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  • GSA, Geological Society of America  (1)
  • Oxford University Press  (1)
  • 1
    Publication Date: 2017-05-17
    Description: Experimental studies have shown that temperature, pressure, sulfur fugacity (fS2), and oxygen fugacity (fO2) influence the Fe content of sphalerite. We present compositional in situ data on sphalerite from submarine volcanic-hosted massive sulfide (VHMS) ores of hydrothermal vents from different plate tectonic settings and with variable host-rock compositions. Sphalerite from sediment-hosted vents has systematically higher S contents and Fe/Zn ratios than those of the sediment-starved vents, reflecting an influence of fS2 and fO2 on Fe partitioning between fluid and sphalerite. The Fe/Zn ratios of sphalerite from sediment-starved vent systems apparently increase systematically with the fluid temperatures of the corresponding vents. We conclude that the composition of sphalerite can be used to (1) distinguish between sediment-hosted and sediment-starved hydrothermal processes, and (2) estimate minimum fluid temperatures of sphalerite precipitation from inactive sediment-starved hydrothermal vent sites and fossil VHMS deposits.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2015-03-19
    Description: There has been much recent interest in the origin of silicic magmas at spreading centres away from any possible influence of continental crust. Here we present major and trace element data for 29 glasses (and 55 whole-rocks) sampled from a 40 km segment of the South East Rift in the Manus Basin that span the full compositional continuum from basalt to rhyolite (50–75 wt % SiO 2 ). The glass data are accompanied by Sr–Nd–Pb, O and U–Th–Ra isotope data for selected samples. These overlap the ranges for published data from this part of the Manus Basin. Limited increases in Cl/K ratios with increasing SiO 2 , La–SiO 2 and Yb–SiO 2 relationships, and the oxygen isotope data rule out models in which the more silicic lavas result from partial melting of altered oceanic crust or altered oceanic gabbros. Rather, the data form a coherent array that is suggestive of closed-system fractional crystallization and this is well simulated by MELTS models run at 0·2 GPa and QFM (quartz–fayalite–magnetite buffer) with 1 wt % H 2 O, using a parental magma chosen from the basaltic glasses. Although some assimilation of altered oceanic crust or gabbro cannot be completely ruled out, there is no evidence that this plays an important role in the origin of the silicic lavas. The U-series disequilibria are dominated by 238 U and 226 Ra excesses that limit the timescale of differentiation to less than a few millennia. Overall, the data point to rapid evolution in relatively small magma lenses located near the base of thick oceanic crust; we speculate that this was coupled with relatively low rates of basaltic recharge. A similar model may be applicable to the generation of silicic magmas elsewhere in the ocean basins.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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