Description: Paleoclimate evidence from South America and Asia has been interpreted to indicate that tropical rainfall migrated southward during the Northern Hemisphere cooling associated with Heinrich stadial 1 (HS1), an event of massive iceberg discharge to the North Atlantic ca. 18–15 ka. Although arid conditions associated with such a shift are well documented in southern Asia, as far south as Borneo, debate still exists regarding the precipitation response in southern Indonesia and Australia during HS1. This study utilizes concentrations of the long-lived nuclide 232Th as a proxy for detrital riverine input and 230Th normalization to estimate the history of preserved fluxes reaching the seafloor in the Flores Sea, located between southern Sulawesi and the Lesser Sunda Islands, Indonesia. Because the only source of 232Th to the ocean is continental minerals, this proxy is a robust indicator of continental weathering. The 230Th normalized burial fluxes of lithogenic and biogenic matter demonstrate that both detrital and biogenic fluxes in the Flores Sea were higher during HS1 than any other period in the past 22 k.y. High detrital fluxes indicate enhanced precipitation runoff from surrounding landmasses during a period of maximum southward shift of the Intertropical Convergence Zone. This study further constrains the northern limit of enhanced rainfall associated with a southward shift of Australian monsoon-related rainfall at the time of HS1 and highlights the value of 232Th as a proxy of continental input to deep-sea sediment records.

Description: The first inter-calibration study of the stable silicon isotope composition of dissolved silicic acid in seawater, δ30Si(OH)4, is presented as a contribution to the international GEOTRACES program. Eleven laboratories from seven countries analyzed two seawater samples from the north Pacific subtropical gyre (Station ALOHA) collected at 300 m and at 1000 m water depth. Sampling depths were chosen to obtain samples with a relatively low (9 μmol L-1, 300 m) and a relatively high (113 μmol L-1, 1000 m) silicic acid concentration as sample preparation differs for low- and high- concentration samples. Data for the 1000m water sample were not normally distributed so the median is used to represent the central tendency for the two samples. Median δ30Si(OH)4 values of +1.66 ‰ for the low-concentration sample and +1.25 ‰ for the high-concentration sample were obtained. Agreement among laboratories is overall considered very good; however, small but statistically significant differences among the mean isotope values obtained by different laboratories were detected likely reflecting interlaboratory differences in chemical preparation including pre-concentration and purification methods together with different volumes of seawater volume analyzed, and the use of different mass spectrometers including the Neptune MC-ICP-MS (Thermo Fisher™, Germany), the Nu Plasma MC-ICP-MS (Nu Instruments™, Wrexham, UK), and the Finnigan™ (now Thermo Fisher™, Germany) MAT 252 IRMS. Future studies analyzing δ30Si(OH)4 in seawater should also analyze and report values for these same two reference waters in order to facilitate comparison of data generated among and within laboratories over time.