In:
Acta Crystallographica Section E Crystallographic Communications, International Union of Crystallography (IUCr), Vol. 76, No. 2 ( 2020-02-01), p. 254-256
Abstract:
The structure of (μ-1κ N :2(η 2 ),κ 2 N , N ′-(2-{[2,6-bis(propan-2-yl)phenyl]azanidyl}ethyl)[2-(1 H -inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-hexaoxacyclooctadecane-1κ 6 O )lithiumtin, [LiSn(C 8 H 16 O 4 )(C 25 H 31 N 2 )], at 100 K has monoclinic ( P 2 1 / n ) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η 2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.
Type of Medium:
Online Resource
ISSN:
2056-9890
DOI:
10.1107/S205698902000047X
DOI:
10.1107/S205698902000047X/ff2165sup1.cif
DOI:
10.1107/S205698902000047X/ff2165Isup3.cdx
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2020
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
Permalink