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  • IOP Publishing  (178)
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  • IOP Publishing  (178)
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  • 1
    Online Resource
    Online Resource
    IOP Publishing ; 2020
    In:  IOP Conference Series: Earth and Environmental Science Vol. 467, No. 1 ( 2020-03-01), p. 012052-
    In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, Vol. 467, No. 1 ( 2020-03-01), p. 012052-
    Abstract: CuO-CeO 2 /γ-Al 2 O 3 catalysts with different CeO 2 loadings were synthesized by wet impregnation method. Selective catalytic reduction (SCR) of NO over the two kinds of catalysts was carried out in a fixed bed reactor. CuO-CeO 2 /γ-Al 2 O 3 catalysts reached NO conversion efficiency 65% at 150 °C and maintained over 80% at 200-400 °C, The maximum efficiency is stably reached at 300 °C. CuO-CeO 2 /γ-Al 2 O 3 catalysts showed wider temperature range than that of the CuO/γ-Al 2 O 3 . NH 3 -TPD tests were carried out to study the adsorption and oxidation behavior of NH 3 over CuO-CeO 2 /γ-Al 2 O 3 catalysts with different CeO 2 loadings in the presence of oxygen. The NH 3 adsorption and activation performance were modified attributing to the modification of the Surface acidity of the CuO-CeO 2 /γ-Al 2 O 3 catalysts. The mass transfer was improved due to the promotion of the pore numbers in 8-50, 50-200μm which was another NO conversion promotion factor. Surface acidity and the pore volume decreased obviously as CeO 2 overloaded in CuO-CeO 2 /γ-Al 2 O 3 , with a negative influence of NH 3 adsorption and oxidation performance. It is considered to be the main factor of the NO conversion efficiency decreased.
    Type of Medium: Online Resource
    ISSN: 1755-1307 , 1755-1315
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2434538-6
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  • 2
    Online Resource
    Online Resource
    IOP Publishing ; 2020
    In:  IOP Conference Series: Earth and Environmental Science Vol. 508, No. 1 ( 2020-05-01), p. 012139-
    In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, Vol. 508, No. 1 ( 2020-05-01), p. 012139-
    Abstract: The simultaneous desulfurization and denitration performance of the Cu8Ce3 and Cu8Ce3S catalysts were studied in a fixed-bed reactor. The test results show that the presence of SO 2 has a poisoning effect on the denitration performance of Cu8Ce3 when the flue gas temperature is below 350°C, but this kind of toxic effect is reversible. The root cause is that the sulfate species such as CuSO 4 and Ce 2 (SO 4 ) 2 formed on the surface of Cu8Ce3S have a lower denitration activity below 350°C than CuO and CeO 2 . However, Changes in catalyst pore structure after desulfurization could not affect the amount of NH 3 adsorbed significantly. The formation of SO 4 2- on the Cu8Ce3S catalyst surface increased the number of Lewis acid sites on the catalyst surface, which improved the catalyst’s strength ability to react with NH 3 to ensure that Cu8Ce3S has a faster reaction rate than that of Cu8Ce3 above 350°C. The catalytic selectivity of Cu8Ce3S for NH 3 is better than that of Cu8Ce3 at 350-500°C, which is the fundamental reason for the improvement of denitration efficiency at high temperatures.
    Type of Medium: Online Resource
    ISSN: 1755-1307 , 1755-1315
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2434538-6
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  • 3
    Online Resource
    Online Resource
    IOP Publishing ; 2020
    In:  IOP Conference Series: Earth and Environmental Science Vol. 446, No. 2 ( 2020-02-01), p. 022068-
    In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, Vol. 446, No. 2 ( 2020-02-01), p. 022068-
    Abstract: The effects of different flue gas components such as n(NH 3 )/n(NO) ratio, SO 2 and H 2 O on the NO removing efficiency of Cu8Ce3 catalyst were studied in a fixed bed reactor. The experimental results show that the diffusion pressure and diffusion rate of NH 3 in the catalyst microporous are the main factors affecting the NO removing efficiency, when n(NH 3 )/n(NO) ratio 〈 1.05. The n(NH 3 )/n(NO) ratio no longer plays a decisive role in the denitration efficiency, when n(NH 3 )/n(NO) ratio 〉 1.05. The effect of water vapor and SO 2 on the denitration efficiency is different at 350°C and 400°C. The water vapor and NH 3 have a competitive adsorption relationship on the catalyst surface, which reduces the adsorption of NH 3 on the catalyst surface. This is the reason why the efficiency is suppressed at 350°C; the addition of water vapor can improve the surface acidity of the catalyst at 400°C, which is why the denitration efficiency is improved at this temperature. At 400°C, the adsorption rate of SO 2 on the surface of Cu8Ce3 catalyst is higher than that at 350°C. As the temperature of flue gas increases, the adsorption amount of NH 3 on the catalyst surface is reduced. This is why the denitration efficiency is depressed under the SO 2 intervention. The adsorption and oxidation efficiency of NH 3 in the sulfided catalyst at 400°C is improved, which is the main reason for the improvement of denitration efficiency at this temperature.
    Type of Medium: Online Resource
    ISSN: 1755-1307 , 1755-1315
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2434538-6
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  • 4
    Online Resource
    Online Resource
    IOP Publishing ; 2022
    In:  Nanotechnology Vol. 33, No. 38 ( 2022-09-17), p. 385703-
    In: Nanotechnology, IOP Publishing, Vol. 33, No. 38 ( 2022-09-17), p. 385703-
    Abstract: Exploring cost-effective and highly active electrocatalysts is of great significance for sustainable electrochemical NH 3 synthesis. Palladium (Pd)-based catalysts have been unanimously considered as one of the most efficient catalysts for the nitrogen reduction reaction (NRR). Herein, self-supported mesoporous Pd film with partial oxidation on Ni foam (mPd-PdO/NF) was synthesized through the micelle-assisted chemical replacement method coupled with air oxidation under 260 °C, and the mPd-PdO/NF electrocatalyst exhibited superior NRR performance with the maximum values of r NH3 (24.8 mg h −1 mg cat. −1 ) and FE (16.64%) were obtained at −0.1 V, relative to the single counterparts (mPd/NF and mPdO/NF). It is proposed that both metallic Pd and its oxide domains when co-existing with a phase boundary between them can facilitate nitrogen activation and hydrogenation, resulting in an enhanced NRR performance. This work provides an inspiring strategy for the rational design of highly active and durable metal–metal–oxide nanoarchitectonics for ammonia electrosynthesis.
    Type of Medium: Online Resource
    ISSN: 0957-4484 , 1361-6528
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 1362365-5
    SSG: 11
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  • 5
    Online Resource
    Online Resource
    IOP Publishing ; 2020
    In:  Plasma Science and Technology Vol. 22, No. 4 ( 2020-04), p. 045403-
    In: Plasma Science and Technology, IOP Publishing, Vol. 22, No. 4 ( 2020-04), p. 045403-
    Type of Medium: Online Resource
    ISSN: 1009-0630
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2240796-0
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  • 6
    In: Plasma Science and Technology, IOP Publishing, Vol. 23, No. 7 ( 2021-07-01), p. 075403-
    Abstract: In this paper, an improved air discharge fluid model under non-uniform electric field is constructed based on the plasma module COMSOL Multiphysics with artificial stability term, and the boundary conditions developed in the previous paper are applied to the calculation of photoionization rate. Based on the modified model, the characteristics of low temperature sub-atmospheric air discharge under 13 kV direct current voltage are discussed, including needle-plate and needle-needle electrode structures. Firstly, in order to verify the reliability of the model, a numerical example and an experimental verification were carried out for the modified model respectively. Both verification results show that the model can ensure the accuracy and repeatability of the calculation. Secondly, according to the calculation results of the modified model, under the same voltage and spacing, the reduced electric field under low temperature sub-atmosphere pressure is larger than that under normal temperature and atmospheric pressure. The high electric field leads to the air discharge at low temperature and sub atmospheric pressure entering the streamer initiation stage earlier, and has a faster propagation speed in the streamer development stage, which shortens the overall discharge time. Finally, the discharge characteristics of the two electrode structures are compared, and it is found that the biggest difference between them is that there is a pre-ionization region near the cathode in the needle-needle electrode structure. When the pre-ionization level reaches 10 13 cm −3 , the propagation speed of the positive streamer remains unchanged throughout the discharge process, and is no longer affected by the negative streamer. The peak value of electric field decreases with the increase of pre-ionization level, and tends to be constant during streamer propagation. Based on the previous paper, this paper constructs the air discharge model under non-uniform electric field, complements with the previous paper, and forms a relatively complete set of air discharge simulation system under low temperature and sub atmospheric pressure, which provides a certain reference for future research.
    Type of Medium: Online Resource
    ISSN: 1009-0630
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 2240796-0
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  • 7
    Online Resource
    Online Resource
    IOP Publishing ; 2020
    In:  IOP Conference Series: Materials Science and Engineering Vol. 774, No. 1 ( 2020-03-01), p. 012017-
    In: IOP Conference Series: Materials Science and Engineering, IOP Publishing, Vol. 774, No. 1 ( 2020-03-01), p. 012017-
    Abstract: The CuO/γ-Al 2 O 3 absorbent was modified by CeO 2 and NaCl, and its desulfurization performance was studied experimentally in a fixed bed reactor. The experimental results show that the adsorption capacity of sulfur dioxide is significantly improved and the adsorption saturation time of sulfur dioxide is significantly extended with CeO 2 and NaCl addition. The sulfur dioxide adsorption saturation time of the absorbent can be extended from 56 minutes to 78 minutes at 400°C, When the CeO 2 loading is 3%, and can be further extended to 104 min, with 2% CeO 2 and 5% NaCl loading. The improvement mechanism of the desulfurization performance of the modified CuO/γ-Al 2 O 3 can be attributed to the promotion of the uniform distribution of the active components in the carrier and the optimization of the pore structure of the absorbent.
    Type of Medium: Online Resource
    ISSN: 1757-8981 , 1757-899X
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2506501-4
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  • 8
    Online Resource
    Online Resource
    IOP Publishing ; 2018
    In:  IOP Conference Series: Earth and Environmental Science Vol. 170 ( 2018-07), p. 042121-
    In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, Vol. 170 ( 2018-07), p. 042121-
    Type of Medium: Online Resource
    ISSN: 1755-1307 , 1755-1315
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2018
    detail.hit.zdb_id: 2434538-6
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  • 9
    Online Resource
    Online Resource
    IOP Publishing ; 2018
    In:  IOP Conference Series: Earth and Environmental Science Vol. 170 ( 2018-07), p. 042120-
    In: IOP Conference Series: Earth and Environmental Science, IOP Publishing, Vol. 170 ( 2018-07), p. 042120-
    Type of Medium: Online Resource
    ISSN: 1755-1307 , 1755-1315
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2018
    detail.hit.zdb_id: 2434538-6
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  • 10
    Online Resource
    Online Resource
    IOP Publishing ; 2023
    In:  Chinese Physics B Vol. 32, No. 4 ( 2023-04-01), p. 048702-
    In: Chinese Physics B, IOP Publishing, Vol. 32, No. 4 ( 2023-04-01), p. 048702-
    Abstract: Terahertz time-domain spectroscopy (THz-TDS) system, as a new means of spectral analysis and detection, plays an increasingly pivotal role in basic scientific research. However, owing to the long scanning time of the traditional THz-TDS system and the complex control of the asynchronous optical scanning (ASOPS) system, which requires frequent calibration, we combine traditional THz-TDS and ASOPS systems to form a composite system and propose an all-fiber trigger signal generation method based on the time overlapping interference signal generated by the collinear motion of two laser pulses. Finally, the time-domain and frequency-domain spectra are obtained by using two independent systems in the integrated systems. It is found that the full width at half maximum (FWHM) of the time-domain spectra and the spectral width of the frequency-domain spectra are almost the same, but the sampling speed of the ASOPS system is significantly faster than that of the traditional THz-TDS system, which conduces to the study of the transient characteristics of substances.
    Type of Medium: Online Resource
    ISSN: 1674-1056
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 2412147-2
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