Description: In this study we combine for the first time silicon (Si) isotope compositions of small mixed diatom species (δ30SibSiO2) and of large handpicked mono-generic (i.e. genus = Coscinodiscus) diatom samples (δ30SiCoscino) with diatom assemblages extracted from marine sediments in the Peruvian upwelling region in order to constrain present and past silicate utilisation. The extension of a previous core-top data set from the Peruvian shelf demonstrates that δ30SiCoscino values record near-complete Si utilisation, as these are similar to the isotopic composition of the subsurface source waters feeding the upwelling. In contrast, the δ30SibSiO2 of small mixed diatom species increase southward along the shelf as well as towards the shore. We attribute highest δ30SibSiO2 values partly to transient iron limitation but primarily to the gradual increase of Si isotope fractionation within the seasonal diatom succession, which are mainly recorded by small diatom species during intense bloom events. In contrast, lower δ30SibSiO2 values are related to initial Si isotope utilisation during periods of weak upwelling, when low Si(OH)4 concentrations do not permit intense blooms and small diatom species record substantially lower δ30Si signatures. As such, we propose that the intensity of the upwelling can be deduced from the offset between δ30SibSiO2 and δ30SiCoscino (Δ30Sicoscino–bSiO2), which is low for strong upwelling conditions and high for prevailing weak upwelling. We apply the information extracted from surface sediments to generate a record of the present-day main upwelling region covering the past 17,700 years and find that this location has also been characterized by a persistent offset (Δ30Sicoscino–bSiO2). By comparison with the diatom assemblages we show that the coastal upwelling system changed markedly between weak and strong upwelling conditions. In addition, our model calculations to quantify species-specific Si isotope fractionation effects based on the diatom assemblages indicate an overall minor influence that cannot explain the high amplitude in the measured δ30SibSiO2 record.

Description: The Weddell Sea sector is one of the main formation sites for Antarctic Bottom Water and an outlet for about one fifth of Antarctica’s continental ice volume. Over the last few decades, studies on glacialegeological records in this sector have provided conflicting reconstructions of changes in ice-sheet extent and ice-sheet thickness since the Last Glacial Maximum (LGM at ca 23e19 calibrated kiloyears before present, cal ka BP). Terrestrial geomorphological records and exposure ages obtained from rocks in the hinterland of the Weddell Sea, ice-sheet thickness constraints from ice cores and some radiocarbon dates on offshore sediments were interpreted to indicate no significant ice thickening and locally restricted grounding-line advance at the LGM. Other marine geological and geophysical studies concluded that subglacial bedforms mapped on theWeddell Sea continental shelf, subglacial deposits and sediments over-compacted by overriding ice recovered in cores, and the few available radiocarbon ages from marine sediments are consistent with major ice-sheet advance at the LGM. Reflecting the geological interpretations, different icesheet models have reconstructed conflicting LGM ice-sheet configurations for the Weddell Sea sector. Consequently, the estimated contributions of ice-sheet build-up in the Weddell Sea sector to the LGM sealevel low-stand of w130 m vary considerably. In this paper, we summarise and review the geological records of past ice-sheet margins and past icesheet elevations in the Weddell Sea sector. We compile marine and terrestrial chronological data constraining former ice-sheet size, thereby highlighting different levels of certainty, and present two alternative scenarios of the LGM ice-sheet configuration, including time-slice reconstructions for post- LGM grounding-line retreat. Moreover, we discuss consistencies and possible reasons for inconsistencies between the various reconstructions and propose objectives for future research. The aim of our study is to provide two alternative interpretations of glacialegeological datasets on Antarctic Ice- Sheet History for the Weddell Sea sector, which can be utilised to test and improve numerical icesheet models

Description: Temperature changes in Antarctica over the last millennium are investigated using proxy records, a set of simulations driven by natural and anthropogenic forcings and one simulation with data assimilation. Over Antarctica, a long term cooling trend in annual mean is simulated during the period 1000-1850. The main contributor to this cooling trend is the volcanic forcing, astronomical forcing playing a dominant role at seasonal timescale. Since 1850, all the models produce an Antarctic warming in response to the increase in greenhouse gas concentrations. We present a composite of Antarctic temperature, calculated by averaging seven temperature records derived from isotope measurements in ice cores. This simple approach is supported by the coherency displayed between model results at these data grid points and Antarctic mean temperature. The composite shows a weak multi-centennial cooling trend during the pre-industrial period and a warming after 1850 that is broadly consistent with model results. In both data and simulations, large regional variations are superimposed on this common signal, at decadal to centennial timescales. The model results appear spatially more consistent than ice core records. We conclude that more records are needed to resolve the complex spatial distribution of Antarctic temperature variations during the last millennium.