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  • MDPI AG  (2)
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  • MDPI AG  (2)
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  • 1
    Online Resource
    Online Resource
    MDPI AG ; 2023
    In:  Micromachines Vol. 14, No. 5 ( 2023-04-28), p. 960-
    In: Micromachines, MDPI AG, Vol. 14, No. 5 ( 2023-04-28), p. 960-
    Abstract: With the rapid development of photoelectric communication and other fields, the demand for high-precision aspheric mirrors has been increasing. Predicting dynamic cutting forces is vital in selecting machining parameters and also affects the surface quality of the machined surface. This study comprehensively considers the effects of different cutting parameters and workpiece shape parameters on dynamic cutting force. The actual width of cut, depth of cut, and shear angle are modelled while considering the effects of vibration. A dynamic cutting-force model considering the aforementioned factors is then established. Using experimental results, the model accurately predicts the average value of dynamic cutting force under different parameters and the range of fluctuation of dynamic cutting force, with a controlled relative error of about 15%. The influence of workpiece shape and workpiece radial size on dynamic cutting force is also considered. The experimental results show that the greater the surface slope, the more dramatic the dynamic cutting force fluctuations. This lays the foundation for subsequent writing on vibration suppression interpolation algorithms. The influence of the radius of the tool tip on dynamic cutting forces leads to the conclusion that to achieve the goal of reducing the fluctuation of cutting forces, diamond tools with different parameters should be selected for different feed rates. Finally, a new interpolation-point planning algorithm is used to optimize the position of interpolation points in the machining process. This proves the reliability and practicability of the optimization algorithm. The results of this study are of great significance to the processing of high-reflectivity spherical/aspheric surfaces.
    Type of Medium: Online Resource
    ISSN: 2072-666X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2023
    detail.hit.zdb_id: 2620864-7
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  • 2
    In: Polymers, MDPI AG, Vol. 11, No. 12 ( 2019-11-29), p. 1967-
    Abstract: Pyrolysis of styrene-butadiene rubber receives renewed attention due to its application in tackling the waste tire disposal problem while allowing energy recovery. The density functional theory calculation (DFT) and ReaxFF molecular dynamics simulation (MD) are adopted to study the pyrolysis process with the variation of temperature and pressure. The bond dissociation energies of intramonomer and intermonomer bonds in trimers with different linking methods are calculated by DFT, where the bond with low energy tends to break during the pyrolysis process. The following MD simulation shows the pyrolysis product distribution of chain segments in styrene-butadiene rubber, where bond breaking positions in MD agree well with corresponding results in DFT and experiment. The next nearest neighbor bonds (single bonds) connected with double bond or benzene usually have lower dissociation energies than other single bonds and prone to break during the pyrolysis process. And thus, the intermonomer bonds tend to break at relatively low temperatures (around 650 K in experiment) prior to intramonomer bonds, which result in the emergence of monomers. With the temperature increase, intramonomer bonds are broken and thus large fragments are further pyrolyzed into small ones (e.g., C2 and C). Besides, the pressure strongly influences the product distribution, where high pressures promote the occurrence of secondary reactions.
    Type of Medium: Online Resource
    ISSN: 2073-4360
    Language: English
    Publisher: MDPI AG
    Publication Date: 2019
    detail.hit.zdb_id: 2527146-5
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