Note: Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Chemical Shift Scales -- 3 Basic Aspects of Nuclear Shielding -- A Magnetic Field-dependent Chemical Shifts -- B Developments in Theory -- 4 Calculations of Nuclear Shielding -- A Ab Initio Calculations -- B Semi-empirical Calculations -- 5 Transmissions of Shielding Effects within Molecules -- A Introduction -- B Inductive and Resonance Effects -- C Magnetic Anisotropy Effects -- D The Ring Current Effects -- E Electric Field Effects -- F Intramolecular Dispersion Forces -- G Steric Effects -- H Intramolecular Hydrogen-bonding -- I Isotope Shifts -- J Shielding Anisotropies -- 6 Shieldings of Particular Nuclear Species -- A Introduction -- B Proton Chemical Shifts -- C Carbon Chemical Shifts -- D Fluorine Chemical Shifts -- E Nitrogen Chemical Shifts -- F Chemical Shifts of Nuclei Other Than H, C, F, and N -- Chapter 2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Basic Theory -- A Ramsey's Equations -- B The Average Energy Approximation -- C Useful General Expressions -- D The Finite Perturbation Theory (FPT) -- E Coupling by π-Electrons -- F The Variation Method -- G SI Units -- 3 Recent Theoretical Work -- A Calculations on H2 or HD -- B Ab Initio Calculations of Coupling in Small Molecules -- C Semi-empirical Calculations -- D Theoretical Work on π-Electron Coupling -- E The Anisotropy of Electron-coupled Nuclear Spin Interactions -- F Solvent Effects on Coupling -- 4 Coupling of Directly Bonded Nuclei -- A Coupling between 13C and 1H -- B Coupling between 15N and 1H -- C Coupling between 31P and 1H -- D Coupling between 1H and Other Nuclei -- E 1J(13C13C)and 1J(13C14/15N) -- F Coupling between 13C and 31P -- G Coupling between 13C and 19F -- H 1J(13CM) where M is a Metal -- I Couplings to 19F, except 1J(19F31P) -- J Couplings between 31P and 19F. , K Other One-bond Couplings involving 31P -- 5 Coupling between Atoms Separated by Two Chemical Bonds, 2J -- A Geminal Proton-Proton Coupling across Carbon -- B Geminal Proton-Proton Coupling across Other Elements -- C 2J(13CCH) -- D Coupling of Other Elements to Hydrogen through Carbon -- E 2J(19FP19F) and 2J(19FPH) -- F 2J(19FM19F), where M is a Metal -- G 2J(19FC19F) -- H 2J(13CO31P) and 2J(13CC31P) -- I 2J(31PO31P) and 2J(31PS31P) -- J 2J(31PM31P), where M is a Metal -- K Other Two-bond Couplings -- 6 Coupling between Atoms Separated by Three Chemical Bonds, 3J -- A Coupling of Hydrogen Atoms through Two Carbon Atoms -- B 3J(HNCH) and 3J(HOCH) -- C 3J(13CCCH) -- D Coupling to Fluorine through Two Carbon Atoms. 3J(HCC19F), 3J(13CCC19F), and 3J(19FCC19F) -- E Three-bond Couplings involving 31P and 1H -- F Miscellaneous Three-bond Couplings -- 7 Coupling between Nuclei Separated by Four or More Chemical Bonds -- A Long-range Coupling between Protons -- Long-range H-H Coupling in Saturated Systems -- Long-range H-H Coupling in Unsaturated Systems -- B Long-range Couplings involving at least One Nucleus other than H -- Saturated Systems-Coupling between 1H and 19F -- Saturated Systems-Coupling between Other Nuclei -- Unsaturated Systems -- C 'Through-space' Coupling -- 8 Experimental Work of Significance for the Measurement or Interpretation of SpinSpin Coupling Constants -- A Multiple-resonance Experiments -- B Bandshape Analyses -- C Effects of Paramagnetic Materials -- D Other Experimental Techniques -- Chapter 3 Nuclear Spin Relaxation -- 1 Introduction -- 2 Nuclear Spin Relaxation in Gases -- A Introduction -- B Theoretical Developments -- C Diatomic Gases -- D Polyatomic Gases -- Pure Gases -- Stepped T1/ρ vs. ρ Plot -- CH4-O2 and CH4-NO Mixtures -- E Self-diffusion Measurements -- 3 Spin Relaxation in Liquids -- A Pure Liquids. , Molecular Rotation -- Studies of Anisotropic Rotation -- Relaxation by internal rotation of functional groups -- Relaxation in water -- Determination of nuclear quadrupole coupling constants -- Studies of Scalar Relaxation -- Relaxation in glasses and viscous liquids -- B Molecular Motion and Association in Mixtures of Liquids -- C Electrolyte Solutions -- Diamagnetic Solutions -- Paramagnetic Solutions -- D Studies of Critical Phenomena in Liquids -- E 13C Relaxation Studies -- F Methods for Selective Measurement of T1 and T2 -- 4 Spin-echo Experiments in Liquids -- A Self-diffusion Measurements -- B Spin-echo Studies of Fluid Flow -- C Carr-Purcell Spin-echo Experiments -- 5 Nuclear Spin Relaxation and Diffusion in Liquid Crystals -- A Thermotropic Liquid Crystals -- B Lyotropic Liquid Crystals -- 6 Spin Relaxation in Solids -- A N.M.R. Saturation in Solids -- B Nuclear Dipolar Relaxation -- C Relaxation by Rotational Motion -- D Spin-Lattice Relaxation by Spin-Rotational and Anisotropic Chemical Shielding Interactions -- E Spin-Lattice Relaxation due to Paramagnetic Impurities -- F Spin-Lattice Relaxation by Nuclear Quadrupole Interaction -- G Spin-Lattice Relaxation Time Measurements in Miscellaneous Solids -- Molecular Solids -- Ionic Solids -- Antiferromagnetic Solids -- Metallic Hydrides -- Hexagonal Ice -- Molecules Bound to Surfaces -- H Self-diffusion in Molecular Crystals -- I Ferroelectric Phase Transitions -- 7 Pulsed N.M.R. in Solids -- A Application of Multiple-pulse Experiments to Line-narrowing in Solids -- B Application of Multiple-pulse Experiments to the Study of Molecular Motion -- C Pulsed Double Nuclear Magnetic Resonance Experiments -- Chapter 4 Experimental Techniques -- 1 Introduction -- 2 The Magnet -- A Permanent Magnets -- B Electromagnets -- C Superconducting Magnets -- D Control of Homogeneity -- E Stability. , 3 Sensitivity -- 4 Frequency Generation -- A Single Resonance -- B Double Resonance -- Homonuclear -- Heteronuclear -- Noise -- Universal Shift Reference -- 5 The Probe -- A Single-coil Systems -- B Crossed-coil Systems -- C Double Resonance -- D Field-Frequency Lock -- E General Construction -- F Field Modulation -- G Variable-temperature Operation -- H Rapid Sample Spinning -- 6 The Preamplifier -- 7 The Receiver -- 8 Modulation Schemes -- 9 Computer Techniques -- 10 Pulsed Spectrometers -- 11 Measurement of Relaxation Times -- A Values of T1 -- C.W. Methods -- Pulse Methods -- B Values of T2 -- C.W. Methods -- Pulse Methods -- 12 Miscellaneous Topics -- A Stochastic Resonance -- B Fourier Difference Spectroscopy -- Chapter 5 Spectral Analysis -- 1 New Spin Systems Studied -- Analysis of N.M.R. Spectra of the Type [AMX]2 with J(XX') = 0 -- 2 New Methods of Tackling Known Spin Systems -- A Superoperator Direct Method Least-squares Analysis of N.M.R. Spectra -- B A Systematic Approach to the [AB]2, [AB]2MX, and Derived Systems -- C Use of Double Quantum Transitions -- Double Resonance: Perturbation of Double Quantum Transitions -- Effect of Double Irradiation (Tickling) of Single Quantum Transitions or Double Quantum Transitions in Systems Simplified by Double Resonance -- 3 Studies of Known Spin Systems -- A Systems involving Protons Only -- Aliphatic Systems -- Olefinic Systems -- Heterocyclic Systems -- Aromatic Systems -- B Compounds containing Fluorine -- 2,2'-, 3,3'-, and 4,4'-Dihalogenobiphenyl Compounds ABCD, ABCDX -- Pyridine Compounds -- Pentafluorophenol, (AM)2X -- Benzene, Naphthalene, Phenanthrene, and Biphenyl Compounds -- Tetrafluorodichlorocyclopropanes, [AX]2, A4 -- 1,1,2,2-Tetrafluoroethane [AMX]2 -- C Compounds containing Phosphorus -- Bis(dialkylphosphines) -- The [AMX18]2 System -- Tri-(3-furyl)phosphine, ABCX. , 1-Phospha-2,6-dioxacyclohexanes -- 1-Phospha-2,5-dioxa(diaza, dithia)cyclopentanes -- Bis-(5,5-dimethyl-1-phospha-2-oxo-6-thionocyclo-hexane) -- D Organometallic Compounds -- Triphenyl Group IV Element Lithium Compounds, [AB]2C -- Allenic Derivatives of Tin, Lead, and Mercury AB2X -- Cycloheptatrienyl Manganese Tricarbonyl Compounds, A[BCXY]2, ABCDEXYZ -- Aryl Derivatives of Mercury, [AB]2C, [AB]2X, [AB]2 -- 4 General Comments -- Books and Reviews -- Computer Programs -- Chapter 6 Bandshape Phenomena for Fluids -- 1 General Introduction -- A Current Developments -- B Coverage of the Report -- C Nomenclature, Notation, and Units -- D Reviews and Symposia -- 2 Experimental Features -- Miscellaneous -- 3 Exchange of Magnetic Sites -- A Theoretical Work -- B Examples of Intramolecular Exchange -- Hindered Internal Rotation -- Nitrogen Inversion -- Ring Inversion -- Phosphorus-containing Compounds -- Metal Complexes -- C Examples of Intermolecular Exchange -- Studies of Ligand Exchange (The Swift-Connick Approach) -- Other Studies of Intermolecular Exchange -- 4 Effects of Quadrupolar Nuclei -- A Theoretical Work -- B Resonance of Spin-½ nuclei Coupled to Quadrupolar Nuclei -- C N.M.R. Spectra of Quadrupolar Nuclei -- Nitrogen -- Other Nuclei -- D Effects of Magnetic Site Exchange on N.M.R. Spectra for Spin Systems containing Quadrupolar Nuclei -- 5 Relaxation Effects - Linewidths -- A Theoretical Work -- B Paramagnetic Effects -- C Gas-phase Studies -- D Miscellaneous Width Studies -- 6 Relaxation Effects-Saturation -- 7 Bandshapes in Multiple Resonance -- Cases including Exchange -- Chapter 7 Multiple Resonance -- 1 Introduction -- 2 Theory of Multiple Resonance -- 3 Double Resonance in the Presence of Chemical Exchange -- 4 Chemical Applications of Multiple-resonance Techniques -- Spin Decoupling -- Generalized Overhauser Effect -- INDOR. , Nuclear Overhauser Effect (NOE).

Note: Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Basic Aspects of Nuclear Shielding -- A General Theory -- B Basic Physical Aspects -- 3 Calculations of Nuclear Shielding -- A Introduction -- B Ab Initio Calculations -- C Empirical and Semi-empirical Calculations -- 4 Transmission of Effects within Molecules -- A Introduction -- B 'Resonance Effects', 'Inductive Effects', and 'Substituent Effects' in General -- C Magnetic Anisotropy Effects -- E Electric Field Effects -- F van der Waals and Steric Effects -- G Hydrogen Bonding Effects -- H Isotope Shifts -- 5 Shielding of Particular Nuclear Species -- A Introduction -- B Fluorine Chemical Shifts -- C Phosphorus Chemical Shifts -- D Boron Chemical Shifts -- E Silicon Chemical Shifts -- F Nitrogen Chemical Shifts -- G Chemical Shifts of other Nuclei -- 6 Conclusions -- Chapter2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Theoretical Work -- A Ab Initio Calculations -- B Semi-empirical Calculations -- C Other Topics of Theoretical Interest -- 3 Coupling of Directly Bonded Nuclei -- A Coupling to Hydrogen -- B Coupling to Elements of Groups IIIB and IVB -- C Coupling to Elements of Group VB -- D Coupling to Elements of Group VIB -- E Coupling to Elements of Group VIIB -- F Miscellaneous One-bond Couplings -- 4 Coupling between Nuclei Separated by Two Chemical Bonds, 2J -- A Geminal Proton-Proton Coupling -- B Two-bond Coupling of Other Nuclei to Protons -- C Two-bond Coupling to Carbon, Excluding 2J(13CX1H) -- D 2J(31P,29Si) -- E Coupling of Group VB and VIIB Elements to Group VB -- F Two-bond (19F,19F) Coupling -- G Miscellaneous Two-bond Couplings -- 5 Coupling between Nuclei Separated by Three Chemical Bonds, 3J -- A Vicinal Proton-Proton Coupling via Carbon 3J(1HCC1H) -- B Three-bond coupling of Protons via Other Atoms. , C Three-bond Coupling of Other Nuclei to Protons -- D Three-bond Coupling to Carbon -- E Three-bond Coupling to Phosphorus -- F Three-bond Coupling to Fluorine -- 6 Coupling between Nuclei Separated by Four Chemical Bonds, 4J -- A Proton-Proton Coupling via Carbon, 4J(1HCCC1H) -- B Four-bond Coupling of Protons via Other Atoms -- C Four-bond Coupling of Other Nuclei to Protons -- D Four-bond Coupling to Carbon -- E Four-bond Coupling to Fluorine -- A Proton-ProtonCoupling via Carbon,5J(1HCCCC1H) -- B Five-bond Proton-Proton Coupling via Other Atoms -- C Five-bond Coupling of Other Nuclei to Protons -- D Five-bond Coupling to Carbon -- E Five-bond (19F,19F) Coupling -- F 5J(195PtSiCCC19F) -- G Other Five-bond Couplings -- 8 Coupling between Nuclei Separated by Six Chemical Bonds,6J -- A Proton-Proton Coupling via Carbon, 6J(1HCCCCC1H) -- B Proton-Proton Coupling via Other Atoms -- C Six-bond Coupling of Other Nuclei to Protons -- 9 Coupling between Nuclei Separated by Seven or More Chemical Bonds -- A 7J(lH,1H) -- B 9J(1HCCCCCCCC1H) -- C nJ(19F,19F) -- n = 9-14 -- 10 Coupling in π-Electron Systems -- A Homo-aromatic Molecules -- B Annulenes -- C Heterocyclic Molecules -- D Linear Molecules -- 11 Through-space Coupling -- 12 Recent Experimental Advances -- Chapter3 Nuclear Spin Relaxation in Liquids -- 1 Introduction -- 2 Models for Molecular Rotation -- 3 Relaxation Studies in Pure Liquids -- A Proton and Deuteron Relaxation -- B 13C Relaxation -- C 29Si Relaxation -- D 207Pb Relaxation -- E Studies of Several Resonant Nuclei: 1H, 2H, 14N, 19F, 35Cl -- 4 Relaxation Studies in Liquid Mixtures of Non-electrolytes -- A Proton and Deuteron Relaxation -- B 13C Relaxation -- C Studies of Several Resonant Nuclei: 1H, 2H, 14N, 19F -- 5 Relaxation Studies in Electrolyte Solutions -- A Proton Relaxation -- B 13C Relaxation. , C Relaxation of Heavy Spin-1/2 Nuclei: 113Cd, 199Hg, 205Tl, 207Pb -- D Relaxation of Alkali-metal and Halogen Nuclei: 7Li, 23Na, 85Rb, 87Rb, 133Cs, 19F, 35Cl, 37Cl, 79Br, 81Br, 127I -- Chapter 4 Bandshape Phenomena in Liquids -- 1 Introduction -- A Recent Developments -- B Coverage of the Report -- 2 Experimental Aspects -- A Fourier Transform versus Continuous Wave Spectra -- B Resolution Enhancement -- C Magnetic Field Inhomogeneities -- 3 Exchange of Magnetic Sites -- A General Aspects -- B Intramolecular Exchange -- C Intermolecular Exchange -- D Mechanistic Studies in Inorganic Chemistry -- 4 Relaxation Effects: Linewidths -- A Theoretical Work -- B Chemical Exchange Rates Determined by the Swift-Connick Approach -- C Linewidth Determinations in Paramagnetic Systems -- D Effects of Scalar Coupling to Quadrupolar Nuclei -- Chapter5 Multiple Resonance -- 1 Introduction -- 2 Theory of Multiple Resonance -- 3 Experimental Techniques -- 4 The Nuclear Overhauser Effect -- A Intramolecular -- B Intermolecular -- 5 Chemical Applications of Multiple Resonance -- A Decoupling: Simplification and Assignment -- B Selective Irradiation Experiments: Measurements of Magnitudes and Relative Signs of Coupling Constants -- C Chemical Shift Determination -- 6 Solid-state Studies -- Chapter6 Macromolecules -- 1 Introduction -- 2 Reviews -- 3 Synthetic Macromolecules -- A 1H High-resolution N.M.R. -- B Broadline N.M.R. -- C Spin-echo N.M.R. -- D 13C N.M.R. -- E 19F N.M.R. -- 4 Biological and Related Macromolecules -- A 1H N.M.R. of Synthetic Polypeptides -- B 1H N.M.R. of Natural and Related Polypeptides and Polysaccharides -- C 1H N.M.R. of Proteins -- D 1H N.M.R. of Enzymes -- E 1H N.M.R. of Polynucleotides -- F 13C Studies -- G Other Nuclei -- 5 Small Molecules -- A 1H Studies of Hydration -- B 1H N.M.R.- General Studies -- C 13C N.M.R. Studies -- D Other Nuclei. , E Counter-ion N.M.R. -- Chapter 7 Liquid Crystals and Micellar Solutions -- 1 Introduction -- 2 Reviews -- 3 Lyotropic Liquid Crystal Phases -- A Alkyl-chain Resonances -- B Water Studies -- C Counter-ion Studies -- D Vesicle Studies -- 4 Thermotropic Liquid Crystals -- 5 Micelles -- 6 Reversed Micelles -- 7 Microemulsions and Emulsions -- Chapter 8 The Solid State -- 1 General Introduction -- 2 Half-integral Spins in Diamagnetic Solids -- A Introduction -- B Theory of the Resonance Spectrum -- C Nuclear Spin-Lattice Relaxation Theory -- D Structural Studies -- E Motional Studies (Classical Regime) -- F Quantum Effects -- G High Resolution in Solids -- H N.M.R. Image Formation -- A Introduction -- B 2H N.M.R. -- C First-row Elements -- D Second-row Elements -- E Other Nuclei -- 4 Systems with Unpaired Electrons in the Absence of Magnetic Ordering -- A Non-metallic Paramagnetic Systems -- B Metals -- C Alloys -- D Semiconductors -- E Metal Hydrides -- F One-dimensional Metals -- 5 Ordered Magnetic Materials -- A Ferromagnetic Materials -- B Antiferromagnetic Materials -- C Ferrimagnetic Materials -- 6 New Apparatus and Techniques -- A Techniques -- B Analysis -- C Sources of Error -- D Apparatus -- 7 Surface Phenomena -- A Introduction -- B Adsorption on Graphite and Charcoal -- C Adsorption on Silica -- D Adsorption on Aluminas and other Surfaces -- E Zeolites -- Chapter 9 Medium Effects -- 1 Introduction -- 2 Non-specific Medium Effects -- 3 Effects due to Specific Interactions with the Medium -- A The ASIS Effect -- B Hydrogen-bonded Systems -- C Aqueous Systems -- D Ionic Solutions -- E Micellar Aggregation -- 4 Shift Reagents -- Author Index.

Note: NM9780851862729-FX001 -- NM9780851862729-FP001 -- NM9780851862729-FP003 -- NM9780851862729-FP005 -- NM9780851862729-FP017 -- NM9780851862729-FP023 -- NM9780851862729-00001 -- NM9780851862729-00050 -- NM9780851862729-00106 -- NM9780851862729-00156 -- NM9780851862729-00181 -- NM9780851862729-00223 -- NM9780851862729-00249 -- NM9780851862729-00279 -- NM9780851862729-00311 -- NM9780851862729-00342 -- NM9780851862729-00368 -- NM9780851862729-00378 -- NM9780851862729-00408.

Note: Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Basic Aspects of Nuclear Shielding -- A General Theory -- B Basic Physical Aspects -- 3 Calculations of Nuclear Shielding -- 4 Transmission of Shielding Effects within Molecules -- A Introduction -- B Inductive Effects -- C Resonance Effects -- D Magnetic Anisotropy Effects -- E Electric Field Effects -- F The Ring-current Effect -- G Van der Waals and Steric Effects -- H Intramolecular Hydrogen Bonding -- I Isotope Shifts -- 5 Shieldings of Particular Nuclear Species -- A Introduction -- B Carbon Chemical Shifts -- C Fluorine Chemical Shifts -- D Phosphorus Chemical Shifts -- E Nitrogen Chemical Shifts -- F Chemical Shifts of Nuclei Other than H,C,F,P, and N -- 6 Chemical Shift Anisotropy -- Chapter 2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Basic Theory: Notation and Abbreviations -- A Sum-Over-States Perturbation Theory (SOS) -- B Finite Perturbation Theory (FPT) -- C Semi-empirical Molecular Orbital Methods -- D Units -- 3 Theoretical Work -- A Calculations on H2 or HD -- B Ab Initio Calculations of Coupling in Small Molecules -- C Semi-empirical Calculations -- D π-Electron Coupling -- E Nuclear-spin and Electron-spin Coupling -- F Solvent Effects -- 4 Coupling of Directly Bonded Nuclei -- A Coupling in HD -- B Coupling between 13C and 1H -- C Coupling between 15N and 1H -- D Coupling between 31P and 1H -- E Coupling between 1H and Other Nuclei -- F 1J(13C,13C), 1J(l3C,15N), 1(11B,13C), and 1J(11B,11B) -- G Coupling between 13C and 31P -- H Coupling between 13C and 19F -- I Coupling between 13C and Metals -- J Coupling to 19F, except 1J(19F,31P) and 1J(19F,13C) -- K Coupling between 31P and 19F -- L Other One-Bond Couplings involving 31P -- 5 Coupling between Nuclei Separated by Two Chemical Bonds, 2J. , A Geminal Proton-Proton Coupling across Carbon -- B Geminal Proton-Proton Coupling across Other Elements -- C 2J(13CC1H) -- D Coupling of Other Nuclei to Protons via Carbon, 2J(XC1H) -- (i) X = 199Hg -- (ii) X = 11B and 27A1 -- (iii) X = 73Ge, 119,117Sn, and 207Pb -- (iv) X = 15,14N and 31P -- (v) X = 77Se -- (vi) X = 19F -- (vii)X = 183W and 19SPt -- E 2J(19FC19F) -- F 2J(13CC13C), 2J(31PC13C), and 2J(15NC13C) -- G 2J(31PN13C) and 2/(31PN31P) -- H 2J(31PM13C), where M is a metal -- I 2J(31PM31P), where M is a Metal -- J 2J(13CO13C) and 2J(31PO13C) -- K Other Two-bond Coupling Constants -- 6 Coupling between Nuclei Separated by Three Chemical Bonds, 3J -- A Coupling of Protons via Two Carbon Atoms -- B Three-bond Coupling of Protons via Other Atoms -- C Three-bond Coupling of Carbon to Protons -- D Three-bond Coupling of Other Nuclei to Protons via Two Carbon Atoms, 3J(XCC1H) -- (i) X = 15,14N -- (ii) X = 11B and 27A1 -- E Three-bond Coupling to Fluorine via Two Carbon Atoms, 3J(XCC19F) -- (i) X = 1H -- (ii) X = 19F -- (iii) X = 15N and 199Hg -- F Three-bond Couplings between Phosphorus and Hydrogen, 3J(31PXC1H) -- (i) X = O -- (ii) X = N -- (iii) X = S -- (iv) X = a Group IVB Element -- (v) X = Au and Pt -- G 3J(13CCC31P) and 3/(13CC031P) -- H 3J(13CCC13C) -- I 3J(199HgXC1H) -- J 3J(195PtXC1H), X = N, P, and As -- K Other Three-bond Coupling Constants -- 7 Coupling between Nuclei Separated by Four Chemical Bonds, 4J -- A 4J(1HCCC1H) -- B Other Four-bond (H,H) Couplings -- C Four-bond Coupling of 13C, 14N, and 31P to 1H via Carbon Atoms -- D Four-bond Coupling of Metals to Protons -- E 4J(1HCCC19F) and 4J(19FCCC19F) -- F Other Four-bond Couplings -- 8 Coupling between Nuclei Separated by Five Chemical Bonds, 5J -- A 5J(1HCCCC1H) -- B 5J(1HCCXC1H), X = N, O, and S -- C Five-bond Coupling of 1H to 19F -- D Other Five-bond Couplings. , 9 Coupling between Nuclei Separated by Six or More Chemical Bonds -- A 6J -- B 7J and 8J -- 10 Coupling in Aromatic Systems -- A (1H,1H) Coupling in Benzenoid Aromatic Systems -- B (1H,1H) Coupling in Heteroaromatic Systems -- C Coupling in Metal-Cyclopentadienyl Compounds -- D (1H,19F) Coupling in Aromatic Systems -- E (1H,13C) Coupling in Aromatic Systems -- F (1H,31P) Coupling in Aromatic Systems -- G Coupling of Protons to Other Nuclei in Aromatic Systems -- H (13C,15N) Coupling in Aromatic Systems -- I Other Couplings in Aromatic Systems -- 11 'Through-space' Coupling -- 12 Isotope Effects -- 13 Experimental Work of Significance for the Measurement or Interpretation of Spin-Spin Coupling Constants -- A Multiple-resonance Experiments -- B Bandshape Analyses -- C Effects of Paramagnetic Materials -- D Fourier-transform Experiments -- E Other Experimental Techniques -- Chapter 3 Nuclear Spin Relaxation -- 1 Introduction -- 2 Spin Relaxation in Gases -- A Introduction -- B Theoretical Developments -- C Diatomic Molecules -- D Polyatomic Molecules -- E Spin Diffusion Measurements -- 3 Spin Relaxation in Liquids -- A Introduction -- B Pure Liquids -- Linear Molecules -- Spherically Symmetric Molecules -- Axially Symmetric Molecules -- Asymmetric Molecules -- C Internal Rotation of Methyl Groups -- D Molecular Motion and Association in Mixtures of Liquids -- Molecular Rotation Studies -- Molecular Association Studies -- Aqueous Solutions of Non-electrolytes -- Hydrogen-bonded Systems -- E Ionic Solutions -- Diamagnetic Solutions -- Paramagnetic Solutions -- F Relaxation by Translational Diffusion -- G Spin-diffusion Measurements in Liquids -- H Transverse Relaxation and Spin-echo Studies -- Spin-echo Spectroscopy -- Selective Measurement of Transverse Relaxation Rates -- Chemical Exchange Studies -- I Models for Molecular Rotation. , J Studies of Critical Phenomena in Fluids -- K 13C Relaxation Studies -- Small Molecules -- Complex Molecules -- L 15N Relaxation Studies -- M 31P Relaxation Studies -- N Determination of Spin Interaction Constants from Spin-Relaxation Measurements -- Scalar Spin-Spin Coupling Constants -- Nuclear Quadrupole Coupling Constants -- Spin-Rotation Interaction Constants and Chemical Shielding Anisotropics -- O Miscellaneous Papers -- 4 Spin Relaxation in Liquid Crystals -- A Nematic Phases -- B Cholesteric Phases -- C Isotropic Phases -- D Spin-diffusion Studies -- 5 Spin Relaxation in Solids -- A Spin-Lattice Relaxation in the Rotating Frame and Dipolar Relaxation -- B Spin-Lattice Relaxation by Anisotropic Chemical Shielding Interaction -- C Spin-Lattice Relaxation by Spin-Rotation Interaction -- D Spin-Lattice Relaxation by Nuclear Quadrupole Interaction -- E Spin-Lattice Relaxation due to Paramagnetic Impurities -- F Investigations of Molecular Reorientation -- Molecular Solids -- Internal Rotation in Molecular Solids -- Internal Rotation in Ionic Solids -- Spin-Lattice Relaxation by Quantum Mechanical Rotation at Low Temperatures -- G Investigations of Self-diffusion -- General Developments -- Metals -- Metal Hydrides -- Ionic Crystals -- Molecular Crystals -- H Studies of Molecules Bound to Solid Surfaces -- I Ferroelectric Materials -- Chapter 4 Experimental Techniques -- 1 Introduction -- 2 Probes -- A Variable Temperature -- B High Pressure -- C High Field -- 3 Frequency Generation -- 4 Pulse-sequence Generation -- 5 Continuous-wave Spectroscopy -- A Double-resonance Techniques -- B 'Other' Nuclei -- C Use of Computers -- D Relaxation Measurements -- 6 High-resolution Fourier-transform Spectroscopy -- A Introduction -- B Fourier Spectrometers -- C Relaxation Measurements -- T1 -- Spin Echoes -- D Gated Double Resonance. , E Difference Spectroscopy -- 7 General Pulsed Spectroscopy -- A Introduction -- B Spectrometers -- C Relaxation Measurements in Liquids -- T1ρ -- Spin Echoes -- T1 -- D High-resolution Studies in Solids -- Chapter 5 Spectral Analysis -- 1 Introduction -- 2 New Methods of Studying Known Spin Systems -- A Proton Spin-echo N.M.R. Spectra of 2,2-Dichloro-1,1-difluoroethane: Sub-spectral Analysis -- B Spin Hamiltonian for Twofold Symmetry -- Matrix Elements of the Hamiltonian with Symmetrized Spin Operators -- Symmetry Properties of the | A,M > -- Basis Functions -- C Double-quantum Effects in the Spectrum of 2-Bromothiazole -- D The Direct Method Applied to Nuclear Magnetic Double Resonance -- 3 Known Spin Systems -- A AB-Based N.M.R. Systems: Choice of Bounds for θ in Trigonometric Forms of Co-factors in Mixed Wave-functions -- B Systems involving Protons Only -- Saturated Acyclic Systems -- (i) n-Propyl derivatives -- [AB]2C3 -- (ii) 2,2'-Dihalogenodiethyl ethers -- [AB]2 -- Saturated Cyclic Systems -- (i) 1,3-Dioxans -- AB, AMX, ABX, [AX]2 -- (ii) D-Aldopentapyranosyl derivatives -- ABX -- (iii) N-Substituted styreneimines -- ABX -- (iv) L-Azetidine-2-carboxylic acid (L-ACA) and N-acetyl-L-azetidine-2-carboxylic acid (N-A-L-ACA) -- ABCDE -- (v) 1,2,3-Substituted prolines -- ABCDEF -- Olefinic Compounds: Dichloropentenes -- ABCDE -- Unsaturated Five-membered Ring Compounds -- (i) 3,5-Disubstituted 1,2-dihydro-furans and -thiophens -- ABX, ABXY3, ABXY2, ABC -- (ii) Dimers of cyclopentadienyl compounds -- Sesquiterpenoids -- ABX{H} -- Aromatic Systems -- Aromatic substitution patterns -- Biologically important aromatic acids -- Benzocycloheptenes -- Carbanions and Ion Pairing -- [AM]2X, AMRX, [AX]2, AA'X -- Aryldi-t-butylmethanol -- Acridine and Five Monomethyl Derivatives -- 'ABCDX' -- Sulphur Heterocycles -- syn- and anti-2-Furanaldoximes. , C Compounds containing Fluorine.

Note: Nuclear Magnetic Resonance -- Contents -- Chapter 1 Nuclear Shielding -- 1 Introduction -- 2 Basic Aspects of Nuclear Shielding -- A General Theory -- B Basic Physical Aspects -- 3 Calculations of Nuclear Shielding -- 4 Transmission of Shielding Effects within Molecules -- A Introduction -- B Inductive, Resonance, and General Substituent Effects -- C Electric Field Effects -- D Magnetic Anisotropy Effects -- E Ring-current Effects -- F van der Waals and Steric Effects -- G Intramolecular Hydrogen Bonding -- H Isotope Effects -- I Chemical Shift Anisotropy -- 5 Shieldings of Particular Nuclear Species -- A Introduction -- B Carbon Chemical Shifts -- C Fluorine Chemical Shifts -- D Phosphorus Chemical Shifts -- E Chemical Shifts of other Nuclei -- Chapter 2 Nuclear Spin-Spin Coupling -- 1 Introduction -- 2 Theoretical Work -- A Ab Initio Calculations -- B Semi-Empirical Calculations (Excluding Those on π-Electron Systems) -- C Semi-Empirical Calculations on π-Electron Systems -- D Calculations of Through-space Coupling -- E Other Topics of Theoretical Interest -- 3 Coupling of Directly-bonded Nuclei -- A Coupling to Hydrogen -- B Coupling to Elements of Groups IIIB and IVB -- C Coupling to Elements of Group VB -- D Coupling to Elements of Group VIB -- E Coupling to Elements of Group VIIB -- F Miscellaneous One-bond Couplings -- 4 Coupling between Nuclei Separated by Two Chemical Bonds, 2J -- A Geminal Proton-Proton Coupling -- B Two-bond Coupling of Other Nuclei to Protons -- C Two-bond Coupling to Carbon [Excluding 2J(13CXlH)] -- D Two-bond Coupling to Group VB Atoms -- E 2J(31PC19F) -- F Two-bond (19F,19F) Coupling -- G Miscellaneous Two-bond Couplings -- 5 Coupling between Nuclei Separated by Three Chemical Bonds, 3J -- A Vicinal Proton-Proton Coupling via Carbon, 2J(1HCC1H) -- B Three-bond Coupling of Protons via Other Atoms. , C Three-bond Coupling of Other Nuclei to Protons -- D Three-bond Coupling to Carbon -- E Three-bond Coupling to Phosphorus -- F Three-bond Coupling to Fluorine -- 6 Coupling between Nuclei Separated by Four Chemical Bonds, 4J -- A Proton-Proton Coupling via Carbon, 4J(1HCCC1H) -- B Four-bond Coupling of Protons via Other Atoms -- C Four-bond Coupling of Other Nuclei to Protons -- D Four-bond Coupling to Carbon -- E Four-bond Coupling to Fluorine -- 7 Coupling between Nuclei Separated by Five Chemical Bonds, 5J -- A Proton-Proton Coupling via Carbon, 5J(1HCCCC1H) -- B Five-bond Proton-Proton Coupling via Other Atoms -- C Five-bond Coupling of Other Nuclei to Protons -- D Five-bond Coupling to Carbon -- E Five-bond Coupling to Fluorine -- 8 Coupling between Nuclei Separated by Six Chemical Bonds, 6J -- 9 Coupling between Nuclei Separated by Seven Chemical Bonds, 7J -- 10 Coupling in π-Electron Systems -- A Homoaromatic Molecules -- B Heterocyclic Molecules -- C Annulenes -- D Linear Conjugated Systems -- 11 Through-space Coupling -- 12 Recent Experimental Advances -- Chapter 3 Nuclear Spin Relaxation in Fluids -- 1 Introduction -- 2 Theoretical Work -- 3 Relaxation Studies in Pure Liquids -- A Proton and Deuteron Relaxation -- B 13C Relaxation -- C Relaxation of Other Nuclei: 14N, 15N, 17O, 19F, 29Si, 77Se -- D Studies of Several Resonant Nuclei: 2H, 13C, 14N, 15N, ,19F -- 4 Relaxation Studies in Liquid Mixtures of Non-electrolytes -- A Proton and Deuteron Relaxation -- B 13C Relaxation -- C Studies of Several Resonant Nuclei: !H, 2H, 13C, 14N -- 5 Relaxation Studies in Electrolyte Solutions -- A Proton and Deuteron Relaxation -- B Relaxation of the Nuclei: 13C, 17O, 69Ga, 71Ga, 113Cd -- C Relaxation of Alkali-metal and Halogen Nuclei: 7Li, 23Na, 39K, 41K, 87Rb, 133Cs, 35C1, 79Br, 81Br -- 6 Relaxation Studies in Gas-Liquid Solutions. , 7 Relaxation Studies of Gases -- A Theoretical Work -- B Mono- and Di-atomic Gases -- C Polyatomic Gases -- Chapter 4 Experimental Techniques -- 1 Introduction -- 2 Diverse Applications of N.M.R. -- A General -- B Neutron Resonance and Diffraction -- C Image Formation by Zeugmatography -- 3 Temperature and Pressure Studies -- 4 Measurement of Relaxation Times -- A Systematic Errors -- B Quantization and Other Errors -- C Technique -- 5 Broad-line and Solid-state Spectroscopy -- 6 Instrumentation -- A Signal Processing -- B The Probe Area -- C The Transmitter -- D Modulation Control -- E Complete Spectrometers -- F Modification of Commercial Instruments -- 7 Miscellaneous -- Chapter 5 Spectral Analysis -- 1 Introduction -- 2 New Approaches to Known Spin Systems -- A [A]2X and ABX Systems -- B [AB]2 Systems. -- C The X-{A} indor Spectrum of the [AXn]2 Spin System -- D [[A]2Xn]2 and [ABXn]2 Spin Systems, with n = 1, 2 or 3 -- 3 More Examples of Known Spin Systems -- A Three-spin systems -- B Four-spin systems -- C Five-spin systems -- D Six-spin systems -- E Seven-spin systems -- F Eight-spin systems -- G Spin systems of nine nuclei or more -- 4 Conclusions -- Chapter 6 Bandshape Phenomena in Liquids -- 1 Introduction -- 2 General Theory -- 3 Exchange of Magnetic Sites -- A General Theory -- B Intramolecular Exchange Processes in Organic Molecules -- C Complex Rearrangements -- D Intermolecular Exchange Processes -- E Biochemical Applications -- 4 Relaxation Effects: Linewidths -- A Chemical Exchange Rates Determined by the Swift-Connick Approach -- B Linewidth Determinations in Paramagnetic Systems -- Chapter 7 Fourier Transform N.M.R. -- 1 Introduction -- 2 New Applications -- 3 Instrumentation -- A Multinuclear Spectrometers -- B Quadrature Phase Detection (QPD) -- C Solvent Elimination -- 4 Computer Simulation of Pulsed N.M.R. , A Multipulse Experiments -- B Diffusion and Field Gradient Effects -- 5 The Equivalence of Fourier and Continuous Wave Spectra -- 6 Correlation Spectroscopy -- 7 Hadamard Spectroscopy -- 8 Double Resonance in FT N.M.R. -- 9 The Measurement of Relaxation Times -- 10 Miscellaneous -- Chapter 8 Macromolecules -- 1 Introduction -- 2 Reviews -- 3 Synthetic Macromolecules -- A High-resolution 1H N.M.R. -- B Broadline N.M.R. -- C Spin-echo N.M.R. -- D 13C N.M.R. -- E Other Nuclei -- 4 Biological and Related Macromolecules -- A 1H N.M.R. of Synthetic Polypeptides -- B 1H N.M.R. of Proteins -- C 1H N.M.R. of Enzymes -- D 1H N.M.R. of Natural and Related Polypeptides and Polysaccharides -- E 1H N.M.R. of Polynucleotides -- F 13C N.M.R. -- G Other Nuclei -- 5 Small Molecules -- A 1H N.M.R.: Hydration -- B 1H N.M.R.: General Studies -- C 13C N.M.R. Studies -- D Other Nuclei -- Chapter 9 The Solid State -- 1 General Introduction -- 2 Half-integral Spins in Diamagnetic Solids -- A Introduction -- B Theoretical Aspects -- C Structural Studies (Broadline Techniques) -- D High Resolution in Solids -- E Motional Studies (Classical Regime) -- F Quantum Effects in Molecular Solids -- G N.M.R. Studies of Helium -- 3 Nuclei of Spin > -- 1/2 in Diamagnetic Solids -- A Introduction -- B 2H N.M.R. -- C The Halogen Nuclei -- D The Alkali-metal Nuclei -- E Transition-element Nuclei -- F Other Nuclei -- 4 Systems with Unpaired Electrons in the Absence of Magnetic Ordering -- A Non-metallic Paramagnetic Systems -- B Metals -- C Alloys and Intermetallic Systems -- D Hydrides -- E Semiconductors -- F One-dimensional Conductors -- 5 Ordered Magnetic Materials -- A Ferromagnetic Materials -- B Antiferromagnetic Materials -- C Ferrimagnetic Materials -- 6 New Techniques and Apparatus -- A Techniques -- B Data Analysis -- C Apparatus -- Chapter 10 Heterogeneous Systems. , 1 Introduction -- 2 Adsorption Studies -- A General -- B Cryogenic Studies -- C Zeolites -- 3 Polymers, Exchange Resins, and Gels -- 4 Protein Hydration -- 5 Cellular Systems -- 6 Membranes -- 7 Micellar Systems -- Chapter 11 Medium Effects on Chemical Shifts and Coupling Constants -- 1 Introduction -- 2 Non-specific Solvent Effects -- 3 Specific interactions with the Medium -- A General -- B Solvent Effects on Conformational Equilibria -- C The ASIS Effect -- D Hydrogen Bonding -- E Ionic Solutions -- F Micellar Systems -- 4 Shift Reagents -- A General -- B The Stoicheiometry of the Shift-reagent-Substrate Complex -- C Dipolar, Contact, and Complexation Shifts -- D Calculation of the Substrate-Shift Reagent Complex Geometry -- E Structural Assignments -- F Preferred Binding Sites -- Chapter 12 Oriented Molecules -- 1 Introduction -- 2 Structure Determination -- A Structures of Rigid Molecules -- B Corrections for Vibrational Motion -- C Molecules with Internal Motion -- 3 Determination of Indirect Couplings -- 4 Double-resonance Techniques -- 5 Order Parameters -- 6 Anisotropies in Indirect Couplings -- 7 Anisotropies in Chemical Shifts -- 8 Nuclear Quadrupole Coupling Constants -- Author Index.

Note: Organometallic Chemistry -- Contents -- Chapter 1 Group I. The Alkali and Coinage Metals -- 1 Lithium -- Structural and Bonding Studies -- Polylithio-compounds -- Halogenocarbon Derivatives -- Some Organic Reactions -- 2 Sodium and Potassium -- 3 Copper, Silver, and Gold -- Copper and Silver π-Complexes -- σ-Bonded Organo-copper and -silver Compounds -- Gold -- Chapter 2 Group II. The Alkaline Earths and Zinc and its Congeners -- 1 Beryllium -- 2 Magnesium -- Preparation and Composition -- Reactions -- Inversions and Rearrangements -- Halogenocarbon Derivatives -- 3 Calcium, Strontium, and Barium -- 4 Zinc and Cadmium -- 5 Mercury -- Preparative Reactions -- Mercuration and Demercuration Reactions -- Other Reactions -- Carbene Precursors -- Chapter 3 Group III. Boron, Aluminium, Gallium, Indium, and Thallium -- 1 Introduction -- 2 Boron -- General -- Preparations -- Radical Reactions -- Mechanisms and Kinetics -- Preparative Reactions involving Radicals -- Non-radical Mechanisms and Kinetics -- Nucleophilic Displacements at Tetrahedral Boron Centres -- Displacement of the Alkyl Groups attached to Boranes -- Olefin Elimination and Addition -- Reactions of R3B -- Organic Reactions of R3B -- Hydrido-organoboranes -- Compounds containing Boron-Nitrogen Bonds -- Borinic and Boronic Acids and their Derivatives -- Synthesis -- Reactions -- Compounds containing Boron-Chalcogen Bonds -- Compounds containing Boron-Halogen Bonds -- 3 Aluminium -- Preparations and Reactions -- Structures, Bonding, and Exchange Reactions -- Organic Applications -- Mechanisms and Kinetics -- Various Reactions -- Transition-metal-Organoaluminium Systems -- 4 Gallium -- 5 Indium -- 6 Thallium -- Trialkylthalliums-R3T1 -- Dialkylthallium and Diarylthallium Compounds-R2T1X -- Monoalkylthallium and Monoarylthallium Compounds-RT1X2 -- Organic Reactions. , Thallium(i) Cyclopentadienides -- Chapter 4 Group III. The Carboranes -- Chapter 5 Group IV. The Silicon Group -- 1 Introduction -- 2 Formation of the Carbon-Metal Bond Synthesis -- Reactions of M-C Compounds -- 3 Cleavage of the Carbon-Metal Bond -- 4 Mechanistic Studies of Carbon-Metal Bond Cleavage -- Rearrangement Reactions involving the Silicon-Carbon Bond -- 5 Thermochemical, Spectroscopic, and Structural Studies -- 6 Cyclopentadienyl Derivatives of the Group IV Elements -- 7 Addition Reactions -- 8 Alkali-metal Derivatives R3MM' -- 9 Catenation -- 10 Carbenes and their Silicon Group Congeners -- 11 Mercury Derivatives -- 12 Free Radicals -- 13 Hydrides of Silicon and Germanium -- 14 Organotin Hydrides -- 15 Boron Derivatives -- 16 Nitrogen Derivatives -- Diazo-compounds -- Azides -- Addition Reactions -- Silazanes -- Aminosilanes -- 17 Phosphine, Arsine, and Stibine Derivatives -- 18 Silicon-Oxygen Compounds -- Alkoxysilanes and Siloxanes -- Rearrangements involving Compounds containing the Si-O Bond -- Silyl Esters -- Organosilicon Peroxides -- 19 Germanium-Oxygen Compounds -- 20 Tin-Oxygen Compounds -- 21 Sulphur Derivatives -- 22 Lead-Oxygen and Lead-Halogen Compounds -- 23 Halogen Exchange Reactions -- 24 Complexes of Silicon, Germanium, Tin, and Lead -- 25 Structural Determinations -- 26 Bonding in Group IV Organometallic Compounds -- Chapter 6 Metal Carbonyls -- 1 Introduction -- 2 Spectroscopic Studies -- 3 Preparation of Carbonyl Compounds -- 4 Hydrido(carbonyl)metal Complexes -- 5 Halogeno- and Azido-(carbonyl)metal Complexes -- Chapter 7 Organometallic Compounds containing Metal-Metal Bonds -- 1 Introduction -- 2 Compounds containing Transition Metal-Transition Metal Bonds -- Compounds containing Isolated Bonds and Bond Sequences -- Transition Metal Clusters. , 3 Compounds containing Bonds between Transition Metals and the Elements of Groups IB-VB -- Group IB -- Group IIB -- Group IIIB -- Boron -- Aluminium -- Indium and Thallium -- Group IV -- General Preparative Work -- The Nature of the Metal-Metal Bond -- Titanium Group -- Chromium Group -- Manganese Group -- Iron Group -- Cobalt Group -- Nickel Group -- Group V -- 4 Compounds containing Group IIB-Group IV Element Bonds -- Chapter 8 Substitution Reactions of Metal and Organo-metal Carbonyls with Group V and VI Donor Ligands -- 1 Introduction -- 2 General Papers on Metal Carbonyl Complexes -- 3 Group V -- 4 Group VI -- Complexes of Cr°, Mo° and W° -- Halogenocarbonyl Complexes of and IIMo WII -- Cyclopentadienyl Carbonyl Complexes of MoII and WII -- 5 Group VII -- Complexes of Mn° and Re0 -- Cyclopentadienyl Carbonyl Complexes of MnI -- Other Complexes of MnI and ReI -- 6 Group VIII: Fe, Ru, and Os -- Complexes of the Cluster Carbonyls -- Mononuclear Complexes of Fe° and Ru° -- Complexes containing the M2(CO)6 Unit (M = Fe or Ru) -- Cyclopentadienyl Carbonyl Complexes of FeII -- Other Complexes of FeII, RuII, and OsII -- 7 Group VIII: Co, Rh, and Ir -- Complexes of Co0, Rh°, and Ir° -- Complexes of Co1, Rh1, and Ir1 -- 8 Group VIII: Ni, Pd, and Pt -- 9 Copper -- Chapter 9 Carbene, Nitrene, and Related Complexes -- 1 Synthesis of Carbene Complexes -- 2 Structure and Bonding in Carbene Complexes -- 3 Reactions of Carbene Complexes -- 4 Nitrene Complexes -- Chapter 10 Complexes containing Metal-Carbon σ-Bonds -- 1 σ-Bonded Complexes -- Group IV -- Group V -- Group VI -- Group VII -- Group VIII -- Group I -- 2 Compounds Derived from Carbonylmetal Anions -- 3 Insertion Reactions -- Carbon Monoxide (and Decarbonylation Reactions) -- Sulphur Dioxide -- Olefins and Acetylenes -- Tetracyanoethylene -- Isocyanides -- 4 ortho-Metallation and Related Reactions. , Nitrogen Donors -- Phosphorus Donors -- Carbon Donors -- Sulphur Ligands -- 5 Formation of M-C σ-Bonds from Olefin or Diene Complexes -- 6 Cobaloximes, Cobalamins, and Related Compounds -- 7 Organic Derivatives of Schiff-base Complexes -- Chapter 11 Hydrocarbon-Metal π-Complexes -- 1 Bonding in Mono-olefin and Acetylene Complexes -- 2 Mono-olefin Complexes -- 3 Mono-olefin Chelate Complexes -- 4 Acetylene Complexes -- 5 Acyclic Conjugated Diolefin Complexes -- 6 Cyclic Conjugated Diolefin Complexes -- Cyclobutadiene Complexes -- Cyclopentadiene Complexes -- Complexes of Six- and Seven-membered Rings -- Complexes of Eight-membered Rings -- 7 Complexes of Chelating Unconjugated Diolefins -- 8 Cationic Metal-Olefin and -Acetylene Complexes -- 9 Complexes Derived from Allenes and from Trimethyl-enemethane -- 10 Complexes of Polycyclic Hydrocarbons -- Chapter 12 π-Allylic Complexes -- 1 General Developments -- 2 Tantalum -- 3 Iron, Ruthenium, and Osmium -- 4 Cobalt, Rhodium, and Iridium -- 5 Nickel, Palladium, and Platinum -- Chapter 13 π-Cyclopentadlenyl, Arene, and Related Compounds -- 1 Introduction -- 2 π-Cyclopentadienyl Complexes -- Features of General Interest -- Group IV -- Preparation of Complexes -- Other Studies -- Group V -- Group VI -- Preparation of Complexes -- Other Studies -- Group VII -- Group VIII: Fe, Ru, and Os -- Preparation of Complexes -- Other Studies -- Group VIII: Co, Rh, and Ir -- Group VIII: Ni, Pd, and Pt -- Preparation of Complexes -- Other Studies -- Other Metals -- 3 π-Arene Complexes -- Group VI -- Preparation of Complexes -- Other Studies -- Group VII -- Group VIII: Fe, Ru, and Os -- Group VIII: Co, Rh, and Ir -- Group VIII: Ni -- Uranium -- 4 Carborane Complexes -- The [B9C211]2- Ligand and Related Systems -- Other Carborane Ligands -- Theory of Bonding in Carborane Complexes -- 5 Complexes with Other Related Ligands. , Tris(pyrazolyl)borate Complexes -- Borabenzene Complexes -- Borazole Complexes -- Pyrrole and Pyrrolyl Complexes -- Thiophen Complexes -- Chapter 14 Substitution Reactions of Hydrocarbon-Metal π-Complexes -- 1 Introduction -- 2 Results of General Interest -- 3 Individual Systems -- OC6H6)Cr(CO)3 (Benchrotrene) -- [(Tropylium)Cr(CO)3]+ and Related Complexes -- (π-C5H5)Mn(CO)3 (Cymantrene) -- (π-C4H4)Fe(CO)3 -- (π-Diene)Fe(CO)3 Complexes -- [(π-C5H5)Fe(π-C6H6)]+ Complexes -- (π-CsHs)2Co and Derived (π-C5H5)Co(π-diene) Complexes -- Cobalt-Carbon Cluster Compounds -- 4 Chemistry of the Iron-group Metallocenes (Ferrocene, Ruthenocene, and Osmocene) -- General -- General Chemistry -- Proton N.M.R. Studies -- Stereochemistry of Ferrocenes -- Biferrocenyls and Bridged Ferrocenes (Ferro-cenophanes) -- Polymeric Ferrocene Derivatives -- Ferrocene Derivatives containing Heteroatoms -- Boron -- Silicon and Germanium -- Phosphorus and Arsenic -- Sulphur -- Transition Metals -- Ferricinium Salts -- Chapter 15 Oxidative-addition and Related Reactions -- 1 Niobium and Tantalum -- 2 Chromium, Molybdenum, and Tungsten -- 3 Iron, Ruthenium, and Osmium -- 4 Cobalt, Rhodium, and Iridium -- 5 Nickel, Palladium, and Platinum -- Chapter 16 Homogeneous Catalysis -- 1 General -- 2 Hydrogenation -- 3 Isomerization -- 4 Skeletal Rearrangements -- 5 Rearrangement of Strained Cycloalkanes -- 6 Hydroformylation and Related Reactions -- 7 Dimerization and Oligomerization -- 8 Oxidation -- 9 Synthesis -- Reduction of Dinitrogen -- Chapter 17 X-Ray and Electron Diffraction Studies of Organometallic Compounds -- 1 Introduction -- Coverage -- Symbols, Abbreviations, and Conventions -- 2 Main Table Listing Compounds and Structural Data -- 3 Cross-reference Lists -- Metal Listings -- Ligand Listings -- Author Index.