Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Mears, C., Thomas, H., Henderson, P. B., Charette, M. A., MacIntyre, H., Dehairs, F., Monnin, C., & Mucci, A. Using Ra-226 and Ra-228 isotopes to distinguish water mass distribution in the Canadian Arctic Archipelago. Biogeosciences, 17(20), (2020): 4937-4959, doi:10.5194/bg-17-4937-2020.

Description: As a shelf-dominated basin, the Arctic Ocean and its biogeochemistry are heavily influenced by continental and riverine sources. Radium isotopes (226Ra, 228Ra, 224Ra, and 223Ra), are transferred from the sediments to seawater, making them ideal tracers of sediment–water exchange processes and ocean mixing. As the two long-lived isotopes of the radium quartet, 226Ra and 228Ra (226Ra with a t1∕2 of 1600 years and 228Ra with a t1∕2 of 5.8 years) can provide insight into the water mass compositions, distribution patterns, as well as mixing processes and their associated timescales throughout the Canadian Arctic Archipelago (CAA). The wide range of 226Ra and 228Ra activities, as well as of the 228Ra∕226Ra, measured in water samples collected during the 2015 GEOTRACES cruise, complemented by additional chemical tracers – dissolved inorganic carbon (DIC), total alkalinity (AT), barium (Ba), and the stable oxygen isotope composition of water (δ18O) – highlight the dominant biogeochemical, hydrographic, and bathymetric features of the CAA. Bathymetric features, such as the continental shelf and shallow coastal sills, are critical in modulating circulation patterns within the CAA, including the bulk flow of Pacific waters and the inhibited eastward flow of denser Atlantic waters through the CAA. Using a principal component analysis, we unravel the dominant mechanisms and apparent water mass end-members that shape the tracer distributions. We identify two distinct water masses located above and below the upper halocline layer throughout the CAA and distinctly differentiate surface waters in the eastern and western CAA. Furthermore, we highlight water exchange across 80∘ W, inferring a draw of Atlantic water (originating from Baffin Bay) into the CAA. This underscores the presence of an Atlantic water “U-turn” located at Barrow Strait, where the same water mass is seen along the northernmost edge at 80∘ W as well as along the southeasternmost confines of Lancaster Sound. Overall, this study provides a stepping stone for future research initiatives within the Canadian Arctic Archipelago, revealing how quantifying disparities in the distributions of radioactive tracers can provide valuable information on water mass distributions, flow patterns, and mixing within vulnerable areas such as the CAA.

Description: This research has been supported by Canadian GEOTRACES via NSERC-CCAR, the U.S. GEOTRACES via NSF Chemical Oceanography (grant no. OCE-1458305), and the DAAD, MOPGA-GRI (grant no.57429828).

Description: Alkalinity generation from rock weathering modulates Earth’s climate at geological time scales. Although lithology is thought to dominantly control alkalinity generation globally, the role of other first-order controls appears elusive. Particularly challenging remains the discrimination of climatic and erosional influences. Based on global observations, here we uncover the role of erosion rate in governing riverine alkalinity, accompanied by areal proportion of carbonate, mean annual temperature, catchment area, and soil regolith thickness. We show that the weathering flux to the ocean will be significantly altered by climate warming as early as 2100, by up to 68% depending on the environmental conditions, constituting a sudden feedback of ocean CO2 sequestration to climate. Interestingly, warming under a low-emissions scenario will reduce terrestrial alkalinity flux from mid-latitudes (–1.6 t(bicarbonate) a−1 km−2) until the end of the century, resulting in a reduction in CO2 sequestration, but an increase (+0.5 t(bicarbonate) a−1 km−2) from mid-latitudes is likely under a high-emissions scenario, yielding an additional CO2 sink.