Description: Enhanced weathering of mafic and ultra-mafic minerals has been suggested as a strategy for carbon dioxide removal (CDR) and a contribution to achieve a balance between global CO2 sources and sinks (net zero emission). This study was designed to assess CDR by dissolution of ultramafic sand (UMS) in artificial seawater (ASW). Fine grained UMS with an olivine content of ~75% was reacted in ASW for up to 134 days at 1 bar and 21.5–23.9°C. A decline in total alkalinity (TA) was observed over the course of the experiments. This unexpected result indicates that TA removal via precipitation of cation-rich authigenic phases exceeded the production of TA induced by olivine dissolution. The TA decline was accompanied by a decrease in dissolved inorganic carbon and Ca concentrations presumably induced by CaCO3 precipitation. Temporal changes in dissolved Si, Ca, Mg, and TA concentrations observed during the experiments were evaluated by a numerical model to identify secondary mineral phases and quantify rates of authigenic phase formation. The modeling indicates that CaCO3, FeOOH and a range of Mg-Si-phases were precipitated during the experiments. Chemical analysis of precipitates and reacted UMS surfaces confirmed that these authigenic phases accumulated in the batch reactors. Nickel released during olivine dissolution, a potential toxic element for certain organisms, was incorporated in the secondary phases and is thus not a suitable proxy for dissolution rates as proposed by earlier studies. The overall reaction stoichiometry derived from lab experiments was applied in a box model simulating atmospheric CO2 uptake in a continental shelf setting induced by olivine addition. The model results indicate that CO2 uptake is reduced by a factor of 5 due to secondary mineral formation and the buffering capacity of seawater. In comparable natural settings, olivine addition may thus be a less efficient CDR method than previously believed.

Description: We estimate the maximum geothermal potential in Germany available for exploitation by operated engineered geothermal systems (EGS). To this end, we assume that (a) capabilities for creating sufficient permeability in engineered deep heat exchange systems will become available in the future and (b) it will become possible to implement multiple wells in the reservoir for extending the rock volume accessible by water circulation for increasing the heat yield. While these assumptions may be challenged as far too optimistic, they allow for testing the potential of EGS, given the required properties, in countries lacking natural steam reservoirs. With this aim, we model numerically the thermal and electric energies which may be delivered by such systems by solving coupled partial differential equations governing fluid flow and heat transport in a porous medium. Thus, our model does not represent the engineered fractures in their proper physical dimension but rather distributes their flow volume in a small region of enhanced permeability around them. By varying parameters in the subsurface, such as flow rates and well separations, we analyze the long-term performance of this engineered reservoir. For estimating the maximum achievable potential for EGS in Germany, we assume the most optimistic conditions, realizing that these are unlikely to prevail. Considering the available crystalline landmass and accounting for the competing land uses, we evaluate the overall EGS potential and compare it with that of other renewables used in Germany. Under most optimistic assumptions, the land surface available for emplacing EGS would support a maximum of 13,450 EGS plants each comprising 18 wells and delivering an average electric power of 35.3 MW e . When operated at full capacity, these systems collectively may supply 4155 TWh of electric energy in 1 year which would be roughly seven times the electric energy produced in Germany in the year 2011. Thus, our study suggests that major scientific, engineering, and financial efforts are justified for developing the drilling and stimulation technologies required for creating the permeabilities required for successful EGS. Then, EGS will have great potential for contributing towards national power production in a future powered by sustainable, decentralized energy systems.