Anmerkung: Intro -- Preface -- Contents -- Contributors -- Chapter 1: Role of Nano-photocatalysis in Heavy Metal Detoxification -- 1.1 Introduction -- 1.2 Heavy Metals and Their Toxicological Effects -- 1.2.1 Cadmium -- 1.2.2 Chromium -- 1.2.3 Copper -- 1.2.4 Lead -- 1.2.5 Mercury -- 1.2.6 Nickel -- 1.2.7 Zinc -- 1.3 Overview of Photocatalysis -- 1.4 Mechanism of Photocatalysis -- 1.5 Types of Photocatalysis -- 1.5.1 Homogeneous Photocatalysis -- 1.5.2 Heterogeneous Photocatalysis -- 1.6 Overview and Mechanism of Nano-photocatalysis -- 1.7 Photocatalytic Nanoparticle Synthesis -- 1.7.1 Organic Synthesis -- 1.7.1.1 Plant Extracts Aqueous Solutions -- 1.7.1.2 Microorganisms -- 1.7.2 Chemical Synthesis -- 1.7.2.1 Sol-Gel Method -- 1.7.2.2 Hydrothermal Method -- 1.7.2.3 Polyol Synthesis -- 1.7.2.4 Precipitation Method -- 1.7.3 Physical Synthesis -- 1.7.3.1 Ball Milling -- 1.7.3.2 Melt Mixing -- 1.7.3.3 Physical Vapour Deposition (PVD) -- 1.7.3.4 Laser Ablation -- 1.7.3.5 Sputter Deposition -- 1.8 Mode of Operation on Nano-photocatalysis -- 1.9 Parameters Affecting the Photocatalytic Efficiency -- 1.9.1 Effect of pH of the Reaction Solution -- 1.9.2 Effect of Photocatalyst Concentration -- 1.9.3 Effect of Substrate Adsorption -- 1.9.4 Effect of Dissolved Oxygen -- 1.10 Application -- 1.10.1 Chromium -- 1.10.1.1 pH -- 1.10.1.2 Light Intensity -- 1.10.1.3 Photocatalyst Dosage -- 1.10.1.4 Presence of Organic Compounds -- 1.10.2 Mercury -- 1.10.3 Arsenic -- 1.10.4 Uranium -- 1.11 Disadvantages of Photocatalysis -- 1.12 Photocatalyst Modifications -- 1.12.1 Dye Sensitization -- 1.12.2 Ion Doping -- 1.12.3 Composite Semiconductor -- 1.13 Conclusion -- References -- Chapter 2: Solar Photocatalysis Applications to Antibiotic Degradation in Aquatic Systems -- 2.1 Introduction -- 2.2 Solar Photocatalysis Process. , 2.3 Solar Photocatalysis Treatment for Antibiotic Degradation -- 2.3.1 Trimethoprim -- 2.3.2 Sulfamethoxazole -- 2.3.3 Erythromycin -- 2.3.4 Ciprofloxacin -- 2.4 Conclusions -- References -- Chapter 3: Biomass-Based Photocatalysts for Environmental Applications -- 3.1 Introduction -- 3.2 Background of Biomass-Derived Carbon -- 3.2.1 Biochar -- 3.2.2 Activated Carbon (AC) -- 3.3 Synthesis Methods of Biomass-Derived Carbon -- 3.3.1 Pyrolysis -- 3.3.2 Hydrothermal Carbonization -- 3.3.3 Physical and Chemical Activation -- 3.4 Photocatalysts and Photocatalysis Reactions -- 3.5 Functionalized AC and Applications -- 3.5.1 Types of Functionalized AC -- 3.5.2 Functionalized AC Photocatalysts and Its Application -- 3.6 Future Challenges and Conclusions -- References -- Chapter 4: Application of Bismuth-Based Photocatalysts in Environmental Protection -- 4.1 Introduction -- 4.2 Photocatalytic Oxidation of Pharmaceuticals in Water -- 4.2.1 Tetracycline -- 4.2.2 Ciprofloxacin and Other Antibiotics -- 4.2.3 Carbamazepine -- 4.2.4 Ibuprofen and Diclofenac -- 4.2.5 Other Pharmaceuticals -- 4.3 Photocatalytic Oxidation of Industrial Micropollutants -- 4.3.1 Bisphenol A -- 4.3.2 Oxidation of Other Industrial Pollutants -- 4.4 Oxidation of the Indoor Air Pollutant NOx -- 4.5 Photocatalytic Reduction of Pollutants in Water and Air -- 4.5.1 Reduction of Cr(VI) in Water -- 4.5.2 Reduction of CO2 in Air -- 4.6 Water Splitting -- 4.7 Conclusions -- References -- Chapter 5: Phosphors-Based Photocatalysts for Wastewater Treatment -- 5.1 Introduction -- 5.2 Phosphor Materials: A Historical Background -- 5.3 Inorganic Phosphors in Photocatalysis -- 5.3.1 Types of Inorganic Phosphor Materials -- 5.3.2 Down-Conversion Phosphors in Photocatalysis -- 5.3.3 Up-Conversion Phosphors in Photocatalysis -- 5.3.4 Long-Persistent Phosphors in Photocatalysis. , 5.4 Organic Up-Conversion Phosphors in Photocatalysis -- References -- Chapter 6: Nanocarbons-Supported and Polymers-Supported Titanium Dioxide Nanostructures as Efficient Photocatalysts for Remedi... -- 6.1 Introduction -- 6.1.1 Heterogeneous Semiconductor Photocatalysis -- 6.1.2 Potential TiO2-Based Photocatalysts -- 6.1.3 Limitations of the Fine Powder Form of TiO2-Based Photocatalysts -- 6.1.3.1 Comparison of Synthesis Methods -- 6.1.3.2 Improvements in TiO2 Performance by Structural Change, Doping, and Hybridization -- 6.2 TiO2 Photocatalysts with Polymer-Based Hybrid Photocatalysts for Wastewater Treatment -- 6.2.1 Need for Immobilization of TiO2-Based Photocatalysts -- 6.2.1.1 Features of a Stable Substrate, and Available Substrates -- 6.2.1.2 Comparison of Polymeric Supports for Wastewater Treatment -- 6.3 TiO2 Photocatalysts Supported with Nanocarbons for Wastewater Treatment -- 6.3.1 TiO2-Functionalized Nanocarbon-Based Photocatalysts -- 6.3.1.1 Potential Photocatalytic Improvements with Carbon Nanostructures for Wastewater Treatment -- 6.4 Conclusions and Future Outlook -- References -- Chapter 7: Investigation in Sono-photocatalysis Process Using Doped Catalyst and Ferrite Nanoparticles for Wastewater Treatment -- 7.1 Introduction -- 7.2 Dependency of Catalytic Activity -- 7.2.1 Size-Dependent Catalytic Activity -- 7.2.2 Shape-Dependent Catalytic Effect -- 7.2.3 Interparticle Distance-Dependent Catalytic Effect -- 7.2.4 Support Interaction and Charge Transfer-Dependent Reactivity -- 7.3 Type of Nanoparticles -- 7.3.1 Non-metallic Nanoparticles -- 7.3.2 Metallic Nanoparticles -- 7.3.3 Semiconductor Nanoparticles -- 7.3.4 Ceramic Nanoparticles -- 7.3.5 Polymer Nanoparticles -- 7.3.6 Lipid-Based Nanoparticles -- 7.4 Types of Nanoparticles Based on Structure -- 7.5 Synthesis and Applications -- 7.5.1 Discussions -- 7.6 Synergetic Effect. , 7.7 Conclusion and Overview -- References -- Chapter 8: Magnetic-Based Photocatalyst for Antibacterial Application and Catalytic Performance -- 8.1 Introduction -- 8.2 Magnetic-Based Photocatalysts in Inactivation of the Microorganism -- 8.3 Factors Affecting the Photocatalytic Bacterial Inactivation -- 8.3.1 Effect of Magnetic-Based Photocatalyst Concentration and Light Intensity -- 8.3.2 Nature of Microorganism -- 8.3.3 Solution pH of Magnetic-Based Photocatalyst Suspension -- 8.3.4 Initial Bacterial Concentration -- 8.3.5 Physiological State of Bacteria -- 8.4 Proposed Mechanism for Bacteria Disinfection by the Magnetic-Based Photocatalyst -- 8.5 Using Magnetic-Based Catalyst in Photocatalytic Abatement of Organics -- 8.6 Photocatalysis for the Simultaneous Treatment of Bacteria and Organics -- 8.7 Conclusion and Future Prospects -- References -- Chapter 9: Antimicrobial Activities of Photocatalysts for Water Disinfection -- 9.1 Introduction -- 9.2 Mechanisms of Photocatalytic Disinfection -- 9.3 Pure and Modified Photocatalysts -- 9.4 Photocatalytic Films and Biofilms -- 9.5 Photocatalytic Composites and Nanocomposites -- 9.6 Materials with Antimicrobial Activity in the Absence of Light -- 9.7 Case Study: Application of Supported Photocatalysts in Disinfection of Whey-Processing Water -- 9.8 Final Considerations -- References -- Chapter 10: Medicinal Applications of Photocatalysts -- 10.1 Introduction -- 10.1.1 Background -- 10.2 Antifungal Activity -- 10.3 Virucidal Activity -- 10.4 Antimicrobial Activity -- 10.5 Anticancer Activity -- 10.6 Conclusion -- References -- Index.

Anmerkung: Intro -- Contents -- 1 Chemical Valorization of CO2 -- Abstract -- 1 Introduction -- 2 CO2-Derived Fuels and Chemicals -- 2.1 Methane -- 2.2 Methanol -- 2.3 Dimethyl Ether -- 2.4 Formic Acid -- 2.5 Ethanol -- 2.6 CO2-Fischer-Tropsch Liquid Fuels -- 2.7 Carbon Monoxide-Syngas -- 3 CO2 Chemically Derived Materials -- 3.1 Polymers -- 3.2 CO2-Derived Building Materials -- 4 Conclusions -- References -- 2 Progress in Catalysts for CO2 Reforming -- Abstract -- 1 Introduction -- 2 Technologies for Capturing and Storing Carbon Dioxide -- 3 Technologies for Using Carbon Dioxide -- 4 Methane Dry Reforming Process -- 4.1 Progress in Catalysts for Methane Dry Reforming (1928-1989) -- 4.2 Progress in Catalysts for Methane Dry Reforming (1990-1999) -- 4.3 Progress in Catalysts for Methane Dry Reforming (2000-2009) -- 4.4 Progress in Catalysts for Methane Dry Reforming (2010-2019) -- 4.5 Current Status in the Catalysts for Methane Dry Reforming -- 5 Dry Reforming of Other Compounds -- 6 Use of Steam or Oxygen in Dry Reforming of Methane and Other Compounds -- 7 Solid Oxide Fuel Cells Fueled with Biogas -- 8 Commercialization of Dry Reforming Process -- 9 Conclusions -- References -- 3 Fuel Generation from CO2 -- Abstract -- 1 Introduction -- 2 Approaches for Directly Converting CO2 to Fuels -- 2.1 Pure CO2 Decomposition Technology -- 2.2 Reagent-Based CO2 Conversion Technology -- 2.2.1 Dry Deformation of Methane Technology -- 2.2.2 Catalytic Hydrogenation of CO2 -- 3 Biological CO2 Fixation for Fuels -- 3.1 Thermochemical Conversion -- 3.1.1 Torrefaction -- 3.1.2 Pyrolysis -- 3.1.3 Thermochemical Liquefaction -- 3.1.4 Gasification -- 3.1.5 Direct Combustion -- 3.2 Biochemical Conversion -- 3.2.1 Biodiesel -- 3.2.2 Bioethanol -- 3.2.3 Biomethane -- 3.2.4 Biohydrogen -- 3.2.5 Bioelectricity -- 3.2.6 Volatile Organic Compounds. , 4 Conclusion and Future Perspectives -- References -- 4 Thermodynamics of CO2 Conversion -- Abstract -- 1 Introduction -- 2 Carbon Dioxide Capture -- 3 Carbon Dioxide Utilisations -- 4 Thermodynamic Considerations -- 5 Thermodynamics of CO2 -- 5.1 The Thermodynamic Attainable Region (AR) -- 5.2 Using Hess's Law to Transform the Extents to G-H AR @ 25˚C -- 5.3 Increasing Temperature on G-H AR -- 6 Conclusion -- Acknowledgements -- References -- 5 Enzymatic CO2 Conversion -- Abstract -- 1 Introduction -- 1.1 CO2 as a Greenhouse Gas -- 1.2 Carbon Capture, Storage, and Utilization -- 1.3 CO2 as a Chemical Feedstock -- 1.4 CO2 Conversion with Enzymes -- 2 Natural Conversion of CO2 in Cells -- 3 Enzymatic Conversion of CO2 in Cells -- 3.1 Conversion of CO2 by a Single Enzyme (in vitro) -- 3.1.1 Formate Dehydrogenase -- 3.1.2 Carbonic Anhydrase -- 3.1.3 Carbon Monoxide Dehydrogenase -- 3.1.4 Ribulose-1,5-bisphosphate Carboxylase/Oxygenase (RuBisCO) -- 3.2 Conversion of CO2 by a Multi-Enzyme Cascade in vitro -- 3.3 Other Ways (Photocatalytic CO2 Methanation) -- 4 Industrial Applications -- 4.1 Alcohols -- 4.2 Organic Acids -- 4.3 Terpenoids -- 4.4 Fatty Acids -- 4.5 Polyhydroxyalkanoates -- 4.6 Calcium Carbonate -- 5 Summary and Future Prospects -- References -- 6 Electrochemical CO2 Conversion -- Abstract -- 1 Introduction -- 2 Electrochemical CO2 Conversion -- 2.1 Fundamentals of the Process -- 2.2 Variants of Electrochemical Conversion of CO2 -- 2.2.1 Aqueous Electrolytes -- 2.2.2 Non-Aqueous Electrolytes -- 2.2.3 Solid Oxide Electrolytes -- 2.2.4 Molten Salt Electrolytes -- 3 Electrochemical CO2 Conversion from Molten Salts -- 3.1 Present State of Electrochemical Reduction of CO2in Molten Salts for the Production of Solid-Phase Carbonaceous Nanomaterials -- 3.2 Direct Electrochemical Reduction of CO2 in Chloride Melts. , 3.3 Indirect Electrochemical Reduction of CO2 in Molten Salts -- 3.4 The Mechanisms of Electrode Reactions Occurring at the Cathode and Anode -- 3.5 Prospects for CO2 Conversion in Molten Salts -- 4 Conclusions -- References -- 7 Supercritical Carbon Dioxide Mediated Organic Transformations -- Abstract -- 1 Introduction -- 2 Applications of Supercritical Carbon Dioxide -- 2.1 Hydrogenation Reactions -- 2.2 Asymmetric Hydrogenation Reactions -- 2.3 Diels-Alder Reaction -- 2.4 Coupling Reaction -- 2.5 Oxidation Reaction -- 2.6 Baeyer-Villiger Oxidation Reaction -- 2.7 Iodination Reaction -- 2.8 Polymerization Reaction -- 2.9 Carbonylation Reaction -- 2.9.1 Acetalization Reaction -- 2.9.2 Olefin Metathesis Reaction -- 2.9.3 Synthesis of heterocycles -- Synthesis of α-alkylidene Cyclic Carbonates -- Synthesis of 4-Methyleneoxazolidin-2-Ones -- Synthesis of 5-Alkylidene-1, 3-Oxazolidin-2-Ones -- Synthesis of 6-Phenyl-3a, 4-Dihydro-1H-Cyclopenta[C]furan-5(3H)-One -- Synthesis of 3, 4, 5, 6-Tetraethyl-2H-Pyran-2-One -- 3 Conclusions -- Acknowledgements -- References -- 8 Theoretical Approaches to CO2 Transformations -- Abstract -- 1 Carbon Dioxide Properties -- 2 CO2 Transformation as an Undeniable Necessity -- 3 CO2 Activation -- 3.1 Methodologies of CO2 Activation -- 4 Theoretical Insight of CO2 Transformation -- 4.1 The Theoretical Approach in CO2 Conversion to Value-Added Chemicals -- 4.1.1 Carbon Monoxide -- 4.1.2 Methane -- 4.1.3 Methanol -- 4.1.4 Formic Acid -- 4.1.5 Heterocycles -- Cyclic Carbonates -- Cyclic Carbamate -- Quiznazoline-2,4(1H,3H)-Dione -- 4.1.6 Summary and Outlook -- 5 Theoretical Designing of Novel Catalysts Based on DFT Studies -- 5.1 Theoretical Designing: Problems and Opportunities -- 6 Conclusion -- References -- 9 Carbon Dioxide Conversion Methods -- Abstract -- 1 Introduction -- 2 Molecular Structure of CO2. , 3 Thermo-Kinetics of CO2 Conversion -- 4 CO2 Conversion Methods and Products -- 4.1 Fischer-Tropsch Gas-to-Liquid (GTL) -- 4.2 Mineralization -- 4.3 Chemical Looping Dry Reforming -- 4.4 Enzymatic Conversion -- 4.5 Photocatalytic and Photo-Electrochemical Conversion -- 4.6 Thermo-Chemical Conversion -- 4.7 Hydrogenation -- 4.8 Reforming -- 5 Economic Assessment of CO2Alteration to Valuable Products -- 5.1 Syngas -- 5.2 Methanol -- 5.3 Formic Acid -- 5.4 Urea -- 5.5 Dimethyl Carbonate (DMC) -- 6 Conclusions and Future Perspective -- Acknowledgements -- References -- 10 Closing the Carbon Cycle -- Abstract -- 1 Introduction -- 2 Methods to Capture CO2 -- 3 CO2 Capture Technologies -- 4 CO2 Capture from the Air -- 5 Biomass and Waste-Based Chemicals -- 6 Advantages of Biomass-Based Chemicals -- 7 Replacement of Carbon-Based Energy Resources -- 8 Biomass Energy -- 9 Wind Energy -- 10 Solar Energy -- 11 Ocean Energy -- 12 Geothermal Energy -- 13 Hydrothermal Energy -- 14 Conclusions -- References -- 11 Carbon Dioxide Utilization to Energy and Fuel: Hydrothermal CO2 Conversion -- Abstract -- 1 Introduction -- 2 Hydrothermal CO2 Conversion -- 2.1 Metals and Catalysts as Reductant -- 2.2 Organic Wastes as Reductant -- 2.3 Inorganic Wastes as Reductant -- 2.4 Biomass as Reductant -- 3 Conclusion -- References -- 12 Ethylenediamine-Carbonic Anhydrase Complex for CO2 Sequestration -- 1 Introduction -- 2 An Overview of Carbonic Anhydrase (CA) -- 3 Mechanism of Action for Biocarbonate Formation -- 4 Historical Background of Carbonic Anhydrase -- 5 Sources of Carbonic Anhydrase -- 6 Carbonic Anhydrase in Microorganism -- 6.1 Micrococcus Lylae, Micrococcus Luteus, and Pseudomonas Fragi -- 6.2 Bacillus Subtilis and Citrobacter Freundii -- 6.3 Neisseria Gonorrhoeae -- 6.4 Helicobacter Pylori -- 7 Plant Carbonic Anhydrase -- 8 Overview of CO2. , 9 Sources of Carbon Dioxide (CO2) -- 10 Effect of Carbon Dioxide (CO2) -- 11 Carbon Dioxide Capturing -- 12 Carbon Dioxide (CO2) Sequestration -- 13 Carbon Dioxide (CO2) Sequestration by Carbonic Anhydrase -- 14 Separation System for CO2 Sequestration -- 15 Cryogenic Separation -- 16 Membrane Separation -- 17 Absorption -- 18 Adsorption -- 19 Bioreactors for CO2 Sequestration -- 20 Carbonic Anhydrase Immobilization -- 21 Ethylenediamine for Carbon Dioxide (CO2) Capturing -- 22 CO2 Capturing and Sequestration with Ethylenediamine-Carbonic Anhydrase Complex -- 23 CO2 Capturing and Sequestration Design and Optimization: Challenges and Future Prospects -- 24 Conclusion -- References -- 13 Green Pathway of CO2 Capture -- Abstract -- 1 Introduction -- 2 Molecular Structure of Carbon Dioxide -- 3 CO2 Capture System -- 3.1 Post-Combustion System -- 3.2 Pre-Combustion System -- 3.3 Oxy-Fuel Combustion System -- 4 Absorption Technology -- 4.1 Green Absorption with Ionic Liquids -- 4.1.1 Properties and Uses of Ionic Liquids -- 4.1.2 CO2 Solubility in PILs -- 4.1.3 CO2 Absorption in PILs with Carboxylate Anion -- 4.2 Reaction Mechanism Involved in CO2-Absorption -- 5 Adsorption Technology -- 5.1 Organic Adsorbents -- 5.1.1 Activated Charcoal -- 5.1.2 Biochar -- 5.1.3 Metal-Organic Frameworks (MOFs) -- 5.2 Other CO2 Adsorbents -- 5.2.1 Metal Oxide-Based Absorbents -- 5.2.2 Zeolites -- 5.3 Biological Processes of CO2Sequestration -- 5.3.1 Carbon Utilization by Forest and Agricultural Management -- 5.3.2 Ocean Fertilization -- 5.3.3 CO2 Capture by Microalgae -- 5.4 Electrochemical Ways for CO2 Capture -- 6 Conclusion -- References -- 14 Carbon Derivatives from CO2 -- Abstract -- 1 Introduction -- 2 Artificial Photoreduction -- 3 Electrochemical Reduction -- 4 Hydrogenation -- 5 Synthesis of Organic Carbonates -- 6 Reforming. , 7 Photocatalytic Reduction of CO2 with Water.

Anmerkung: Intro -- Contents -- 1 Biomass-Derived Polyurethanes for Sustainable Future -- Abstract -- 1 Introduction -- 1.1 Chemicals for Preparation of Polyurethanes -- 1.2 Importance of Green Chemicals and Synthesis Methods -- 1.3 Characteristics of Biomaterials for Polyurethanes -- 2 Bio-Oils as a Renewable Resource for Polyurethanes -- 2.1 Epoxidation and Ring-Opening Reactions -- 2.2 Hydroformation and Hydrogenation Reactions -- 2.3 Ozonolysis -- 2.4 Thiol-Ene Reaction -- 2.5 Transesterification Reaction -- 3 Terpenes as Green Starting Chemicals for Polyurethanes -- 4 Lignin for Green Polymers -- 5 Conclusion -- References -- 2 Mechanochemistry: A Power Tool for Green Synthesis -- Abstract -- 1 Introduction -- 2 History of Mechanochemistry -- 3 Principles of Mechanochemistry -- 3.1 Mechanisms and Kinetics of Mechanochemistry -- 3.2 Effects of Reaction Parameters -- 4 Mechanochemical Synthesis of Materials -- 4.1 Mechanochemical Synthesis of Co-crystals -- 4.2 Mechanochemistry in Inorganic Synthesis -- 4.3 Mechanochemistry in Organic Synthesis -- 4.4 Mechanochemistry in Metal-Organic Frameworks (MOFs) -- 4.5 Mechanochemistry in Porous Organic Materials (POMs) -- 4.6 Mechanochemical Synthesis of Polymers -- 5 Conclusions -- References -- 3 Future Trends in Green Synthesis -- Abstract -- 1 Introduction -- 2 Green Chemistry Metrics -- 2.1 Atom Economy (AE) -- 2.2 Environmental Factor (E Factor) -- 2.3 Process Mass Intensity (PMI) -- 2.4 Reaction Mass Efficiency (RME) -- 3 Application of Green Concept in Synthesis -- 3.1 Solvent-Based Organic Synthesis -- 3.2 Aqueous Medium -- 3.2.1 Micellar Media -- 3.2.2 Different Non-Aqueous Media -- Ionic Liquids -- Fluorous Media -- Supercritical Fluid -- Solvent-Free Synthesis -- 4 Future Trends -- References -- 4 Plant-Mediated Green Synthesis of Nanoparticles -- Abstract -- 1 Introduction. , 2 Methods for Metallic Nanoparticle Biosynthesis -- 3 Green Biosynthesis of Metallic NPs -- 3.1 Gold Nanoparticles -- 3.2 Platinum Nanoparticles -- 3.3 Silver Nanoparticles -- 3.4 Zinc Oxide Nanoparticles -- 3.5 Titanium Dioxide Nanoparticles -- 4 Different Parts Used for the Synthesis of Metallic Nanoparticles -- 4.1 Fruit -- 4.2 Stem -- 4.3 Seeds -- 4.4 Flowers -- 4.5 Leaves -- 5 Conclusions -- References -- 5 Green Synthesis of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- Abstract -- 1 Introduction -- 2 Advantages of Green Synthesis Methods -- 3 Green Synthesis Methods for Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 3.1 Biological Methods -- 3.1.1 Using Microorganism -- Microorganisms as Reactant -- Microorganism as Template -- 3.1.2 Using Plant -- Plant as Reactant -- Plant as Template -- 3.1.3 Using Other Green Templates -- 3.2 Physical and Chemical Methods -- 3.2.1 Green Techniques -- 3.2.2 Green Reagents -- 3.2.3 Green Solvents -- 4 Growth Mechanism of Metal and Metal Oxide HSNs -- 4.1 Biological Method -- 4.1.1 Biomolecules as Reagents -- 4.1.2 Biomolecules as Templates -- 4.2 Physical and Chemical Methods -- 5 Applications of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 5.1 Biomedical Application -- 5.2 Environmental Remediation -- 5.2.1 Wastewater Treatment -- 5.2.2 Energy Storage -- 5.2.3 Sensing -- 6 Present Challenges and Future Prospect -- Acknowledgements -- References -- 6 Bioprivileged Molecules -- Abstract -- 1 Introduction -- 2 Four Carbon 1,4-Diacids -- 2.1 Succinic Acid -- 2.2 Fumaric Acid -- 2.3 Malic Acid -- 3 Furan 2,5-Dicarboxylic Acid (FDCA) -- 4 3-Hydroxypropionic Acid (3-HPA) -- 5 Glucaric Acid -- 6 Glycerol -- 7 Aspartic Acid -- 8 Itaconic Acid -- 9 3-Hydroxybutyrolactone -- 10 Sorbitol -- 11 Xylitol -- 12 Glutamic Acid -- 13 Levulinic Acid. , 14 Emerging Molecules -- 15 Conclusion -- References -- 7 Membrane Reactors for Green Synthesis -- Abstract -- 1 Introduction -- 2 Chemical Reaction Enzymatic MR Using Supercritical CO2-IL -- 2.1 Ionic Liquid Media Effect on Free CLAB -- 2.2 Butyl Propionate Synthesis Using Active Membranes SC-CO2 and SC-CO2/IL -- 2.3 Butyl Propionate Synthesis Using Active Membranes in Hexane/IL -- 3 Mixed Ionic Electronic MR -- 3.1 Methane Flow Rate and Concentration Effects on Side II of Membrane -- 3.2 Steam Flow Effect on Side I of Membrane -- 3.3 Temperature Effect -- 4 Green Synthesis of Methanol in a Membrane Reactor -- 5 Green Fuel Energy -- 5.1 Green H2 Energy -- 5.2 Biofuel Energy -- 5.3 Green Fuel Additive -- 6 Biocatalyst Membrane Reactors -- 7 Photocatalytic Membrane Reactors -- 8 Conclusions -- References -- 8 Application of Membrane in Reaction Engineering for Green Synthesis -- Abstract -- 1 Introduction -- 2 Applications of Membrane Reactors in Reaction Engineering -- 2.1 Syngas Production -- 2.2 Hydrogen Production -- 2.3 CO2 Thermal Decomposition -- 2.4 Higher Hydrocarbon Production -- 2.5 Methane Production -- 2.6 Ammonia Production -- 3 Environmental Impacts -- 4 Conclusions and Future Recommendations -- Acknowledgements -- References -- 9 Photo-Enzymatic Green Synthesis: The Potential of Combining Photo-Catalysis and Enzymes -- Abstract -- 1 Introduction -- 2 Principle -- 3 Enzymes Involved in Light-Driven Catalysis -- 3.1 Heme-Containing Enzymes -- 3.1.1 Cytochrome P450 -- 3.1.2 Peroxidases -- 3.2 Flavin-Based Enzyme -- 3.2.1 Baeyer-Villiger Monooxygenases -- 3.2.2 Old Yellow Enzymes -- 3.3 Metal Cluster-Centered Enzyme -- 3.3.1 Hydrogenases -- 3.3.2 Carbon Monoxide Dehydrogenases -- 4 Nanoparticle-Based Activation of Enzyme -- 5 Applications in Photo-Biocatalysis -- 5.1 Isolated Enzymes/Cell Lysates -- 6 Summary and Future Scope -- References. , 10 Biomass-Derived Carbons and Their Energy Applications -- Abstract -- 1 Introduction -- 2 Types of Biomass Materials -- 2.1 Plant-Based Carbons -- 2.2 Fruit-Based Carbons -- 2.3 Animal-Based Carbons -- 2.4 Microorganism-Based Carbons -- 3 Activation of Biomass-Derived Carbons -- 3.1 Activation of Carbons -- 3.1.1 Chemical Activation of Carbons -- 3.1.2 Carbon Activation Through Physical Method -- 3.1.3 Self-activation of Carbons -- 3.2 Pyrolysis Techniques -- 3.2.1 Effect of Temperature -- 3.2.2 Effect of Residence Time -- 3.2.3 Heating Rate Effect -- 3.2.4 Size of the Particle -- 3.3 Microwave-Assisted Technique -- 3.4 Carbonization by Hydrothermal -- 3.5 Ionothermal Carbonization -- 3.6 Template Method -- 4 Energy Storage Applications of Biomass Carbons -- 4.1 Supercapacitors -- 4.2 Li/Na-Ion Batteries -- 5 Conclusion -- Acknowledgements -- References -- 11 Green Synthesis of Nanomaterials via Electrochemical Method -- Abstract -- 1 Introduction -- 2 Green Synthesis -- 2.1 Application of Biology in Green Synthesis -- 2.2 Green Synthesis Based on the Application of Solvent -- 3 Computational Data and Analysis -- 4 Electrochemical Method -- 5 Electrodeposition Method -- 5.1 Experimental Setup for Electrodeposition -- 6 Research Work: Using Green Electrochemical Methods for Nanomaterials Synthesis -- 7 Conclusion -- References -- 12 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridine Class of Bio-heterocycles: Green Avenues and Sustainable Developments -- Abstract -- 1 Introduction -- 2 Microwave-Assisted Synthesis of 2-arylimidazo[1,2-a]pyridines [Abbreviated as 2-Aryl-IPs]. -- 2.1 Synthesis of Fused Bicyclic Heteroaryl Boronates and Imidazopyridine-Quinazoline Hybrids Under MW-irradiations -- 2.2 MW-Irradiated Synthesis of IPs Using Multi-Component Strategy Under Neat Conditions. , 2.3 One-Pot, Three-Component Synthesis of 2-Phenyl-H-Imidazo[1,2-α]pyridine Under MW-Irradiations -- 2.4 Microwave-Assisted Amine-Triggered Benzannulation Strategy for the Preparation of 2,8-Diaryl-6-Aminoimidazo-[1,2-a]pyridines -- 2.5 MW-Assisted NaHCO3-catalyzed Synthesis of Imidazo[1,2-a]pyridines in PEG400 Media and Its Practical Application in the Synthesis of 2,3-Diaryl-IP Class of Bio-Heterocycles -- 2.6 MW-Irradiated, Ligand-Free, Palladium-Catalyzed, One-Pot 3-component Reaction for an Efficient Preparation of 2,3-Diarylimidazo[1,2-a]pyridines -- 2.7 MW-Assisted Water-PEG400-mediated Synthesis of 2-Phenyl-IP via Multi-Component Reaction (MCR) -- 2.8 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridines Under Neat, Catalyst-Free Conditions -- 2.9 Green Synthesis of Imidazo[1,2-a]pyridines in H2O -- 2.10 Microwave-Assisted Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]Pyridines -- 2.11 Microwave-Assisted Nano SiO2 Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]pyridines -- 2.12 Microwave-Assisted NaHCO3-Catalyzed Synthesis of 2-phenyl-IPs -- 3 Microwave-Assisted Synthesis of 3-amino-2-arylimidazo[1,2-a]pyridines [3-amino-2-aryl-IPs] -- 3.1 Microwave-Irradiated Synthesis of 3-aminoimidazo[1,2-a]pyridines via Fluorous Multi-component Pathway -- 3.2 MW-Irradiated Synthetic Protocol for 3-aminoimidazo[1,2-a]pyridines via MCR Pathway -- 3.3 MW-Assisted Sequential Ugi/Strecker Reactions Involving 3-Center-4-Component and 3-Center-5-Component MCR Strategy -- 3.4 One-Pot, 4-component Cyclization/Suzuki Coupling Leading to the Rapid Formation of 2,6-Disubstituted-3-Amino-IPs Under Microwave Irradiations -- 3.5 ZnCl2-catalyzed MCR of 3-aminoimidazo[1,2-a]pyridines Using MW Conditions -- 3.6 Microwave-Promoted Preparation of N-(3-arylmethyl-2-oxo-2,3-dihydroimidazo[1,2-a]pyridin-3-Yl)Benzamides. , 3.7 MW-Assisted Multi-component Neat Synthesis of Benzimidazolyl-Imidazo[1,2-a]pyridines.

Anmerkung: Intro -- Preface -- Contents -- 1 Green Approach: Microbes for Removal of Dyes and Metals via Ion Binding -- Abstract -- 1.1 Introduction -- 1.2 Pollutants in the Environment -- 1.2.1 Toxic Metals -- 1.2.2 Triphenylmethane Dyes -- 1.3 Bioremediation Approaches in Removing Pollutants -- 1.3.1 Non-microbial Strategies -- 1.3.2 Microbial-Based Strategies -- 1.4 Mechanisms for Removal of Pollutant Ions -- 1.4.1 Mechanisms for Removal of Metal Ions -- 1.4.2 Mechanisms for Removal of Dyes -- 1.5 Innovations in the Removal of Pollutant Ions -- 1.6 Conclusions and Future Prospects -- Acknowledgements -- References -- 2 Removal of Heavy Metal from Wastewater Using Ion Exchange Membranes -- Abstract -- 2.1 Introduction -- 2.2 Heavy Metal -- 2.2.1 Chromium -- 2.2.2 Nickel -- 2.2.3 Copper -- 2.2.4 Zinc -- 2.2.5 Cadmium -- 2.2.6 Mercury -- 2.2.7 Lead -- 2.3 Physical Treatment Methods -- 2.3.1 Ultrafiltration -- 2.3.2 Nanofiltration -- 2.3.3 Reverse Osmosis -- 2.3.4 Forward Osmosis -- 2.3.5 Adsorption -- 2.4 Chemical Treatment Methods -- 2.4.1 Electrodialysis Method -- 2.4.2 Fuel Cell Method -- 2.5 Remaining Challenges and Perspectives -- 2.6 Conclusion -- Acknowledgements -- References -- 3 Separation and Purification of Uncharged Molecules -- Abstract -- 3.1 Introduction -- 3.2 Separation and Purification of Vitamin B12 -- 3.2.1 Downstream Processing of Vitamin B12 for Measurement -- 3.3 Separation and Purification of Haemoglobin -- 3.4 Separation and Purification of Uncharged Dyes -- 3.4.1 Purification and Separation of Dyes -- 3.5 Conclusion -- References -- 4 Aluminosilicate Inorganic Polymers (Geopolymers): Emerging Ion Exchangers for Removal of Metal Ions -- Abstract -- 4.1 Introduction -- 4.2 Methodology and Calculations -- 4.2.1 Terminology: Ion Exchange or Adsorption -- 4.2.2 Evidence for Ion Exchange. , 4.2.3 Modeling of Adsorption of Metal Ions on Geopolymers -- 4.2.4 Geopolymer Preparation -- 4.2.5 Washing of the Geopolymeric Adsorbent -- 4.2.6 Comparison Between Geopolymers and Zeolites -- 4.2.7 Geopolymers as Ion Exchangers -- 4.2.7.1 Geopolymers as Ion Exchangers for Alkali Metal Ions -- 4.2.7.2 Geopolymers as Ion Exchangers for Ammonium Ion -- 4.2.7.3 Geopolymers as Ion Exchangers for Alkaline Earth Metals -- 4.2.7.4 Geopolymers as Ion Exchangers for Heavy Metals -- Metakaolin-Based Geopolymers -- Fly Ash-Based Geopolymers -- Zeolite-Based Geopolymers -- 4.2.7.5 Geopolymers as Ion Exchangers/Adsorbents for Cationic Organic Dyes -- 4.2.8 Comparison of Geopolymers with Zeolites -- 4.2.8.1 Synthesis Conditions -- 4.2.8.2 Crystallinity -- 4.2.8.3 Surface Area and Porosity -- 4.2.8.4 Cation Exchange Capacity -- 4.2.8.5 Selectivity for Metal Ions -- 4.2.8.6 Stability in Acidic Solutions -- 4.2.8.7 Thermal Stability -- 4.2.8.8 Mechanical Strength -- 4.2.8.9 Regeneration -- 4.2.9 Stabilization/Solidification/Encapsulation of Ion Exchangers in Geopolymers -- 4.3 Concluding Remarks -- References -- 5 Microwave-Assisted Hydrothermal Synthesis of Agglomerated Spherical Zirconium Phosphate for Removal of Cs+ and Sr2+ Ions from Aqueous System -- Abstract -- 5.1 Introduction -- 5.2 Materials and Methods -- 5.2.1 Preparation of Agglomerated Spherical Zirconium Phosphate -- 5.2.2 Characterization -- 5.2.3 Ion Exchange Properties -- 5.2.4 Elution Behaviour -- 5.2.5 Distribution Studies -- 5.3 Results and Discussion -- 5.3.1 Fourier-Transform Infrared (FT-IR) Characterization -- 5.3.2 Powder X-ray Diffraction Studies -- 5.3.3 Scanning Electron Microscopy (SEM) and Energy Dispersive (EDS) Characterization -- 5.3.4 Zeta and Surface Area Analysis -- 5.3.5 Ion Exchange Characteristics -- 5.3.6 Mechanism of Sr2+ Interaction with Zirconium Phosphate -- 5.4 Conclusion. , Acknowledgements -- References -- 6 Metal Hexacyanoferrates: Ion Insertion (or Exchange) Capabilities -- Abstract -- 6.1 Introduction -- 6.2 Ion Exchange -- 6.2.1 Ion Exchange in MHCF at Work: Potentiometric Ion Sensors -- 6.2.2 An Ion Exchange-Based Approach for the Recovery of Metal Ions: The Case of Cesium and Thallium -- 6.2.3 Electrochemically Driven Ion Exchange -- 6.2.4 Reversible Ion Insertion in Battery Systems -- 6.3 Conclusion -- References -- 7 Biosorbents and Composite Cation Exchanger for the Treatment of Heavy Metals -- Abstract -- 7.1 Introduction -- 7.2 Agro-Based Biosorbents for Heavy Metal Removal -- 7.3 Biopolymers -- 7.3.1 Functional Groups -- 7.3.2 Cellulose -- 7.3.3 Chitosan -- 7.3.4 Nanofiber Membranes and Packed-Bed Adsorbers -- 7.4 Composite Ion Exchangers -- 7.5 Conclusion and Future Outlook -- References -- 8 Rare Earth Elements-Separation Methods Yesterday and Today -- Abstract -- 8.1 Introduction -- 8.2 Rare Earth Elements -- 8.2.1 General Characteristics -- 8.2.2 The Occurrence of Rare Earth Elements -- 8.2.3 Physicochemical Properties of Rare Earth Elements -- 8.2.4 Application of Rare Earth Metals -- 8.2.5 Production and Consumption of Rare Earth Elements in the World -- 8.3 Rare Earth Element Recovery from Nickel-Metal Hydride Batteries -- 8.4 Rare Earth Element Recovery from Permanent Magnets -- 8.5 Separation of High-Purity Rare Earth Elements -- 8.5.1 Separations of Rare Earth Elements of High Purity Using Cation Exchangers -- 8.5.2 Separations of Rare Earth Elements of High Purity Using Anion Exchangers -- 8.5.3 Separations of Rare Earth Elements of High Purity Using Chelating Ion Exchangers -- 8.6 Current Technologies -- 8.7 Conclusions -- References -- 9 Sequestration of Heavy Metals from Industrial Wastewater Using Composite Ion Exchangers -- Abstract -- 9.1 Introduction -- 9.2 Ion-Exchange Materials. , 9.2.1 Organic Materials -- 9.2.2 Inorganic Materials -- 9.2.3 Composite Materials -- 9.2.3.1 Hybrid Materials -- 9.2.3.2 Nanocomposite -- 9.3 Mechanism of Ion-Exchange Process -- 9.4 Conclusion -- Acknowledgements -- References -- 10 Applications of Organic Ion Exchange Resins in Water Treatment -- Abstract -- 10.1 Introduction -- 10.2 Removal of Heavy Metals -- 10.3 Removal of Organics -- 10.3.1 Natural Organic Matter (NOM) -- 10.3.2 Disinfection by-Products (DBPs) -- 10.3.3 Surfactants -- 10.3.4 Pharmaceuticals -- 10.3.5 Dyes -- 10.3.6 Small Organic Matter -- 10.4 Desalination -- 10.5 Boron Removal -- 10.6 Removal of Anions -- 10.7 Removal of Cations -- 10.7.1 Hardness -- 10.7.2 Ammonium -- 10.8 Conclusions -- References.

Anmerkung: Intro -- Preface -- Contents -- 1 Separation and Purification of Amino Acids -- 1.1 Introduction -- 1.2 Ion Exchange Chromatography in the Separation of Amino Acids -- 1.3 Ion Exchange Chromatography of Amino Acids -- 1.4 Ion Exchange Resins -- 1.5 Buffer Systems in IEC for Separation of Amino Acids -- 1.5.1 Sodium Citrate Buffer System -- 1.5.2 Lithium Citrate Buffer System -- 1.6 The Relation Between the Concentration of Eluent and Retention Time of Amino Acids -- 1.7 Effect of Temperature on Separation of Amino Acids -- 1.8 Effect of pH on Separation of Amino Acids -- 1.9 Effect of the Flow Rate of the Eluting Buffer on the IEC of Amino Acids -- 1.10 Regeneration of the Ion Exchange Column -- 1.11 Conclusion -- References -- 2 Ion Exchange Chromatography for Enzyme Immobilization -- 2.1 Introduction -- 2.2 Enzyme Immobilization -- 2.2.1 Immobilization Approaches -- 2.3 Ion-Exchange as an Immobilization Tool -- 2.4 Enzyme Immobilization Research and Application by Ion-Exchange in the Laboratory and Industry -- 2.5 Conclusion and Future Prospects -- References -- 3 Determination of Morphine in Urine -- 3.1 Introduction -- 3.1.1 Structural Features of Morphine -- 3.1.2 Physical Properties -- 3.1.3 Various Routes of Morphine Administration -- 3.1.4 Stay Period of Morphine in the Body -- 3.2 What Is Drug Abuse? -- 3.2.1 Fatal Dose of Morphine -- 3.2.2 Statistics Towards Morphine Addiction -- 3.2.3 Adverse Effect of Morphine -- 3.3 Samples Used for Detection of Morphine -- 3.3.1 Sample Collection/Preparation Prior to Detection -- 3.3.2 Extraction and Derivatization -- 3.4 Detection of Morphine in Urine -- 3.4.1 Chromatographic Methods -- 3.4.2 Liquid Chromatography (LC) and High-Performance Liquid Chromatography (HPLC) -- 3.4.3 Thin-Layer Chromatography (TLC) -- 3.4.4 Capillary Electrophoresis (CE) -- 3.4.5 Electrochemical Detection. , 3.4.6 Combination of Molecularly Imprinted Polymer with Chromatography -- 3.4.7 Some Miscellaneous Detection Techniques -- 3.5 Conclusion and Future Scope -- References -- 4 Chromatographic Separation of Amino Acids -- 4.1 Introduction -- 4.1.1 History -- 4.1.2 Classification of Amino Acids -- 4.2 Separation -- 4.2.1 What is Separation? -- 4.2.2 Why Need to Do Separation of Amino Acids? -- 4.2.3 What is Chromatography? -- 4.2.4 Classification of Chromatographic Methods -- 4.2.5 Advantages of Chromatographic Methods Over Other Methods -- 4.3 Separation of Amino Acids by Gas Chromatography (GC) -- 4.4 Liquid Chromatography (LC) -- 4.4.1 Separation of Amino Acids by High-Performance Liquid Chromatography (HPLC) -- 4.4.2 Advantages of Liquid Chromatography Over the Gas Chromatography -- 4.5 Amino Acid Separation by Countercurrent Chromatography (CCC) -- 4.6 Separation of Amino Acids by Thin-Layer Chromatography (TLC) -- 4.6.1 Preparation of Thin Plates -- 4.6.2 Sample Spotting on the Thin-Layer Plate -- 4.6.3 Detection of Amino Acids on the Thin-Layer Plate -- 4.7 Separation of Amino Acids by Capillary Electrophoresis (CE) -- 4.7.1 Various Modes for Capillary Electrophoresis (CE) -- 4.8 Separation of Amino Acids by the Hyphenated Technique -- 4.8.1 List of Hyphenated Techniques -- 4.8.2 Separation of Amino Acids Using GC-MS -- 4.8.3 Separation of Amino Acids by LC-MS -- 4.8.4 Separation of Amino Acids by LC-MS-MS -- 4.8.5 Separation of Amino Acids by CE-MS -- 4.9 Conclusion and Future Scope -- References -- 5 Applications of Ion-Exchange Chromatography in Pharmaceutical Analysis -- 5.1 Introduction -- 5.2 Application of Ion-Exchange Chromatography in Quantitative Analysis -- 5.2.1 Single-Mode Ion-Exchange Chromatography -- 5.2.2 Analysis of Small Molecules (Organic and Inorganic Ions) -- 5.2.3 Mixed-Mode Chromatography. , 5.3 Pretreatment and Separation Prior to Analysis -- 5.3.1 Ionic Solid-Phase Extraction -- 5.3.2 Mixed-Mode Ion-Exchange Solid-Phase Extraction -- 5.3.3 Flow Injection Ion-Exchange Preconcentration -- 5.4 Summary -- References -- 6 Thermodynamic Kinetics and Sorption of Bovine Serum Albumin with Different Clay Materials -- 6.1 Introduction -- 6.2 Experimental -- 6.3 Results and Discussion -- 6.3.1 The Effect of Some Specific Physicochemical Properties BSA onto Adsorption -- 6.3.2 Analyses of FTIR, TGA, and SEM Images -- 6.3.3 Kinetic Analysis -- 6.3.4 Thermodynamic Parameters -- 6.4 Conclusions -- References -- 7 Sorbitol Demineralization by Ion Exchange -- 7.1 Introduction -- 7.2 Industrial Application of Sorbitol -- 7.3 Importance of Demineralization/Deashing of Sorbitol -- 7.4 Role of Ion-Exchange Chromatography -- 7.5 Different Types of Ion Exchangers for Sorbitol Demineralization -- 7.5.1 Cation-Exchange Chromatography -- 7.5.2 Anion-Exchange Chromatography -- 7.6 Conclusion -- References -- 8 Separation and Purification of Nucleotides, Nucleosides, Purine and Pyrimidine Bases by Ion Exchange -- 8.1 Introduction -- 8.2 Ion-Exchange Chromatography -- 8.2.1 Mechanism of Ion Exchange -- 8.2.2 Components of Ion-Exchange Chromatography -- 8.3 Nucleotides -- 8.4 Nucleosides -- 8.5 Purines and Pyrimidines -- 8.6 Column Preparation and Operation -- 8.7 Operation -- 8.8 Impact of Separation Parameters -- 8.9 Separation of Nucleotides -- 8.9.1 Fractionation of Nucleotides -- 8.9.2 Cation-Exchange Resin -- 8.9.3 Anion-Exchange Materials -- 8.10 Separation of Nucleosides -- 8.10.1 Purification of Nucleosides -- 8.10.2 Cation-Exchange Chromatography -- 8.10.3 Anion-Exchange Chromatography -- 8.11 Separation of Purines and Pyrimidines -- 8.11.1 Cation-Exchange Chromatography -- 8.11.2 Anion-Exchange Chromatography. , 8.12 Applications of Ion-Exchange Chromatography -- 8.13 Conclusion -- References -- 9 Separation and Purification of Vitamins: Vitamins B1, B2, B6, C and K1 -- 9.1 Introduction -- 9.2 Significance of Vitamins -- 9.3 Classification of Vitamins -- 9.3.1 Water-Soluble Vitamins -- 9.3.2 Fat-Soluble Vitamins -- 9.4 Sources of Vitamins -- 9.4.1 B Vitamins -- 9.4.2 Vitamin C -- 9.4.3 Vitamin K -- 9.5 Vitamin Deficiency Disorders -- 9.6 B Vitamins -- 9.6.1 Vitamin B1 -- 9.6.2 Vitamin B2 -- 9.6.3 Vitamin B6 -- 9.7 Vitamin C -- 9.8 Vitamin K1 -- 9.9 Separation and Purification of Vitamin -- 9.10 Ion-Exchange Chromatography -- 9.11 Mechanism of Ion-Exchange Chromatography -- 9.12 Separation and Purification of Vitamins B1, B2 and B6 -- 9.13 Separation and Purification of Vitamin C -- 9.14 Ion-Exchange Separation and Purification of Vitamin K1 -- 9.15 Conclusion -- References -- 10 Colour Removal from Sugar Syrups -- 10.1 Colourants in Sugar Solutions -- 10.1.1 Determination of Colour in Sugar and Sugar Juices -- 10.1.2 Colour Substances in Sugar and Sugar Solutions -- 10.1.3 Formation of Beet and Cane Colourants During the Technological Process -- 10.1.4 Removal of Colourants from Beet and Cane Sugar and Sugar Solution -- 10.2 Decolourisation with Ion-Exchange Resins -- 10.2.1 The Terminology Used in Ion-Exchange Technology -- 10.2.2 Types of Ion-Exchange Resins -- 10.2.3 Set-up of Industrial Chromatographic Systems for Colour Removal -- 10.2.4 Comparison of Ion-Exchange Technology with Other Decolourising Techniques -- References.

Anmerkung: Intro -- Preface -- Contents -- Contributors -- Chapter 1: Conversion of Carbon Dioxide into Liquid Hydrocarbons Using Cobalt-Bearing Catalysts -- 1.1 Introduction -- 1.2 Hydrogenation of CO2 into Hydrocarbons over a Cobalt Catalyst in a Fischer-Tropsch Process -- 1.2.1 Fischer-Tropsch Reactions -- 1.2.2 Bimetallic Cobalt and Iron Catalysts -- 1.2.3 Promoters on Cobalt-Based Catalysts for CO2 Hydrogenation -- 1.2.4 Effect of the Supports and Structure of Cobalt-Based Catalysts -- 1.2.5 Pretreatment of Cobalt Catalysts -- 1.2.6 Effect of Pressure and Ratio of the Feed Gas -- 1.3 Hydrogenation of CO2 over a Cobalt Catalyst in a Solution -- 1.4 CO2 Reforming of CH4 over a Cobalt Catalyst -- 1.5 Electrochemical Reduction of CO2 over a Cobalt Catalyst -- 1.5.1 Electrochemical Reduction of CO2 -- 1.5.2 Cobalt-Based Electrocatalysts for Reduction of CO2 into Formate -- 1.5.3 Cobalt Phthalocyanines and Cobalt Porphyrins for CO2 Reduction -- 1.6 Photocatalytic Reduction of CO2 over a Cobalt Catalyst -- 1.7 Conclusions -- References -- Chapter 2: Conversion of Carbon Dioxide Using Lead/Composite/Oxide Electrode into Formate/Formic Acid -- 2.1 Introduction -- 2.2 Electrode Composition -- 2.2.1 Lead Metal -- 2.2.2 Lead-Based Composites -- 2.2.3 Lead Oxides -- 2.3 Catalytic Mechanism -- 2.4 Reactor and Electrode Type -- 2.4.1 Traditional Electrode -- 2.4.2 Gas Diffusion Electrodes -- 2.4.3 Other Types -- 2.5 Effects of Operation Conditions -- 2.6 Conclusions -- References -- Chapter 3: Thermochemical Conversion of Carbon Dioxide to Carbon Monoxide by Reverse Water-Gas Shift Reaction over the Ceria-B... -- 3.1 Introduction -- 3.2 Reverse Water-Gas Shift Thermodynamic Considerations -- 3.3 Reverse Water-Gas Shift Catalyst -- 3.3.1 Supported Metal Catalysts -- 3.3.2 Reverse Water-Gas Shift Promoters. , 3.4 Chemistry of Cerium During Reduction and Reverse Water-Gas Shift -- 3.4.1 CeO2 Reduction Thermodynamics -- 3.4.2 In Situ CeO2 Reduction -- 3.4.3 CeO2 Reduction Mechanism -- 3.5 Conclusion -- References -- Chapter 4: Photocatalytic Systems for Carbon Dioxide Conversion to Hydrocarbons -- 4.1 Introduction -- 4.2 Fundamental Aspects for CO2 Photoconversion -- 4.2.1 Background and General Principles -- 4.2.2 Challenges of CO2 Photoconversion -- 4.3 Carbon Dioxide Photoreduction over UV-Light Semiconductors -- 4.3.1 Titanium Dioxide (TiO2) Material -- 4.3.2 TiO2-Based Photocatalyst -- Transition and Noble Elements -- Rare Earth Elements -- 4.4 Carbon Dioxide Photoreduction on Visible Light Materials -- 4.4.1 Metal Oxide Photocatalyst -- 4.4.2 Porous Materials -- 4.4.3 Carbon-Based Materials -- Graphene and Graphene Oxide -- Graphitic Carbon Nitride (g-C3N4) -- References -- Chapter 5: Electrochemical Reduction of Carbon Dioxide to Methanol Using Metal-Organic Frameworks and Non-metal-Organic Framew... -- 5.1 Introduction -- 5.2 Challenges Involved in Methanol Production from Carbon Dioxide Electrocatalytic Reduction -- 5.3 Homogeneous and Heterogeneous Electrocatalysts for Electroreduction of Carbon Dioxide -- 5.3.1 Homogeneous Catalysts for Electroreduction of Carbon Dioxide -- 5.3.2 Heterogeneous Catalysis for Electroreduction of Carbon Dioxide -- 5.4 Kinetics of Electroreduction of Carbon Dioxide into Methanol -- 5.5 Formation of Carbon Dioxide Anion Radical -- 5.6 Formation of Methanoate from the Electroreduction of Carbon Dioxide -- 5.7 Formation of Carbon Monoxide from Electroreduction of Carbon Dioxide -- 5.8 Formation of Methanol from Electroreduction of Carbon Dioxide -- 5.9 Hydrogen Evolution Reaction -- 5.10 Benchmark Non-metal-Organic Framework-Based Catalysts for Carbon Dioxide Reduction. , 5.11 Metal-Organic Frameworks as Catalysts for the Carbon Dioxide Reduction Reaction -- 5.12 Conclusion and Recommendations -- References -- Chapter 6: Photocatalytic Conversion of Carbon Dioxide into Hydrocarbons -- 6.1 Introduction -- 6.2 General Principles of Artificial Photocatalysis -- 6.2.1 Thermodynamic Theory of Carbon Dioxide Photoreduction -- 6.2.2 General Criterion of Carbon Dioxide Photoconversion Systems -- Product Formation Rate -- Selectivity Percentage -- Amount of Carbon Dioxide Converted -- Apparent Quantum Efficiency -- Turnover Number -- 6.3 Photocatalytic Material for Carbon Dioxide Photoreduction -- 6.3.1 Metal Oxide Photocatalyst for Carbon Dioxide Reduction -- 6.3.2 Layered Double Hydroxide -- 6.3.3 Metal Chalcogenides -- 6.3.4 Carbon-Based Two-Dimensional Layered Material -- 6.4 Surface Modification of Photocatalyst for Carbon Dioxide Reduction -- 6.4.1 Metal and Non-metal Doping Semiconductor -- 6.4.2 Surface Sensitization of Semiconductor -- 6.4.3 Hybridization with Another Semiconductor Material -- 6.5 Effect Operating Parameters on Carbon Dioxide Reduction -- 6.5.1 Reaction Medium -- 6.5.2 pH -- 6.5.3 Wavelength and Light Intensity -- 6.5.4 Amount of Catalyst -- 6.5.5 Particle Size -- 6.5.6 Pressure -- 6.5.7 Temperature -- 6.6 Photoreactors for Carbon Dioxide Photoconversion -- 6.6.1 Fluidized Bed Reactor -- 6.6.2 Fixed Bed Reactor -- 6.7 Conclusions -- References -- Chapter 7: Electrocatalytic Production of Methanol from Carbon Dioxide -- 7.1 Introduction -- 7.2 Liquid Phase Electrocatalytic Production of Methanol from Carbon Dioxide -- 7.2.1 Electrocatalysts -- 7.2.2 Electrolytes -- 7.2.3 Electrode Structure -- 7.2.4 Electrochemical Cell Configuration -- 7.2.5 Operation Parameters -- 7.3 Gaseous Phase Electrocatalytic Production of Methanol from Carbon Dioxide -- 7.3.1 Electrocatalysts -- 7.3.2 Electrolytes. , 7.3.3 Electrochemical Cell Configuration -- 7.3.4 Operation Parameters -- 7.4 Conclusions -- References -- Index.

Anmerkung: Intro -- ADVANCED FUNCTIONAL POLYMERS AND COMPOSITES: MATERIALS, DEVICES AND ALLIED APPLICATIONS. VOLUME 1 -- ADVANCED FUNCTIONAL POLYMERS AND COMPOSITES: MATERIALS, DEVICES AND ALLIED APPLICATIONS. VOLUME 1 -- Library of Congress Cataloging-in-Publication Data -- Dedication -- Contents -- Preface -- Contributors -- About the Editor -- Acknowledgments -- Chapter 1: Advances in Membranes for High Temperature Polymer Electrolyte Membrane Fuel Cells -- Abstract -- Abbreviations -- 1. Introduction -- 2. Proton Exchange Membrane Fuel Cells (PEMFCS) -- 2.1. Role of Proton Conducting Membrane in Proton Exchange Membrane Fuel Cells -- 2.2. Requirement for Proton Conducting Membrane for Proton Exchange Membrane Fuel Cells -- 2.3. Current Status of Perfluorinated Sulfonic Acid and Alternative Proton Conducting Membranes -- 2.4. Proton Transport in Sulfonic Acid Membranes -- 2.5. Challenges Facing Sulfonic Acid Membranes in Proton Exchange Membrane Fuel Cells -- 3. High Temperature Polymer Electrolyte -- Membrane Fuel Cell -- 3.1. Proton Exchange Membranes for High Temperature Proton Exchange Membrane Fuel Cells -- 3.2. Membranes Obtained by Modification with Hygroscopic Inorganic Fillers -- 3.3. Membranes Obtained by Modification with Solid Proton Conductors -- 3.4. Membranes Obtained by Modification with Less Volatile Proton Assisting Solvent -- 3.4.1. Doping with Heterocyclic Solvents -- 3.4.2. Doping with Phosphoric Acid -- 3.4.3. Radiation Grafted and Acid Doped Membranes -- 3.5. Disadvantages of Using Phosphoric Acid Composite Membranes for High Temperature Proton Exchange Membrane Fuel Cell Applications -- 3.6. Alternative Membranes Based on Benzimidazole Derivatives -- 3.7. Alternative Benzimidazole Polymers Doped with Heteropoly Acids -- 3.8. Membrane Impregnated with Ionic Liquids -- 3.9. Summary of Membranes Obtained by Modification of Sulfonic. , Acid Ionomers -- 4. Proton Conduction Mechanism in High Temperature Proton Conducting Membrane -- Conclusion and Prospectives -- Acknowledgments -- References -- Chapter 2: Surface-Confined Ruthenium and Osmium Polypyridyl Complexes as Electrochromic Materials -- Abstract -- Abbreviations -- 1. Introduction -- 1.1. Electrochromic Windows, Displays and Mirrors -- 1.2. Classes of Electrochromic Materials -- 1.3. Metal Complexes As Electrochromic Materials -- 1.3.1. Ruthenium (II) Complexes As Electrochromic Materials -- (I). Optical Behavior of Ruthenium Complexes -- (II). Redox Behavior of Ruthenium Complexes -- (III). Role of Spacers in Dinuclear Ruthenium Complexes -- 1.3.2. Osmium (II) Complexes As Electrochromic Materials -- 1.3.3. Other Metal Complexes As Electrochromic Materials -- 1.4. Substrates Used for Electrochromic Material -- 1.5. Modification of Substrates -- 2. Surface-Confined Ruthenium Complexes -- As Electrochromic Materials -- 2.1. Chemically Adsorbed Ruthenium Complexes -- 2.2. Physically Adsorbed Ruthenium Complexes -- 3. Surface-Confined Osmium Complexes -- As Electrochromic Materials -- 3.1. Osmium Complex-Based Monolayer -- 3.2. Osmium Complex-Based Multilayer -- 4. Surface-Confined Hetero-Metallic -- Complexes As Electrochromic Materials -- 4.1. Coordinative Supramolecular Assembly As Thin Films -- Conclusion -- Acknowledgments -- References -- Chapter 3: Magnetic Polymeric Nanocomposite Materials: Basic Principles Preparations and Microwave Absorption Application -- 1Department of Materials Science, School of Applied Physics, Faculty of Science -- and Technology, Universiti Kebangsaan Malaysia, Bangi, Selangor, Malaysia -- 2Institute of Hydrogen Economy, Universiti Teknologi Malaysia, -- Jalan Semarak, Kuala Lumpur, Malaysia -- Abstract -- Abbreviations -- 1. Introduction -- 2. Historical Background. , 3. Interaction Mechanisms of Electromagnetic Wave -- with Materials -- 3.1. Interaction Mechanism with Conductor Materials -- 3.2. Interaction Mechanism with Dielectric Materials -- 3.3. Interaction Mechanism with Magnetic Materials -- 4. The Reason of Using Microwave Absorbing Materials -- 5. The Criteria for Choosing the Filler and the -- Importance of Matching Conditions for Ideal -- Microwave Absorbing Materials -- 5.1. Metal-Backed Single Layer Absorber Mode -- 5.2. Stand-Alone Absorbing Material Model -- 6. Types and Properties of Polymers -- 7. Magnetic Polymer Nanocomposites -- 7.1. Nanomaterials -- 7.2. Magnetic Polymer Nanocomposites' Properties -- 7.3. Magnetic Polymer Nanocomposites' Applications -- 7.4. The Importance of Dispersion in Magnetic Polymer Nanocomposites -- 8. Preparation and Processing of -- Magnetic Polymer Nanocomposites -- 8.1. In-Situ Oxidative Polymerization Method (with Sonication) -- 8.2. One-Step Chemical Method -- 8.3. Surface-Initiated Polymerization Method -- 8.4. Microemulsion Chemical Oxidative Polymerization Method -- 8.5. Reverse Micelle Microemulsion Method -- 8.6. In-Situ Inverse Microemulsion Polymerization -- 8.7. Irradiation Induced Inverse Emulsion Polymerization -- 8.8. Miniemulsion Polymerization -- 8.9. Mechanical Melt Blending Method -- 8.10. Melt Processing Method Using Ultrasonic Bath -- 8.11. Template Free Method -- 8.12. Solution Casting Method -- 8.13. Sonochemical Method -- 8.14. Electrochemical Synthesis -- 9. Electromagnetic Wave Absorption Application of Magnetic Polymer Nanocomposites -- 9.1. The Crucial Role of Magnetic Nanoparticles and Sample Thickness in the Determination of the Microwave Absorption Application -- 9.2. Effect of Magnetic Filler Size on the Microwave Absorption and/or Electromagnetic Interference Shielding Application. , 9.3. Broadening the Microwave Absorption Range for Low and High Frequency Applications Using Binary Magnetic Nanofillers -- 9.4. The Enhancement of the Microwave Absorption for Electromagnetic Interference Shielding Application Using Magnetic and Dielectric Nanofillers -- Conclusion -- References -- Chapter 4: Polyetheramide-Birth of a New Coating Material -- Abstract -- Abbreviations -- 1. Introduction -- 2. Raw Materials and Test Methods -- 3. Linseed Oil Based Polyetheramides[LPEtA] -- 4. Soybean Oil Based Polyetheramides (SPEtA) -- 5. Albizia Lebbek Benth Oil Based PEtA (ABOPEtA) -- 6. Jatropha Seed Oil Based PEtA(JPEtA) -- 6. Olive Oil Based PEtA (OPEtA) -- Conclusion -- Acknowledgments -- References -- [1] Sørensen, P. A., Kiil,S., Dam-Johansen, K. & -- Weinell, C. E. (2009). Anticorrosive coatings: a review, J. Coat. Technol. Res., 6(2), 135-176. -- Chapter 5: Advanced Functional Polymers and Composite Materials and Their Role in Electroluminescent Applications -- Abstract -- Introduction & -- Scope of the Work -- 1. Light Emitting Diodes (LEDs), Characteristics and Categories -- (a) LED- Device Configuration -- (b) Recent Developments in The LED's Technology -- In-organic Light Emitting Diode -- Materials & -- Characteristics -- 3-I. Luminescence and Scintillation from the Inorganic Phosphor Materials -- An Ideal Luminescencent Material's Characteristics -- 3-II. Scintillation -- 3-III. Inorganic Electroluminescent Materials & -- Devices -- Organic Light Emitting Diodes Devices (OELDs) -- 4- (i). OLED Characteristics -- 4-(ii). OLED- Device Configuration & -- Working Principle -- 4-(iii). General Electroluminescent Materials Used for OLED Devices -- 4-(iv). OLED Device Fabrication -- 4-(v). OLED- Electro-Optical (EO) Properties -- 4-(vi). Quantum Efficiency of OLED Devices -- The Classifications of OLED types. , 4-I. An Overview of Historical Background about Polymeric OLEDs -- (P-OLEDs) -- 4-II. Polymeric OLEDs (P-OLEDs) as Electroluminescent Devices -- 4- III. Polymeric OLEDs (P-OLEDs) Employed in Various Device's Applications -- Conclusion -- Acknowledgments -- References -- [1] Akcelrud, L. Prog. Polym. Sci. 28 (2003). 875-962. -- Chapter 6: Poly(Methacrylic Acid) and Poly (Itaconic Acid) Applications as pH-Sensitive Actuators -- Abstract -- Abbreviations -- 1. Introduction -- 2. Methacrylic Acid and Itaconic Acid -Basic Properties -- 2. Poly(methacrylic acid) and Poly(Itaconic Acid) pH-sensitive Polymers -- 2.1. Linear Systems -- 2.2. Hydrogels -- 2.3. Amphiphillic Block and Graft Copolymers (Micelles) -- 2.4. Modified Surfaces and Membranes -- Conclusion -- Acknowledgments -- References -- Chapter 7: Cell Scaffolds and Fabrication Technologies for Tissue Engineering -- Abstract -- Abbreviations -- 1. Introduction -- 2. Cell Based-Therapies for Tissue Engineering -- 3. Scaffolds Preparation Technologies -- 3.1. Nanofibrous -- 3.2. Freeze-Drying -- 3.3. Fiber Bonding -- 3.4. Phase Separation -- 3.5. Gas Foaming -- 3.6. Rapid Prototyping -- 4. Special Applications in Tissue Ingineering -- 4.1. Injectable Matrices for Cell Therapy -- 4.2. Bioceramic Matrices for Cell Therapy -- Conclusion -- Acknowledgments -- References -- Chapter 8: Immobilization of Lipase by Physical Adsorption on Selective Polymers -- Abstract -- Abbreviations -- 1. Introduction -- 2. The Mechanism of Action of Lipases -- 3. Properties of Enzymes Influenced by Immobilization -- 4. Properties of Matrices for Immobilization -- 5. Methods for Enzyme Immobilization -- 5.1. Physical Adsorption -- Advantages and Disadvantages of Enzymes Immobilization Using the Adsorption Technique -- 5.2. Ionic Binding -- 5.3. Covalent Binding. , Advantages and Disadvantages of Enzymes Immobilization Using the Covalent Technique.

Anmerkung: Intro -- Foreword -- Contents -- About the Editors -- Chapter 1: Analytical Methods for the Determination of Heavy Metals in Water -- 1.1 Introduction -- 1.2 Total Concentration and Speciation Analysis -- 1.3 Health and Legislation -- 1.4 Sample Preparation for Elemental Analysis of Heavy Metals -- 1.4.1 Solid-Phase Extraction -- 1.4.1.1 Classic Solid-Phase Extraction -- 1.4.1.1.1 Modern Sorbents for Classic Solid-Phase Extraction -- 1.4.1.1.2 Micro Solid-Phase Extraction -- 1.4.1.2 Dispersive Solid-Phase Extraction -- 1.4.1.2.1 Dispersion Techniques -- 1.4.1.2.2 Modern Sorbents for Dispersive Solid-Phase Extraction and Dispersive Micro-Solid Phase Extraction -- Nanostructured Materials -- Hybrid Materials -- 1.4.1.3 Magnetic Solid-Phase Extraction -- 1.4.1.3.1 Advanced Magnetic Sorbents -- 1.4.2 Liquid-Liquid Extraction -- 1.4.2.1 Modern Solvents Used in Liquid-Liquid Extraction -- 1.4.2.1.1 Non-ionic or Zwitterionic Surfactants -- 1.4.2.1.2 Ionic Liquids -- 1.4.2.1.3 Deep Eutectic Solvents -- 1.4.2.2 Novel Liquid-Liquid Microextraction Techniques -- 1.4.2.2.1 Dispersive Liquid-Liquid Microextraction Techniques -- 1.4.2.2.2 In-Situ Phase Separation Techniques -- 1.4.2.2.3 Cloud Point Extraction -- 1.4.2.2.4 Non-dispersive Microextraction Techniques -- 1.4.2.3 Liquid-Liquid Extraction in Flow Analysis -- 1.5 Analytical Techniques for Heavy Metal Detection -- 1.5.1 Spectroscopic Techniques -- 1.5.1.1 Atomic Absorption Spectroscopy -- 1.5.1.2 Atomic Fluorescence Spectrometry -- 1.5.1.3 Atomic Emission Spectrometry -- 1.5.1.4 Inductively Coupled Plasma-Mass Spectrometry -- 1.5.1.4.1 Single Particle Inductively Coupled Plasma-Mass Spectrometry -- 1.5.1.5 Laser-Induced Breakdown Spectroscopy -- 1.5.1.6 X-Ray Fluorescence -- 1.5.1.7 UV-Vis Spectrophotometry -- 1.5.2 Electrochemical Techniques -- 1.5.2.1 Potentiostatic Techniques. , 1.5.2.1.1 Amperometry -- 1.5.2.1.2 Chronocoulometry -- 1.5.2.1.3 Voltammetric Techniques -- 1.5.2.2 Galvanostatic Stripping Chronopotentiometry -- 1.5.2.3 Electrochemiluminescence -- 1.5.3 Other Methods -- 1.5.3.1 Ion Chromatography -- 1.5.3.2 Surface-Enhanced Raman Spectroscopy -- 1.5.3.3 Bio Methods -- 1.6 Conclusions and Future Perspectives -- References -- Chapter 2: Olive-Oil Waste for the Removal of Heavy Metals from Wastewater -- 2.1 Introduction -- 2.2 Olive Tree Pruning as Biosorbent of Heavy Metals from Aqueous Solutions -- 2.2.1 Characterization -- 2.2.2 Biosorption Tests -- 2.3 Olive Stone as Biosorbent of Heavy Metals from Aqueous Solutions -- 2.3.1 Characterization -- 2.3.2 Biosorption Tests -- 2.4 Olive Pomace and Olive-Cake as Biosorbents of Heavy Metals from Aqueous Solutions -- 2.4.1 Characterization -- 2.4.2 Biosorption Tests -- 2.5 Other Valorization Opportunities for Olive-Oil Waste -- 2.6 Conclusions -- References -- Chapter 3: Metal Oxide Composites for Heavy Metal Ions Removal -- 3.1 Introduction -- 3.2 Issues in Environmental Remediation -- 3.3 Different Types of Magnetic Sorbents -- 3.3.1 Iron Oxide Modified Nanoparticle -- 3.3.2 Zeolite -- 3.3.3 Silica -- 3.3.4 Polymer Functionalization -- 3.3.5 Chitosan and Alginate -- 3.3.6 Activated Carbon -- 3.3.7 Carbon Nanotubes (CNTs) and Graphene -- 3.3.8 Agricultural Wastes -- 3.4 Case Studies -- 3.4.1 Characterization -- 3.4.2 Factors Affecting Sorption Processes -- 3.4.3 Agro-Based Magnetic Biosorbents Recovery and Reusability -- 3.5 Conclusion -- References -- Chapter 4: Two-Dimensional Materials for Heavy Metal Removal -- 4.1 Introduction -- 4.2 Heavy Metal Ions Removal Mechanism -- 4.2.1 Surface Complexation -- 4.2.2 Van der Waals Interaction -- 4.2.3 Ion Exchange -- 4.3 Different Types of Two-Dimensional Material for Heavy Metal Removal. , 4.3.1 Graphene-Based Two-Dimensional Materials -- 4.3.1.1 Structure -- 4.3.1.2 Graphene-Based Materials for Heavy Metal Removal -- 4.3.2 Dichalcogenides -- 4.3.2.1 Structure -- 4.3.2.2 Molybdenum Disulfide for Heavy Metal Removal -- 4.3.3 MXenes -- 4.3.3.1 Structure -- 4.3.3.2 MXenes for Heavy Metal Removal -- 4.3.4 Clay Minerals -- 4.3.4.1 Structure -- 4.3.4.2 Clay Mineral for Heavy Metal Removal -- 4.3.5 Layered Double Hydroxides -- 4.3.5.1 Structure -- 4.3.5.2 Layered Double Hydroxides for Heavy Metal Removal -- 4.3.6 Layered Zeolites -- 4.3.6.1 Structure -- 4.3.6.2 Layered Zeolites for Heavy Metal Removal -- 4.3.7 Other Two-Dimensional Materials -- 4.4 Heavy Metal Removal Other than Adsorption -- 4.5 Conclusions and Perspectives -- Appendix: List of Two-Dimensional Materials that Mentioned in this Chapter for Heavy Metal Removal and their Removal Capacities -- References -- Chapter 5: Membranes for Heavy Metals Removal -- 5.1 Introduction -- 5.2 Electrodialysis -- 5.2.1 Electrodialysis Applied to Metal Removal -- 5.2.2 Principle -- 5.2.3 Evaluation and Control Parameters -- 5.2.4 Use in Electroplating Industry -- 5.2.4.1 Zinc -- 5.2.4.2 Chromium -- 5.2.4.3 Copper -- 5.2.4.4 Nickel -- 5.2.5 Use in Mining and Mineral Processing Industry -- 5.2.6 Final Considerations -- References -- Chapter 6: Metal Oxides for Removal of Heavy Metal Ions -- 6.1 Introduction -- 6.2 Adsorption Methods -- 6.3 Metal Oxides for the Removal of Heavy Metal Ions from Water -- 6.3.1 Titanium Dioxide -- 6.3.2 Manganese Dioxide -- 6.3.3 Iron Oxide -- 6.3.4 Aluminum Oxide -- 6.3.5 Binary Metal Oxides -- 6.4 Conclusion -- References -- Chapter 7: Organic-Inorganic Ion Exchange Materials for Heavy Metal Removal from Water -- 7.1 Introduction -- 7.2 Ion Exchange Process -- 7.3 Ion Exchange Materials -- 7.3.1 Inorganic Ion Exchangers -- 7.3.2 Organic Ion Exchangers. , 7.4 Heavy Metal Removal with Ion Exchange Materials -- 7.4.1 Lead (II) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.4.2 Mercury (II) Removal from Waste Water with Organic-Inorganic Ion Exchangers -- 7.4.3 Cadmium (II) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.4.4 Nickel (II) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.4.5 Chromium (III, VI) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.4.6 Copper (II) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.4.7 Zinc (II) Removal from Wastewater with Organic-Inorganic Ion Exchangers -- 7.5 Conclusion -- References -- Chapter 8: Low-Cost Technology for Heavy Metal Cleaning from Water -- 8.1 Introduction -- 8.2 Sources and Impact -- 8.3 Different Routes of Contamination -- 8.4 Conventional Water Treatment Methods -- 8.4.1 Preliminary Treatment -- 8.4.2 Secondary Water Treatment -- 8.4.3 Tertiary Water Treatment -- 8.4.4 Membrane Filtration -- 8.5 Advanced Technology for Heavy Metal Ion Removal -- 8.5.1 Nano-Adsorption -- 8.5.2 Molecularly-Imprinted Polymers -- 8.5.3 Layered Double Hydroxides (LDH) and Covalent-Organic Framework (COF) -- 8.5.4 Emerging Membrane Technologies -- 8.6 Low-Cost and Biotechnological Approaches -- 8.6.1 Biosorption -- 8.6.2 Microbial Remediation -- 8.6.3 Biotechnological Strategies -- 8.7 Conclusion -- References -- Chapter 9: Use of Nanomaterials for Heavy Metal Remediation -- 9.1 General Introduction -- 9.2 Heavy Metals in the Environment -- 9.2.1 Characteristics of Selected Heavy Metals -- 9.3 Wastewater Treatment -- 9.4 Nanomaterials -- 9.4.1 Clay Minerals -- 9.4.2 Layered Double Hydroxide and Their Mixed-Oxides Counterparts -- 9.4.3 Zeolites -- 9.4.4 Two-dimensional Early Transition Metal Carbides and Carbonitrides -- 9.4.5 Metal Based Nanoparticles. , 9.4.5.1 Zero-valent Metals -- 9.4.5.2 Metal Oxides -- 9.4.6 Carbon-based Materials -- 9.4.6.1 Carbon Nanotubes -- 9.4.6.2 Fullerenes -- 9.4.6.3 Graphene -- 9.4.6.4 Graphene Oxide -- 9.4.6.5 Reduced Graphene Oxide -- 9.4.6.6 Graphitic Carbon Nitride -- 9.4.7 Metal Organic Frameworks -- 9.5 Disadvantages of Using Nanomaterials -- 9.6 Conclusions -- References -- Chapter 10: Ecoengineered Approaches for the Remediation of Polluted River Ecosystems -- 10.1 Introduction -- 10.2 Occurrence of Pollutants, Emerging Contaminants and Their Riverine Fates -- 10.3 Hazardous Effects of Water Contaminants on Aquatic and Terrestrial Biota -- 10.4 Historic Concepts of River Bioremediation -- 10.5 Physico-chemical River Remediation Methods -- 10.6 Eco-engineered River Water Remediation Technologies -- 10.6.1 Plant Based River Remediation Systems -- 10.6.1.1 Constructed Wetlands -- 10.6.1.2 Ecological Floating Wetlands, Beds and Islands -- 10.6.1.3 Eco-tanks -- 10.6.1.4 Bio-racks -- 10.6.2 Microorganisms Based River Remediation Systems -- 10.6.2.1 Biofilm Based Eco-engineered Treatment Systems -- 10.6.2.1.1 Bio-filters in River Bioremediation -- 10.6.2.2 Periphyton Based Technologies -- 10.7 In Situ Emerging Integrated Systems for the River Bioremediation -- 10.8 Concluding Remarks -- References -- Chapter 11: Ballast Water Definition, Components, Aquatic Invasive Species, Control and Management and Treatment Technologies -- 11.1 Introduction -- 11.2 Component of Ballast Water -- 11.3 Aquatic Invasive Species -- 11.4 The International Convention for the Control and Management of Ships Ballast Water and Sediments -- 11.5 IMO Standards for Ballast Water Quality -- 11.6 Management Options of Ballast Water -- 11.7 Ballast Water Treatment Technologies -- 11.7.1 Mechanical Treatment -- 11.7.2 Physical Treatment -- 11.7.2.1 Ultrasound and Cavitation. , 11.7.3 Chemical Treatment.

Anmerkung: Intro -- Preface -- Contents -- 1 Use of Ion-Exchange Resins in Dehydration Reactions -- 1.1 Introduction -- 1.2 Catalytic Processes of Dehydration -- 1.2.1 Dehydration of Alcohols to Alkenes -- 1.2.2 Dehydration of Alcohols to Ethers -- 1.2.3 Dehydration of Carbohydrates -- 1.2.4 Other Dehydration Processes -- 1.3 Conclusion -- References -- 2 The Application of Ion-Exchange Resins in Hydrogenation Reactions -- 2.1 Introduction -- 2.2 Ion-exchange resin as a catalyst and support in reaction processes -- 2.2.1 Hydrogenation reactions and catalysis -- 2.3 Ion-Exchange Resins as Catalyst and Support for Hydrogenation Reactions -- 2.3.1 Hydrogenation of Unsaturated Hydrocarbon Compounds Using Ion-Exchange Resins -- 2.3.2 Reduction, Removal, and Hydrogenation of Nitrates Using Ion-Exchange Resin -- 2.3.3 Hydrodechlorination Reaction Using Ion-Exchange Resin -- 2.4 Conclusions -- References -- 3 Use of Ion-Exchange Resins in Alkylation Reactions -- 3.1 Introduction -- 3.2 Aspects of Ion-Exchange Resins for the Alkylation Reaction -- 3.3 Alkylation Process Using Ion-Exchange Resins -- 3.3.1 Reactors and Heterogeneous Catalysis -- 3.3.2 Alkylation Process -- 3.3.3 A Process for Continuous Alkylation of Phenol Using Ion-Exchange Resin -- 3.3.4 Process for Alkylating Benzene with Tri- and Tetra-substituted Olefins with a Sulfonic Acid Type Ion-Exchanger Resin -- 3.4 Alkylation of Alkenes with Isoalkanes -- 3.5 The Reaction of Alkylation of Sulfur Compounds with Olefins -- 3.6 Alkylation of Aromatic Compounds -- 3.6.1 The Reaction of Aromatic Compounds with Olefins -- 3.6.2 The Reaction of Aromatic Compounds with Alkyl Halides and Alcohols -- 3.7 Alkylation of Phenol -- 3.8 Alkylation of Furan and Indol Derivatives -- 3.8.1 Indole Alkylation -- 3.8.2 Furan Alkylation -- 3.9 Conclusions -- References. , 4 Ion Exchange Resins Catalysed Esterification for the Production of Value Added Petrochemicals and Oleochemicals -- 4.1 Introduction -- 4.2 Ion Exchange Resin Catalysed Esterification for the Production of Petrochemicals -- 4.2.1 Esterification of Acetic Acid -- 4.2.2 Esterification of Acrylic Acid -- 4.2.3 Esterification of Lactic Acid -- 4.2.4 Esterification of Maleic Acid -- 4.3 Ion Exchange Resin Catalysed Esterification for the Production of Oleochemicals -- 4.3.1 Esterification of Oleic Acid -- 4.4 Esterification of Butyric Acid -- 4.5 Esterification of Palmitic Acid -- 4.6 Esterification of Nanonoic Acid -- 4.7 Esterification of Free Fatty Acid in Plant Oil -- 4.8 Summary and Future Prospects -- References -- 5 Synthesis and Control of Silver Aggregates in Ion-Exchanged Silicate Glass by Thermal Annealing and Gamma Irradiation -- 5.1 Introduction -- 5.2 Materials and Methods -- 5.2.1 Glass Composition -- 5.2.2 Ion Exchange -- 5.2.3 Gamma Irradiation and Thermal Treatment -- 5.2.4 UV-Vis Optical Absorption Spectrometry -- 5.3 Results and Discussion -- 5.3.1 Effect of Ion Exchange Conditions -- 5.3.2 Effect of Thermal Annealing Conditions -- 5.3.3 Effect of Gamma Irradiation -- 5.3.4 Combined Effects of Gamma Irradiation and Thermal Annealing -- 5.4 Conclusion -- References -- 6 Use of Ion-Exchange Resin in Reactive Separation -- 6.1 Introduction -- 6.2 Use of Ion-Exchange Resin in Reactive Separation -- 6.2.1 Reactive Distillation (RD) -- 6.3 Reactive Chromatography (RC) -- 6.4 Reactive Extraction (RE) -- 6.5 Reactive Absorption (RA) -- 6.6 Conclusion -- References -- 7 Chromatographic Reactive Separations -- 7.1 Introduction -- 7.1.1 Reactive Distillation (RD) -- 7.1.2 Reactive Chromatography (RC) -- 7.1.3 Reactive Extraction (RE) -- 7.1.4 Reactive Membranes (RM) -- 7.1.5 Reactive Crystallization (RCr) -- 7.2 Concluding Remarks -- References. , 8 Ion-Exchange Chromatography in Separation and Purification of Beverages -- 8.1 Introduction -- 8.2 Ion-Exchange Resins -- 8.2.1 Properties of Ion-Exchange Resins Used for Industrial Applications -- 8.2.2 Applications in Drinking Water Treatment -- 8.2.3 Major Ion-Exchange Processes in Water Treatment -- 8.2.4 Applications in Nonalcoholic Beverages -- 8.2.5 Applications in Alcoholic Beverages -- 8.3 Conclusions -- References -- 9 Ion Exchange Resin Technology in Recovery of Precious and Noble Metals -- 9.1 Introduction -- 9.2 Recovery of Metals from Their Pregnant Solutions -- 9.2.1 Gold -- 9.2.2 Recovery and Removal of Silver from Aqueous Industrial Solutions by Ion Exchange Technology -- 9.2.3 Removal of Copper from Industrial Effluents by Ion Exchange Technology -- 9.2.4 Uranium -- 9.2.5 Removal of Iron and Sulfate Ions from Copper Streams by Ion Exchange Technology -- 9.3 Conclusions -- References.

Anmerkung: Intro -- Preface -- Contents -- Chapter 1: Introduction to Carbon Dioxide Capture and Storage -- 1.1 Introduction -- 1.2 Carbon Dioxide -- 1.3 Carbon Dioxide Capture and Storage Technology -- 1.3.1 Capturing and Separation -- 1.3.2 Transport -- 1.3.3 Injection and Storage -- 1.3.3.1 Integrity Issues -- 1.3.4 Monitoring -- 1.4 Technological and Scientific Concerns -- 1.5 Summary -- References -- Chapter 2: Sources of Carbon Dioxide and Environmental Issues -- 2.1 Introduction -- 2.2 Source of Carbon Dioxide -- 2.2.1 Anthropogenic Activities -- 2.2.1.1 Carbon Dioxide Emissions from Fossil Fuels´ Combustion -- 2.2.1.2 Trends in emissions -- 2.2.1.3 Industrial Emissions -- 2.2.1.4 Overpopulation and Carbon Dioxide Emissions -- 2.2.1.5 Agriculture Sector -- 2.2.2 Natural Sources of Carbon Dioxide -- 2.2.2.1 Forest Fires -- 2.2.2.2 Volcanic eruption -- 2.3 Environmental Issues Related to Carbon Dioxide Emissions -- 2.3.1 Cyclones and Hurricanes -- 2.3.2 Droughts -- 2.3.3 Heat Waves -- 2.3.4 Food System and Food Security -- 2.3.5 Glaciers Melting -- 2.4 Conclusion -- References -- Chapter 3: Carbon Capture Utilization and Storage Supply Chain: Analysis, Modeling and Optimization -- 3.1 Introduction -- 3.2 Status of Carbon Capture Utilization and Storage Supply Chain -- 3.3 Carbon Capture Utilization and Storage Technology Overview -- 3.3.1 CO2 Capture Options -- 3.3.1.1 Absorption Technology -- 3.3.1.2 Adsorption Technology -- 3.3.1.3 Membrane Technology -- 3.3.1.4 Chemical Looping Combustion -- 3.3.1.5 Cryogenic Technology -- 3.3.1.6 Hybrid Technology -- 3.3.2 CO2 Utilization Options -- 3.3.3 CO2 Storage Options -- 3.4 Design and Optimization of Carbon Capture Utilization and Storage Supply Chain -- 3.4.1 Methodology for the Design -- 3.4.2 Development of Optimization Tool -- 3.5 Cost Analysis. , 3.6 Literature Work About Carbon Capture Utilization and Storage Supply Chain -- 3.7 Conclusions -- References -- Chapter 4: Natural Carbon Sequestration by Forestry -- 4.1 Introduction -- 4.2 Influence of the Environment and Climate Variables in the Global Carbon Cycle -- 4.2.1 Nitrogen Fertilisation -- 4.2.2 Temperature and Soil Water Availability -- 4.2.3 Radiation -- 4.2.4 Climate Extremes and Disturbance -- 4.3 Forests Global Carbon Sink -- References -- Chapter 5: Carbon Sequestration via Biomineralization: Processes, Applications and Future Directions -- 5.1 Introduction -- 5.2 Biomineralization Processes and Mechanisms -- 5.2.1 Microbially-Mediated Biomineralization -- 5.2.2 Plant-Mediated Biomineralization -- 5.3 Carbon Dioxide Sequestration -- 5.3.1 Microbially-Mediated Biomineralization -- 5.3.2 Plant-Mediated Biomineralization -- 5.3.2.1 The Case of the Iroko Tree -- 5.3.2.2 The Case of Australian Acacia Species -- 5.3.2.3 Carbon Occlusion in Biominerals -- 5.4 Knowledge Gaps and Future Directions -- 5.5 Summary and Conclusions -- References -- Chapter 6: A Review of Coupled Geo-Chemo-Mechanical Impacts of CO2-Shale Interaction on Enhanced Shale Gas Recovery -- 6.1 Introduction -- 6.2 Properties of Shale and CO2 -- 6.2.1 Shale -- 6.2.2 CO2/Supercritical CO2 -- 6.3 Interaction of CO2 and Shale -- 6.3.1 Interaction of Shale with Anhydrous CO2 -- 6.3.2 CO2-Water-Rock Geochemical Reactions in Shale -- 6.3.3 CO2 Adsorption Induced Swelling in Shale -- 6.4 Effect of CO2-Shale Interaction on Rock Properties -- 6.4.1 Porosity and Permeability -- 6.4.2 Mechanical Properties -- 6.4.3 Adsorption Properties -- 6.5 Effect of CO2-Shale Interaction on Groundwater Quality -- 6.6 Conclusions -- References -- Chapter 7: Plantation Methods and Restoration Techniques for Enhanced Blue Carbon Sequestration by Mangroves -- 7.1 Introduction. , 7.2 Blue Carbon Sequestration -- 7.2.1 Carbon Balance in a Mangrove Ecosystem -- 7.3 Plantation Techniques for Mangroves -- 7.3.1 Establishment of Mangrove Nursery -- 7.3.2 Transplantation of Nursery Grown Seedlings -- 7.3.3 Direct Seeding Method -- 7.3.4 Drain and Trench Method -- 7.3.5 Fish Bone Canal System -- 7.4 Post Plantation Management -- 7.5 Community Participation in Mangrove Plantation -- 7.6 Conclusion -- References -- Chapter 8: Biowaste for Carbon Sequestration -- 8.1 Introduction -- 8.2 Sources of Biowastes -- 8.3 Environmental Impact of Biowastes -- 8.4 Application of Biowastes for Carbon Sequestration -- 8.4.1 Composting Technology -- 8.4.2 As a Fertilizer/Organic Farming -- 8.4.3 Energy -- 8.4.4 Biochar Technology -- 8.5 Future Research Directions -- 8.6 Conclusion -- References -- Index.