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  • 1
    In: Geosciences, MDPI AG, Vol. 11, No. 7 ( 2021-07-19), p. 298-
    Abstract: Little is known about the nature of ore fluid at the Sopokomil shale-hosted massive sulfide Zn-Pb deposit (North Sumatra, Indonesia). We therefore investigated its ore-fluid salinities, temperatures, densities, redox state, and pH using fluid inclusion microthermometry, sphalerite composition, and thermodynamic modelling. The fluid salinities and temperatures were ≈6 wt.% NaCl equiv and ≈165 °C, respectively, corresponding to an ore fluid less dense than seawater (≈0.96 g/mL). Sphalerite contains ≈9.9 mole% FeS in the stratiform ore and ≈3.4 mole% FeS in the feeder ore, suggesting a reduced fluid, which must have been acidic to be fertile. Such redox state and acidity invoke fluid dilution as the sulfide depositional mechanism. The bulk of the sulfides were precipitated in the early stage of mixing, within T = 165–155 °C. Key ingredients of sphalerite and galena at Sopokomil include (1) Zn that was primarily transported as ZnCl+, (2) Pb that predominantly occurred as PbCl2(aq), and (3) S that was largely supplied by marine sediment porewater. This study highlights the significance of a dramatic shift in thermal and chemical equilibrium induced by fluid dilution in the making of the first significant shale-hosted massive sulfide Zn-Pb deposit in Indonesia.
    Type of Medium: Online Resource
    ISSN: 2076-3263
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2655946-8
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  • 2
    In: Minerals, MDPI AG, Vol. 9, No. 11 ( 2019-10-24), p. 654-
    Abstract: Most of the granite-related Sn–W deposits in Myanmar are located in the Western Granitoid Province (WGP) of Southeast Asia. The Tagu deposit in the southern part of the WGP is a granite related Sn–W deposit. The biotite granite is composed of quartz, feldspars (plagioclase, orthoclase, and microcline), and micas (muscovite and biotite) and belongs to S-type peraluminous granite. Abundances of large-ion lithophile elements (LILEs), such as Rb, K, and Pb, coupled with the deficiency of high-field-strength elements (HFSEs), such as Nb, P, and Ti, indicate that the parental magma for the Tagu granite was derived from the lower continental crust at syn-collisional setting. Mineralized veins consist of early-formed oxide ore minerals, such as cassiterite and wolframite, which were followed by the formation of sulfide minerals. Three main types of fluid inclusions were distinguished from the mineralized quartz veins hosted by granite and metasedimentary rocks: Type-A—two phases, liquid (L) + vapor (V) aqueous inclusions; Type-B—two phases, vapor (V) + liquid (L) vapor-rich inclusions; And type-C—three phases, liquid + CO2-liquid + CO2-vapor inclusions. Quartz in the veins hosted in granite corresponding with earlier deposition contains type-A, type-B, and type-C fluid inclusions, whereas that in the veins hosted in metasedimentary rocks corresponding with later deposition contains only type-A fluid inclusions. The homogenization temperatures of type-A inclusions range from 140 °C to 330 °C (mode at 230 °C), with corresponding salinities from 1.1 wt.% to 8.9 wt.% NaCl equivalent for quartz veins hosted in metasedimentary rocks, and from 230 °C to 370 °C (mode at 280 °C), with corresponding salinities from 2.9 wt.% to 10.6 wt.% NaCl equivalents for quartz veins hosted in granite. The homogenization temperatures of type-B vapor-rich inclusions in quartz veins in granite range from 310 °C to 390 °C (mode at 350 °C), with corresponding salinities from 6.7 wt.% to 12.2 wt.% NaCl equivalent. The homogenization temperatures of type-C H2O–CO2–NaCl inclusions vary from 270 °C to 405 °C (mode at 330 °C), with corresponding salinities from 1.8 wt.% to 5.6 wt.% NaCl equivalent. The original ascending ore fluid was probably CO2-bearing fluid which evolved into two phase fluid by immiscibility due to pressure drop in the mineralization channels. Furthermore, the temperature and salinities of two-phase aqueous fluids were later most likely decreased by the mixing with meteoric water. The salinities of the type-B vapor-rich inclusions are higher than those of the type-C CO2-rich inclusions, which may have resulted from CO2 separation from the fluids. The escape of gases can lead to an increase in the salinity of the residual fluids. Therefore, the main ore-forming mechanisms of the Tagu Sn–W deposit are characterized by fluid immiscibility during an early stage, and fluid mixing with meteoric water in the late stage at a lower temperature.
    Type of Medium: Online Resource
    ISSN: 2075-163X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2019
    detail.hit.zdb_id: 2655947-X
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  • 3
    In: Minerals, MDPI AG, Vol. 7, No. 7 ( 2017-07-19), p. 124-
    Abstract: Systematic exploration has delineated significant gold mineralization in the River Reef Zone and the presence of a siliceous body at Watuputih Hill, which is a Poboya gold prospect in Central Sulawesi, Indonesia. The mineralization is hosted within the Palu Metamorphic Complex. The host rocks consist of granite, biotite gneiss, and biotite schist, which is intercalated by feldspar porphyroblastic biotite schist and amphibolitic schist. The X-ray fluorescence (XRF) analysis of the granite and biotite gneiss suggests that the granitic rocks can be characterized as magnesian arc calc-alkaline rocks, with a weakly peraluminous composition. Alteration minerals were analyzed by a combination of petrographic and X-ray diffraction (XRD). In the River Reef Zone, the hydrothermal alteration zones can be sorted by their proximity to the primary fluid conduit and divided into inner, high-T, and low-T propylitic zones. In Watuputih Hill, the hydrothermal alteration can be divided into advanced argillic and argillic zones. The hydrothermal alteration assemblages indicated that the fluid was at a near-neutral pH in the River Reef Zone, whereas the fluid was acidic within Watuputih Hill. Because the hill is relatively distant from the River Reef Zone, the presence of these zones at Watuputih Hill may be indicative of another mineralization system beneath the hill.
    Type of Medium: Online Resource
    ISSN: 2075-163X
    Language: English
    Publisher: MDPI AG
    Publication Date: 2017
    detail.hit.zdb_id: 2655947-X
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