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  • MDPI AG  (2)
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  • MDPI AG  (2)
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  • 1
    In: International Journal of Environmental Research and Public Health, MDPI AG, Vol. 16, No. 10 ( 2019-05-16), p. 1724-
    Abstract: Endocrine-disrupting chemicals (EDCs) that exist in the aquatic system bring severe environmental risks. In this study, we investigate the dissolved organic matter (DOM) effect on the release and distribution of EDCs under varied hydrodynamic conditions. A water chamber mesocosm was designed to simulate the hydrodynamic forces in a shallow lake. The contents of bisphenol A (BPA) and nonylphenol (NP) in colloid-bound and soluble phases were measured under four increasing hydrodynamic intensities that were 5%, 20%, 50%, and 80% of the critical shear stress. The total BPA and NP contents in overlying water grew linearly with the hydrodynamic intensity (R2 = 0.997 and 0.987), from 108.28 to 415.92 ng/L of BPA and 87.73 to 255.52 ng/L of NP. The exponential relationships of EDC content and hydrodynamic intensity in soluble phase (R2 = 0.985 of BPA and 0.987 of NP) and colloid phase (R2 = 0.992 of BPA and 0.995 of NP) were also detected. The DOM concentrations in colloid-bound phase (cDOM) and in soluble phase (sDOM) were measured and the linear relationships with BPA content (R2 = 0.967 of cDOM and 0.989 of sDOM) and NP content (R2 = 0.978 of cDOM and 0.965 of sDOM) were detected. We analyzed the ratio (αDOM) of sDOM and cDOM that grew logarithmically with the hydrodynamic intensity (R2 = 0.999). Moreover, the ratio (αEDCs) of BPA and NP contents in soluble and colloid-bound phases varied differently with αDOM. The results suggested that BPA tended to be in the soluble phase and NP tended to be in the colloid-bound phase due to the increasing value of αDOM.
    Type of Medium: Online Resource
    ISSN: 1660-4601
    Language: English
    Publisher: MDPI AG
    Publication Date: 2019
    detail.hit.zdb_id: 2175195-X
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  • 2
    In: Water, MDPI AG, Vol. 13, No. 16 ( 2021-08-06), p. 2161-
    Abstract: Snow cover is a unique environmental medium in cold regions that can cause potential risks to the ecological environment, due to the release of pollutants that are stored in it. In this study, the Qixing River wetland, located in the Sanjiang Plain of China, was taken as the target research area. Heavy metals in snow cover, including Cu, Ni, Cr, Cd, Pb, and Zn were measured at 19 sampling sites. The results showed that the average concentrations of heavy metals were: Zn (103.46 ± 39.16) 〉 Pb (13.08 ± 4.99) 〉 Cr (11.97 ± 2.82) 〉 Ni (9.55 ± 4.96) 〉 Cu (6.19 ± 1.79) 〉 Cd (0.55 ± 0.25) μg·L−1. Cr and Zn were between Class I and Class II in the “Environmental Quality Standards for Surface Water” of China (GB3838-2002). Pb in snow exceeded the upper limit of Class II, and was significantly higher than concentrations measured in water samples from the Qixing River wetland (p 〈 0.05), indicating that atmospheric deposition during winter was the major source of Pb. The water pollution index (WPI) indicated that 61.0% of samples could be considered of “clean” status, while the contribution of Zn, Pb, and Cr to WPI were 33.3%, 21.0%, and 19.3%, respectively. A preliminary evaluation of heavy metal inventory in snow cover showed that the residue level of Zn was the highest (2313.57 ± 1194.67 μg·m−2), while Cd was the lowest (13.91 ± 10.45 μg·m−2). The areas with high residues of heavy metals were all located near the buffer zone of the wetland (except for Zn), where snow depth tended to be greatest. Exposure analysis indicated that the risks to winter resident birds from snow ingestion was minimal, but it should be noted that the exposure risk was higher in birds with lower bodyweights. This study provides important information and scientific knowledge on the pollution characteristics and residue inventory of heavy metals in wetland ecosystems, while the results can also provide a monitoring method, reflecting atmospheric environmental quality at a local or regional scale.
    Type of Medium: Online Resource
    ISSN: 2073-4441
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2521238-2
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