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  • EJournal Publishing  (2)
  • 1
    Online Resource
    Online Resource
    EJournal Publishing ; 2023
    In:  International Journal of Environmental Science and Development Vol. 14, No. 4 ( 2023), p. 265-270
    In: International Journal of Environmental Science and Development, EJournal Publishing, Vol. 14, No. 4 ( 2023), p. 265-270
    Abstract: Acid mine drainage (AMD) is one of the biggest issues faced by the mining and mineral processing industries in terms of removing heavy metals from the effluents. The present study investigated the effects of glyoxylic acid, hydrazine and dimethylamine borane as reducing agents and the effect of using Ni, Fe, basic oxygen furnace slag (BOFS) and granulated blast furnace slag (GBFS) as seeding materials to remove metals from acidic effluents respectively. The experiments were conducted using acidic mine effluent in a 0.5 L batch reactor using different seeding materials and reducing agents respectively. The study is the first of its kind to examine and compare all four seeding materials using different reducing agents respectively. X-ray diffraction (XRD) patterns, scanning electron microscope (SEM), and a Fourier Transform Infrared (FTIR) spectrometer were used to analyse the seeding material before and after Electroless plating.. The study suggests that BOFS is a effective seed together with hydrazine reducing agent that yielded a 99.9% removal of Fe (III), whilst Ni and Fe powder failed to seed effectively. During reduction precipitation, nucleation and breakage were identified as the predominant particulate processes based on particle size distribution (PSD) evolution and its moments. There were significant mineral phases formed, such as bownmillerites Ca2(Al, Fe)2O5, which formed by replacing Si with Al and Fe in all tetrahedral coordinations between Al, Fe and Si, suggesting chemisorption being a dominant mechanism.
    Type of Medium: Online Resource
    ISSN: 2010-0264
    Language: Unknown
    Publisher: EJournal Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 2715487-7
    Location Call Number Limitation Availability
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  • 2
    Online Resource
    Online Resource
    EJournal Publishing ; 2022
    In:  International Journal of Environmental Science and Development Vol. 13, No. 5 ( 2022), p. 170-175
    In: International Journal of Environmental Science and Development, EJournal Publishing, Vol. 13, No. 5 ( 2022), p. 170-175
    Abstract: In the current study, fly ash modified basic oxygen furnace slag geopolymers were synthesized and used as geofilters to remove heavy metals from wastewater. Batch experiment based on the removal of heavy metals from synthesized wastewater was conducted so as to investigate the influence of contact time and porosity on the metal removal efficiency and adsorption capacity of the geofilters. Adsorption kinetics was evaluated using Lagergren's pseudo-first-order model, Ho's pseudo-second order and Elovich models. Effect of contact time between geopolymer and wastewater was investigated within the first 15 minutes of adsorption with time interval of 3 minutes. The highest percentages for the removal of Fe2+, Cu2+, Al3+ and Ni2+ions with 1%H2O2 – FA-BOFS based geopolymer obtained after 15minutes were 100%, 86.87%, 84.64% and 84.63% respectively. The trend based on metal absorption capacities in an ascending order given as Fe 〉 Cu 〉 Ni 〉 Al. The adsorption capacity of metal within the 15miniutes was relatively constant possibly due to sufficient number of sites upon which metal ion adsorption may have possibly occurred on the outer surface of geopolymers irrespective of H2O2 content. Metal ion adsorption rates in the current study strongly adhered to the Ho's pseudo-second-order model based on linear regression fitting method. The correlation coefficients R2 were 0.999. FA-BOFS based geopolymer can be considered as emergent and versatile material with inherent chemical microstructural property able to remove heavy metals from polluted effluent and metalliferous drainage.
    Type of Medium: Online Resource
    ISSN: 2010-0264
    Language: Unknown
    Publisher: EJournal Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 2715487-7
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
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