Keywords:
Electrochemical analysis.
;
Electronic books.
Description / Table of Contents:
For more than three decades the Electroanalytical Chemistry series has delivered the most in-depth and critical research related to issues in electrochemistry. Volume 22 continues this gold-standard with practical reviews of recent applications, as well as innovative contributions from internationally respected specialists highlighting the emergence of new technologies and trends in the field. Previous volumes in the series werehighly recommended by the Journal of the American Chemical Society and consideredessential by the Journal of Solid State Electrochemistry, and this volume continues with a collection of state-of-the-art advances and studies of the highest caliber.
Type of Medium:
Online Resource
Pages:
1 online resource (333 pages)
Edition:
1st ed.
ISBN:
9780429223662
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=216111
DDC:
543/.0871
Language:
English
Note:
Cover -- Half Title -- Title Page -- Copyright Page -- Introduction to the Series -- Contributors to Volume 22 -- Table of Contents -- Contents of Other Volumes -- Looking at the Metal/Solution Interface With the Electrochemical Quartz-Crystal Microbalance: Theory and Experiment -- I. Introduction -- A. Is It Really a Microbalance? -- B. Applications of the Quartz Crystal Microbalance -- C. The Impedance Spectrum of the EQCM -- D. Outline of This Chapter -- II. Theoretical Interpretation of the QCM Response -- A. Impedance -- B. The Effect of Thin Surface Films -- C. The Quartz Crystal Operating in Contact with a Liquid -- D. Quartz Crystals with Rough Surfaces -- III. Electrical Double Layer/Electrostatic Adsorption -- A. Introduction -- B. Some Typical Results -- C. The Potential Dependence of the Frequency -- IV. Adsorption Studies -- A. The Adsorption of Organic Substances -- B. The Adsorption of Inorganic Species -- V. Metal Deposition -- A. Deposition on the Same Metal Substrate -- B. Early Stages of Metal Deposition on a Foreign Substrate -- VI. The Influence of Roughness on the Response of the QCM in Liquids -- A. The Nonelectrochemical Case -- B. The Electrochemical Case -- VII. Conclusion -- VIII. Appendix -- A. Nonuniform Film on the Surface -- B. Experimental Remarks -- References -- The Indirect Laser-Induced Temperature Jump Method for Characterizing Fast Interfacial Electron Transfer: Concept, Application, and Results -- I. Introduction -- A. Why Measure Fast Interfacial Electron Transfer Rate Constants? And How? -- B. Background -- C. The Underlying Principles of the ILIT Method-The Short Version -- D. Definition of Terms -- II. The Evolution of the ILIT Method for the Study of Fast Interfacial Electron Transfer Kinetics -- A. The Temperature-Jump Approach for Studies of Homogeneous Kinetics.
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B. The Temperature-Jump Approach for Studies of Interfacial Kinetics -- III. Relevant Electron Transfer Theory: Marcus's Description of Heterogeneous Nonadiabatic Electron Transfer Reactions -- A. Chidsey's Approach -- B. Temperature Dependence -- C. How Well Does the Butler-Volmer Expression Approximate Marcus's Formalism? -- IV. Analysis of the ILIT Response -- A. Response of the Open-Circuit Electrode Potential to a Change in the Interfacial Temperature in the Presence of a Perfectly Reversible Redox Couple Attached to the Electrode Surface -- B. The Relaxation of the ILIT Response When the Rate of Electron Transfer Is Not Infinitely Fast -- C. When Is the ILIT Response Purely Thermal (i.e., Devoid of Kinetic Information)? -- D. The Shape of the Ideal ILIT Perturbation -- E. Nonidealities of the Shape of the ILIT Perturbation and Response-Extracting the Relaxation Rate Constant, km -- F. Correlating km to Meaningful Physical Parameters -- V. Experimental Implementation of ILIT -- A. The Cell -- B. The Working Electrode: Preparation and Thermal Diffusion Properties -- C. Preparation of Self-Assembled Monolayers -- D. The Electronics -- E. Potential Problems -- F. Energetic and Timing Considerations for Single and Multiple Pulse Experiments -- G. Some Suggested Experimental Protocols -- VI. A Few Examples of Measurements of Interfacial Kinetics -- A. Some Typical Transients -- B. Determining the Value of k° -- C. Arrhenius Plots and Evaluation of ΔH≠ and ΔHλ -- VII. The Potential of the ILIT Approach -- VIII. Some Thoughts About Future Experiments -- IX. Glossary of Terms -- X. Appendix: One-Dimensional Thermal Diffusion into Two Different Phases -- References -- Electrically Conducting Diamond Thin Films: Advanced Electrode Materials For Electrochemical Technologies -- I. Introduction.
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II. Diamond Thin Film Deposition, Electrode Architectures, Substrate Materials, and Electrochemical Cells -- III. Electrical Conductivity of Diamond Electrodes -- IV. Characterization of Microcrystalline and Nanocrystalline Diamond Thin Film Electrodes -- V. Basic Electrochemical Properties of Microcrystalline and Nanocrystalline Diamond Thin Film Electrodes -- VI. Factors Affecting Electron Transfer at Diamond Electrodes -- VII. Surface Modification of Diamond Materials and Electrodes -- VIII. Electroanalytical Applications -- A. Azide Detection -- B. Trace Metal Ion Analysis -- C. Nitrite Detection -- D. NADH Detection -- E. Uric Acid Detection -- F. Histamine and Serotonin Detection -- G. Direct Electron Transfer to Heme Peptide and Peroxidase -- H. Cytochrome . Analysis -- I. Carbamate Pesticide Detection -- J. Ferrocene Analysis -- K. Aliphatic Polyamine Detection -- IX. Electrosynthesis and Electrolytic Water Purification -- X. Optically Transparent Electrodes for Spectroelectrochemistry -- XI. Advanced Electrocatalyst Support Materials -- A. Composite Electrode Fabrication and Characterization -- B. Oxygen Reduction Reaction -- C. Methanol Oxidation Reaction -- XII. Conclusions -- References -- Author Index -- Subject Index.
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