In:
Journal of Physics: Conference Series, IOP Publishing, Vol. 2462, No. 1 ( 2023-03-01), p. 012052-
Kurzfassung:
Muoniated vinyl radicals can be produced by muonium (Mu) addition to triple bonds. Rhodes et al. observed a muoniated radical formed by Mu addition to trimethylsilylacetylene but were unable to determine the structure ( J. Chem. Soc., Chem. Commun. 1987 , 447). We have performed transverse field muon spin rotation measurements on trimethylsilylacetylene at 298 K and two different applied magnetic fields and observed that two types of muoniated radical were formed: a major product with muon hyperfine coupling constant (A µ ) of 587.3(1) MHz and a minor product with A µ of 570.9(5) MHz. DFT calculations show that Mu addition is preferred to the terminal carbon of the triple bond and that the two resulting radicals are isomers of the Me 3 SiĊ =CH(Mu) radical. Calculated muon hyperfine coupling constants were used to assign the observed radicals, which have Mu cis and trans to the trimethylsilyl substituent, respectively.
Materialart:
Online-Ressource
ISSN:
1742-6588
,
1742-6596
DOI:
10.1088/1742-6596/2462/1/012052
Sprache:
Unbekannt
Verlag:
IOP Publishing
Publikationsdatum:
2023
ZDB Id:
2166409-2
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