Note: Intro -- Preface -- Contents -- Transition Metal-Mediated and Metal-Catalyzed Carbon-Fluorine Bond Formation -- 1 Introduction -- 2 C(sp3)-F Bond Formation -- 2.1 Nucleophilic Fluorination Reactions -- 2.1.1 Allylic Fluoride Synthesis -- 2.1.2 Hydrofluorination of Epoxides and Aziridines -- 2.1.3 Nucleophilic Substitution of Alkyl Halides and Pseudohalides -- 2.2 Electrophilic Fluorination Reactions -- 2.2.1 Reactions Proposed to Proceed via Two-Electron Pathways -- 2.2.2 Reactions Proposed to Proceed via One-Electron Pathways -- Fluorination of C-H Bonds -- Decarboxylative Fluorination -- Fluorofunctionalization of Alkenes -- 2.3 Oxidative Fluorination with Fluoride -- 3 C(sp2)-F Bond Formation -- 3.1 Nucleophilic Arene Fluorination -- 3.2 Electrophilic Arene Fluorination -- 3.2.1 Reactions Proposed to Proceed via Two-Electron Pathways -- 3.2.2 Reactions Proposed to Proceed via One-Electron Pathways -- 3.3 Oxidative Arene Fluorination with Fluoride -- 3.4 Alkenyl Fluoride Synthesis -- 4 Outlook -- References -- Activation and Formation of Aromatic C-F Bonds -- 1 Introduction -- 2 Aryl C-F Bond Formation -- 3 Electrophilic Fluorination -- 3.1 Organomagnesium and Organolithium Reagents -- 3.2 Organosilicon Reagents -- 3.3 Organoboron Reagents -- 3.4 Organotin Reagents -- 3.5 Electrophilic Fluorination with Transition Metals -- 4 Nucleophilic Fluorination -- 4.1 Nucleophilic Fluorination with Transition Metals -- 4.1.1 Group 10: Palladium and Platinum -- 4.1.2 Group 11: Copper -- 5 Alternative Methods -- 5.1 Nucleophilic Deoxyfluorination -- 5.2 Phase Transfer Catalysis -- 5.3 Photocatalytic Fluorination -- 6 Aryl C-F Activation -- 7 Early Transition Metals -- 7.1 Group 3, Lanthanides and Actinides -- 7.2 Group 4 -- 7.2.1 Titanium -- Stoichiometric Examples -- Catalytic Examples -- 7.2.2 Zirconium -- Stoichiometric Examples -- Catalytic Examples. , 7.3 Other Early Transition Metal Examples -- 7.3.1 Hafnium -- 8 Late Transition Metals -- 8.1 Group 7 -- 8.1.1 Manganese -- 8.2 Group 8 -- 8.2.1 Iron -- 8.2.2 Ruthenium -- 8.3 Group 9 -- 8.3.1 Cobalt -- 8.3.2 Rhodium -- Stoichiometric Examples -- Catalytic Examples -- 8.3.3 Iridium -- 8.4 Group 10 -- 8.4.1 Nickel -- Stoichiometric Examples -- Catalytic Examples -- 8.4.2 Palladium -- Stoichiometric Examples -- Catalytic Examples -- 8.4.3 Platinum -- Stoichiometric Examples -- Catalytic Examples -- 8.5 Group 11 -- 8.5.1 Copper -- 8.5.2 Gold -- 8.6 Transition Metal-Free Processes -- 9 Main Group Elements -- 10 Summary and Outlook -- References -- Transition-Metal-Catalyzed Difluoromethylation, Difluoromethylenation, and Polydifluoromethylenation Reactions -- 1 Introduction -- 2 Syntheses of Transition-Metal-Difluoromethyl Complexes -- 2.1 Metal-Catalyzed Methods for Difluoromethylation and Difluoromethylenation -- 3 Polydifluoromethylenation -- 3.1 Transition-Metal-Mediated Polydifluoromethylenation -- Summary, Conclusions, and Outlook -- References -- Hydrodefluorination Reactions Catalyzed by Transition-Metal Complexes -- 1 Introduction -- 2 General Consideration of Metal-Fluorine Bond Formation in HDF -- 3 Transition-Metal-Catalyzed HDF Reactions -- 4 Conclusion -- References -- Catalytic Transformations of Fluorinated Olefins -- 1 Introduction -- 2 Transition-Metal-Catalyzed Oligomerization of Fluorinated Olefins -- 2.1 Chromium(0)-Catalyzed Oligomerization of Hexafluoropropylene -- 3 Transition-Metal-Catalyzed Hydrodefluorination of Fluorinated Olefins -- 3.1 Group 4 Metal Catalyst -- 3.2 Group 8 Metal Catalyst -- 3.2.1 Iron-Catalyzed Hydrodefluorination of Hexafluoropropylene -- 3.2.2 Osmium-Catalyzed Hydrodefluorination of Vinyl Fluoride and Vinylidene Fluoride -- 3.3 Group 9 Metal Catalyst. , 4 Transition-Metal-Catalyzed C-X Bond Formation Reactions via C-F Bond Activation of Fluorinated Olefins -- 4.1 Group 9 Metal Catalyst -- 5 Transition-Metal-Catalyzed C-C Bond Formation Reactions via C-F Bond Activation of Perfluorinated Olefins -- 5.1 Group 10 Metal Catalyst -- 5.1.1 Palladium-Catalyzed C-C Bond Formation Reactions via an ``Atypical´´ Mizoroki-Heck-Type Coupling Reaction -- 5.1.2 Palladium-Catalyzed Negishi-Type Cross-Coupling Reaction with Gem-Difluoroalkene -- 5.1.3 Palladium-Catalyzed Negishi-Type Cross-Coupling Reaction with Tetrafluoroethylene -- 5.1.4 Palladium-Catalyzed Base-Free Suzuki-Miyaura-Type Cross-Coupling Reaction with Tetrafluoroethylene -- 5.1.5 Palladium-Catalyzed Base-Free Hiyama-Type Cross-Coupling Reaction with Tetrafluoroethylene -- 5.2 Group 11 Metal Catalyst -- 5.2.1 Copper-Catalyzed C-C Bond Formation Reactions via a Highly Stereoselective Addition-Elimination Reaction with Grignard R... -- References -- Fluorous Organometallic Chemistry -- 1 Introduction -- 2 Organometallic Complexes with Ancillary Fluorous Ligands -- 3 Organometallic Complexes with Fluorous Organic Ligands -- 3.1 Cyclopentadienyl Metal Complexes -- 3.2 Other pi-Ligands -- 3.3 Alkyl and Aryl Metal Complexes -- 3.4 NHC Metal Complexes -- 4 Conclusions and Future Prospects -- References -- Index.