ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
A hydrogen-bonded coordination supramolecule, (meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N)nickel(II) [N,N-o-phenylenebis(oxamato)-κ4O,N,N′,O′]nickelate(II) dihydrate, [Ni(C16H36N4)][Ni(C10H4N2O6)]·2H2O or [Ni(meso-cth)][Ni(opba)]·2H2O, has been prepared and characterized by X-ray crystallographic analysis. The two complex ions, i.e. [Ni(meso-cth)]2+ and [Ni(opba)]2−, are hydrogen bonded to each other, resulting in two-dimensional neutral supramolecular sheets. The sheets stack along the a direction to produce a three-dimensional architecture with one-dimensional channels in which hydrogen-bonded chains of water molecules are included.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101006849
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