In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 76, No. 1 ( 2020-01-01), p. 66-71
Abstract:
The complexes bis(acetylacetonato-κ 2 O , O ′)( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)manganese(II), [Mn(C 5 H 7 O 2 ) 2 (C 6 H 16 N 2 )], bis(acetylacetonato-κ 2 O , O ′)( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)iron(II), [Fe(C 5 H 7 O 2 ) 2 (C 6 H 16 N 2 )], and bis(acetylacetonato-κ 2 O , O ′)( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)zinc(II), [Zn(C 5 H 7 O 2 ) 2 (C 6 H 16 N 2 )], were synthesized from the reaction of the corresponding metal acetylacetonates [ M (acac) 2 (H 2 O) 2 ] with N , N , N ′, N ′-tetramethylethylenediamine (TMEDA) in toluene. Each of the complexes displays a central metal atom which is nearly octahedrally surrounded by two chelating acac and one chelating TMEDA ligand, resulting in an N 2 O 4 coordination set. Despite the chemical similarity of the complex units, the packing patterns for compounds 1 – 3 are different and thus the crystal structures are not isotypic.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S2056989019016372
DOI:
10.1107/S2056989019016372/wm5524sup1.cif
DOI:
10.1107/S2056989019016372/wm55241sup2.hkl
DOI:
10.1107/S2056989019016372/wm55242sup3.hkl
DOI:
10.1107/S2056989019016372/wm55243sup4.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2020
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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