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  • IOP Publishing  (2)
  • 1
    In: Journal of Physics: Conference Series, IOP Publishing, Vol. 2407, No. 1 ( 2022-12-01), p. 012001-
    Abstract: To achieve high photocatalytic activity, TiO 2 nanoparticles nanoparticles require an excitation source in ultraviolet radiation. Incorporating chemical elements into the TiO 2 lattice can tune its band gap, resulting in an edge-shifted red absorption to reduce energies, improving photocatalytic performance in the visible region of the electromagnetic spectrum. In this research, TiO 2 semiconductor nanoparticles were subjected to a doping process using iron chloride (FeCl 3 ) powder to activate photocatalysis under visible light and consequently improve pollutant capture. To study the effectiveness of the doping process, the main ratios (1:1), (1:1.622) and (1:3) of TiO 2 :FeCl 3 were evaluated using Diffuse Reflectance Spectroscopy (DRS), X-ray diffraction (XRD), Fourier-Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The main results of this research show that doping TiO 2 with FeCl 3 shifted the absorption edge to longer wavelength values, changing the optical properties of the material and decreasing the band gap (E g ) of TiO 2 compared to the undoped TiO 2 (reference). There are no relevant differences between the XRD pattern of the samples with TiO 2 -FeCl 3 and TiO 2 nanoparticles (reference). The fraction of the anatase phase in doped TiO 2 nanoparticles has the same magnitude as the reference TiO 2 . Regarding FTIR, the Fe-doping process alters the TiO 2 reference spectrum, increasing the intensity of hydroxyl bonds and peaks particularly, indicating the Ti-O-Fe bond vibration.
    Type of Medium: Online Resource
    ISSN: 1742-6588 , 1742-6596
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 2166409-2
    Location Call Number Limitation Availability
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  • 2
    In: Journal of Physics: Conference Series, IOP Publishing, Vol. 2407, No. 1 ( 2022-12-01), p. 012042-
    Abstract: Thermochromic materials change their optical response to temperature reversibly. This study explores the application of thermochromism to road engineering, which is still incipient in this area, from two perspectives. The first one is about the development of functionalized road markings (FRM) working as thermochromic sensors to alert the presence of ice on the road and, in this way, to improve road safety. The second one concerns the functionalization of asphalt pavements for reversible color change at high temperatures to reduce energy absorption in the form of heat and, in this way, mitigate Urban Heat Islands (UHI) effect. For the development of the FRM, thermocapsules were added into acrylic ink, applied to an AC10 asphalt mixture, submitted to high and low temperatures, and visually characterized. For the functionalization aiming for UHI reduction, thermochromic solutions (TS) containing thermocapsules, dye, and resin were superficially sprayed at an AC10, and the Quick Ultraviolet Accelerated Weathering Test (QUV) was performed with subsequent Colorimetry Analysis, where the color coordinates defined by the Comissione Internationale de l' Éclairage (CIE) were measured. The results show that it is possible to functionalize road marks to work as a thermochromic sensor. Also, this property can be improved by synthesizing or using thermocapsules with TT closer to the water melting point. The results also indicate that the asphalt pavement functionalization with surface spraying of TS points out to higher luminosity results in terms of color coordinate, which is intended for the mitigation of heat energy absorption, consequently mitigating the UHI.
    Type of Medium: Online Resource
    ISSN: 1742-6588 , 1742-6596
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 2166409-2
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
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