymeric Electrolytic Membranes Application -- 9.9 Use of Porous Polymeric Membrane for Numerical Modeling and Optimization -- 9.10 Use of Porous Polymers for Biomedical Application -- 9.11 Use of Porous Polymeric Membrane in Tissue Engineering -- 9.12 Use of Porous Polymeric Membrane in Wastewater Treatment -- 9.13 Use of Porous Polymeric Membrane for Dye Rejection Application -- 9.14 Porous Polymeric Membrane Antifouling Application -- 9.15 Porous Polymeric Membrane Used for Fuel Cell Application -- 9.16 Conclusion -- References -- Chapter 10: Porous Polymers in Solar Cells -- 10.1 Introduction -- 10.1.1 Si-based Solar Cells -- 10.1.2 Thin-film Solar Cells -- 10.1.3 Organic Solar Cells -- 10.2 Porous Polymers in DSSCs -- 10.2.1 Porous Polymers in Electrodes -- 10.2.2 Porous Polymer as a Counter Electrode -- 10.2.3 Porous Polymers in TiO 2 Photoanode -- 10.2.4 Porous Polymers in Electrolyte -- 10.2.5 Porous Polymer as Energy Conversion Film. , 10.2.5.1 Polyvinylidene Fluoride-co-Hexafluoropropylene (PVDF-HFP) Membranes -- 10.2.5.2 Pyridine-based CMPs Aerogels (PCMPAs) -- 10.2.6 Porous Polymers in Coating of Solar Cell -- 10.2.7 Porous Polymers as Photocatalyst or Electrocatalyst -- 10.3 Perovskite Solar Cells -- 10.3.1 Porous Polymers in Electron Transport Layers -- 10.3.2 Porous Polymers in Hole Transport Layers -- 10.3.3 Porous Polymer as Energy Conversion Film -- 10.3.4 Porous Polymers as Interlayers -- 10.3.5 Porous Polymers in Morphology Regulations -- 10.4 Porous Polymers in Silicon Solar Cell -- 10.5 Miscellaneous -- 10.5.1 Porous Polymers in Solar Evaporators -- 10.5.2 Charge Separation Systems in Solar Cells -- 10.5.3 Porous Polymers in ZnO Photoanode -- 10.6 Conclusions -- References -- Chapter 11: Porous Polymers for Hydrogen Production -- 11.1 Introduction -- 11.1.1 Approaches Utilized for the Generation of Porous Polymers (PPs) -- 11.1.1.1 Infiltration -- 11.1.1.2 Layer-by-Layer Assembly (LbL) -- 11.1.1.3 Conventional Polymerization -- 11.1.1.4 Electrochemical Polymerization -- 11.1.1.5 Controlled/Living Polymerization (CLP) -- 11.1.1.6 Macromolecular Design -- 11.1.1.7 Self-assembly -- 11.1.1.8 Phase Separation -- 11.1.1.9 Solid and Liquid Templating -- 11.1.1.10 Foaming -- 11.2 Various Porous Polymers for H 2 Production -- 11.2.1 Photocatalysts Based on Conjugated Microporous Polymers -- 11.2.2 Conjugated Microporous Polymers -- 11.2.3 Porous Conjugated Polymer (PCP) -- 11.2.4 Membrane Reactor -- 11.2.5 Paper-Structured Catalyst with Porous Fiber-Network Microstructure -- 11.2.6 Porous Organic Polymers (POPs) -- 11.2.7 PEM Water Electrolysis -- 11.2.8 Microporous Inorganic Membranes -- 11.2.9 Hybrid Porous Solids for Hydrogen Evolution -- 11.3 Other Alternatives for Hydrogen Production -- 11.3.1 Metal-Organic Frameworks (MOFs) -- 11.3.2 Covalent Organic Frameworks. , 11.3.3 Photochemical Device.
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  • 9
    Keywords: Green chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (426 pages)
    Edition: 1st ed.
    ISBN: 9780323998178
    DDC: 621.312424
    Language: English
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  • 10
    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Raw materials. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (237 pages)
    Edition: 1st ed.
    ISBN: 9781000596465
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Contents -- Preface -- Editors -- Contributors -- Chapter 1: Graphene from Sugar and Sugarcane Extract: Synthesis, Characterization, and Applications -- Chapter 2: Graphene from Honey -- Chapter 3: Graphene from Animal Waste -- Chapter 4: Graphene from Essential Oils -- Chapter 5: Synthesis of Graphene from Biowastes -- Chapter 6: Graphene from Rice Husk -- Chapter 7: Synthesis of Graphene from Vegetable Waste -- Chapter 8: Graphene Oxide from Natural Products and Its Applications in the Agriculture and Food Industry -- Chapter 9: Graphene from Sugarcane Bagasse: Synthesis, Characterization, and Applications -- Chapter 10: Graphene Synthesis, Characterization and Applications -- Chapter 11: Graphene from Leaf Wastes -- Chapter 12: Biosynthesis of Reduced Graphene Oxide and Its Functionality as an Antibacterial Template -- Chapter 13: Graphene and Its Composite for Supercapacitor Applications -- Index.
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