ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The reaction of [RuCl(Cp)(PPh3)2] with Ag[BF4] in tetrahydrofuran, in the presence of benzylamine, leads to the mononuclear title compound [Ru(Cp)(H2NCH2Ph)(PPh3)2]BF4, where Cp is cyclopentadienyl (C5H5). The Ru atom presents a pseudo-octahedral environment with the Cp ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the P atoms of the two triphenylphosphine ligands and by the N atom of the benzylamine ligand. The [BF4]− counter-ion remains uncoordinated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801004469
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