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  • MDPI AG  (3)
  • 1
    Online-Ressource
    Online-Ressource
    MDPI AG ; 2023
    In:  Catalysts Vol. 13, No. 6 ( 2023-06-09), p. 991-
    In: Catalysts, MDPI AG, Vol. 13, No. 6 ( 2023-06-09), p. 991-
    Kurzfassung: Rhodamine B (RhB) in dyes is widely used in various industries, but it poses a great threat to the natural environment and human health. In this work, a series of thermosensitive polymer materials, PNxDy, with controllable morphology and particle size were prepared by free radical polymerization using N-isopropylacrylamide and N,N-dimethylacrylamide as monomers. Then, by using PNxDy as a template, bimetallic Mn- and Co-doped MCM-41 molecular sieves with good morphology and properties were prepared by the microwave-assisted hydrothermal method. The effects of a series of thermosensitive templates on the morphology and properties of the Mn-Co-MCM-41 molecular sieve were investigated. The results demonstrated that the Mn-Co-MCM-41 by PN100D4 as a templating agent showed the best mesoporous ordering and the most regular material morphology with 2 nm nanoparticles. In addition, the molecular sieve with the best structure was selected for the RhB degradation experiments. The Mn-Co-MCM-41 with PN100D4 as the template showed regular morphology and uniform pore channels. It was applied as a catalyst for the degradation of RhB by potassium monopersulfate (PMS). The degradation rate of RhB could reach 98% with a 20 min reaction by Mn-Co-MCM-41 (PN100D4). Meanwhile, the degradation rate could be maintained at 91% after being reused six times. The bimetallic-doped Mn-Co-MCM-41 molecular sieves prepared using the thermosensitive material PN100D4 as a template have good catalytic performance and can be effectively reused.
    Materialart: Online-Ressource
    ISSN: 2073-4344
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2023
    ZDB Id: 2662126-5
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    In: Materials, MDPI AG, Vol. 15, No. 6 ( 2022-03-11), p. 2092-
    Kurzfassung: The dyeing process commonly deteriorates the luster of pre-mercerized cotton fabric, so post-mercerization processes are regularly applied to compensate for this. Herein, the influence of combining pre-mercerization with CS (caustic solution) or LA (liquid ammonia) and post-mercerization with CS or LA on the morphological structure, dyeing performance, tensile strength, and stiffness of woven cotton fabric was investigated. The crystallinity index values greatly decreased from 73.12 to 51.25, 58.73, 38.42, and 40.90% after the combined mercerization processes of LA–LA, CS–CS, LA–CS, and CS–LA, respectively. Additionally, the CS–LA- and LA–CS-treated samples exhibited a mixture of cellulose II and cellulose III allomorphs. The combined mercerization processing of cotton fabric resulted in slightly worse thermal stability. The LA and CS pre-mercerization processes increased the dye exhaustion, although the former decreased the dye fixation rate while the latter increased it by 4% for both dyes. The color strength of the dyed cotton fabric increased after both post-mercerization processes. Moreover, the fabric stiffness and mechanical properties showed an increasing trend due to the combined mercerization efforts.
    Materialart: Online-Ressource
    ISSN: 1996-1944
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2022
    ZDB Id: 2487261-1
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    In: Agronomy, MDPI AG, Vol. 13, No. 9 ( 2023-09-13), p. 2381-
    Kurzfassung: Partial substitution of synthetic nitrogen fertilizer with manure (organic substitution) is highly recommended to minimize environmental risks without compromising crop productivity in intensive agricultural systems. However, our understanding of the effect of organic substitution on soil organic carbon (OC) and total nitrogen (TN) in deep soil and its impact on crop productivity remains limited. Here we investigated OC and TN changes in soil profile down to 100 cm, crop yield, and sustainable yield index under synthetic nitrogen, phosphate, and potassium fertilizers (NPK), NPK plus straw (NPKS), and organic substitution (NPKM) treatments over two decades in four upland fields across different climate zones. Compared with the initial values, two decades of NPKM treatment significantly (p 〈 0.05) increased OC and TN stocks in either topsoil (by 25.6–103.8 and 15.8–89.8%) or deep soil (by 2.9–71.3 and 5.7–36.9%), respectively, across all sites. The increases in OC and TN stocks in 0–100 cm soil receiving NPKM were significantly higher than those receiving NPK at all sites and NPKS at three high-evaporation sites. Compared with NPKS and NPK treatments, crop yield and N uptake were significantly increased under NPKM treatment only at the Qiyang site. Furthermore, OC sequestration in the entire soil profile down to 100 cm and TN accumulation in topsoil exhibited significant positive correlations with crop N uptake, relative crop yield, and sustainable yield index. In conclusion, long-term partial substitution of synthetic N fertilizer with manure facilitates soil OC and TN sequestration in the entire 100 cm profile and thus maintains high crop productivity in upland areas.
    Materialart: Online-Ressource
    ISSN: 2073-4395
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2023
    ZDB Id: 2607043-1
    SSG: 23
    Standort Signatur Einschränkungen Verfügbarkeit
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