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  • Croatian Chemical Society  (1)
  • Geologisches Institut, CAU Kiel  (1)
  • 1
    Publication Date: 2017-03-23
    Description: Under the EC sponsored research project ODER (Oder Discharge-Environmental Response) first investigations have been carried out to estimate the chlorinated biphenyls (CB) input into Oderhaff via the Oder river. For this purpose, vertical profiles of CB content and composition were analysed on samples of three sediment cores. In two water samples, the content of suspended particulate material as weil as the particulate CB content and congener-specific composition were measured. In the Oderhaff the CB concentrations of particulate material were between 700 to 800 pg/dm3. Significant differences in the composition of the components were not observed. In sediments, CB contents were as high as 17 to 24 ngig dry weight in near surface sediment layers. They decreased with increasing sediment depth and were below detection limits at 15 to 21 cm depth. Based on the size of the 49 accumulation area and related hydrographic conditions, we estimated an input of 95 kg into the Oderhaff for the last 65 years since the onset of CB production. Applying the present prevailing conditions, we calculated an average transport of about 825 kg CB by the Oder river during this period. Comparing these two estimates, we observed that at least 15 % of the CB transported by the Oder river was deposited in the Oderhaff. The remaining 85 % (-730 kg), have been further transported into the South Pomeranian Bight and Southern Baltic Sea.
    Type: Article , NonPeerReviewed
    Format: text
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  • 2
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    Croatian Chemical Society
    In:  Croatica Chemica Acta, 70 (1). pp. 309-321.
    Publication Date: 2019-09-23
    Description: Individual chlorobiphenyls (CBs) and p,p'-DDE were determined in solution and suspension in surface transects of the open Mediterranean Sea in 1987. Large volumes of sea water (1400—1700 dm3) were analyzed. Concentrations of CBs were low in solution (〈5 pg/dm3) and in suspension (〈60 pg/dm3). Values for their sum (XCB) were 1.7-43.9 and 190-615 pg/dm3, respectively. Compositions of the CB mixtures in solution as well as those in suspension were very similar in the various transects, but considerable differences were present between solution and suspension in each transect. It was attempted to interpret these differences in terms of molecular characteristics (octanol-water distribution coefficients, Kaw). The resulting plots of log Kovl vs. the apparent distribution coefficient (log K&) gave evidence for the uptake of CBs by suspended particles, followed by sedimentation out of the surface layer. Concentrations in solution were much lower (1-2 orders of magnitude) than those reported before. This may result from improvements in the sampling and analytical techniques. No clear evidence for significant local sources of these compounds was detected in the surface waters, as the levels in solution were very similar to the very low concentrations in the adjacent open Atlantic.
    Type: Article , PeerReviewed
    Format: text
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