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  • Canadian Science Publishing  (6)
  • 1
    Online Resource
    Online Resource
    Canadian Science Publishing ; 1967
    In:  Canadian Journal of Chemistry Vol. 45, No. 12 ( 1967-06-15), p. 1351-1355
    In: Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 45, No. 12 ( 1967-06-15), p. 1351-1355
    Abstract: Secondary reactions in the liquid phase radiolysis of cyclohexane in the presence of N 2 O and SF 6 have been examined by determining the yields of liquid products. When we added up to 0.3 M N 2 O, the hydrogen yield was reduced from its initial yield of 5.5 G units to 2.5 G units. The nitrogen yields were about twice the decrease in hydrogen yields. Bicyclohexyl and cyclohexene yields increased from their initial values to 2.2 7 and 3.5 0  G units respectively. When we added up to 0.12 M SF 6 , all the yields were decreased to about one half of their initial value.These results may be interpreted in terms of Dyne's general mechanism for the radiolysis of hydrocarbons if two cyclohexyl radicals are produced for every electron scavenged by N 2 O, but if none are produced for electrons scavenged by SF 6 . It is suggested that the total electron yield in pure cyclohexane is about 4.1 G units, of which only 3.0 G units produce hydrogen. The other 2.5 G units of hydrogen from the radiolysis of pure cyclohexane are presumed to arise from direct excitation.
    Type of Medium: Online Resource
    ISSN: 0008-4042 , 1480-3291
    RVK:
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 1967
    detail.hit.zdb_id: 1482256-8
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  • 2
    Online Resource
    Online Resource
    Canadian Science Publishing ; 2011
    In:  Applied Physiology, Nutrition, and Metabolism Vol. 36, No. 4 ( 2011-08), p. 570-576
    In: Applied Physiology, Nutrition, and Metabolism, Canadian Science Publishing, Vol. 36, No. 4 ( 2011-08), p. 570-576
    Abstract: We sought to determine whether the Edmonton Obesity Staging System (EOSS), a newly proposed tool using obesity-related comorbidities, can help identify obese individuals who are at greater mortality risk. Data from the Aerobics Center Longitudinal Study (n = 29 533) were used to assess mortality risk in obese individuals by EOSS stage (follow-up (SD), 16.2 (7.5) years). The effect of weight history and lifestyle factors on EOSS classification was explored. Obese participants were categorized, using a modified EOSS definition, as stages 0 to 3, based on the severity of their risk profile and conditions (stage 0, no risk factors or comorbidities; stage 1, mild conditions; and stages 2 and 3, moderate to severe conditions). Compared with normal-weight individuals, obese individuals in stage 2 or 3 had a greater risk of all-cause mortality (stage 2 hazards ratio (HR) (95% CI), 1.6 (1.3–2.0); stage 3 HR, 1.7 (1.4–2.0)) and cardiovascular-related mortality (stage 2 HR, 2.1 (1.6–2.8); stage 3 HR. 2.1 (1.6–2.8)). Stage 0/1 was not associated with higher mortality risk. Lower self-ascribed preferred weight, weight at age 21, cardiorespiratory fitness, reported dieting, and fruit and vegetable intake were each associated with an elevated risk for stage 2 or 3. Thus, EOSS offers clinicians a useful approach to identify obese individuals at elevated risk of mortality who may benefit from more attention to weight management. Further research is necessary to determine what EOSS factors are most predictive of mortality risk, and whether these findings can be generalized to other obese populations.
    Type of Medium: Online Resource
    ISSN: 1715-5312 , 1715-5320
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 2011
    SSG: 31
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  • 3
    Online Resource
    Online Resource
    Canadian Science Publishing ; 1979
    In:  Canadian Journal of Physics Vol. 57, No. 3 ( 1979-03-01), p. 466-476
    In: Canadian Journal of Physics, Canadian Science Publishing, Vol. 57, No. 3 ( 1979-03-01), p. 466-476
    Abstract: Using the grand canonical ensemble, the classical Van Hove correlation function G(r, t) is expanded in a power series in density. The zero density limit is the ideal gas result. We have derived, for a classical gas of hard spheres, exact expressions for [Formula: see text], the zero density derivative of the correlation function, and its Fourier transforms. These involve only two particle dynamics. The first two terms in the density expansions provide representation of the correlation functions for appropriate ranges of density and correlation function arguments. We also show that the same result can be obtained from generalized kinetic equations. To this order in density, the moment relations and the time derivatives of I(q, t) at t = 0 + are satisfied. Numerical results are compared with those of Mazenko, Wei, and Yip and with those of the Boltzmann equation and they show the expected behavior.
    Type of Medium: Online Resource
    ISSN: 0008-4204 , 1208-6045
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 1979
    detail.hit.zdb_id: 2021497-2
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  • 4
    Online Resource
    Online Resource
    Canadian Science Publishing ; 2007
    In:  Applied Physiology, Nutrition, and Metabolism Vol. 32, No. 2 ( 2007-04), p. 265-272
    In: Applied Physiology, Nutrition, and Metabolism, Canadian Science Publishing, Vol. 32, No. 2 ( 2007-04), p. 265-272
    Abstract: The independent associations between liver fat, visceral adipose tissue (AT), and metabolic risk factors are unclear. Although it has been reported that visceral AT is the strongest predictor of metabolic risk, liver fat has also been reported as a strong independent associate of a deleterious metabolic profile. We examined the independent associations between liver fat, visceral AT, and metabolic risk factors in a sample of 293 men varying widely in adiposity. Liver fat and abdominal AT were measured by computed tomography (CT). Univariate analysis revealed that liver fat was associated (p  〈 0.05) with triglycerides (TG), systolic blood pressure (SBP), and total cholesterol (TC), but not with glucose or high-density lipoprotein cholesterol (HDLC). Liver fat remained a significant correlate (p  〈 0.05) of TG and TC after control for age and subcutaneous AT or cardiorespiratory fitness (CRF), but not after adjustment for visceral AT alone. Conversely, visceral AT remained significantly associated with TG, SBP, glucose, HDLC (p  〈 0.01), and TC (p = 0.05) independent of liver fat, subcutaneous AT, CRF, and age. Both liver fat and visceral AT were associated with metabolic risk in men. However, when controlled for each other, visceral AT was the only independent associate of metabolic risk.
    Type of Medium: Online Resource
    ISSN: 1715-5312 , 1715-5320
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 2007
    SSG: 31
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  • 5
    Online Resource
    Online Resource
    Canadian Science Publishing ; 1968
    In:  Canadian Journal of Chemistry Vol. 46, No. 20 ( 1968-10-15), p. 3284-3287
    In: Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 46, No. 20 ( 1968-10-15), p. 3284-3287
    Abstract: The radiolysis of cyclohexane in the vapor phase has been examined in the presence of up to 3 mole % perfluorocyclohexane. The results indicate that perfluorocyclohexyl radicals are produced with a yield of 2.0 G units at 3% perfluorocyclohexane. It is concluded that these radicals are formed when the perfluorocyclohexyl anions are neutralized. The relevance of this neutralization to the liquid phase radiolysis of cyclohexane is discussed.
    Type of Medium: Online Resource
    ISSN: 0008-4042 , 1480-3291
    RVK:
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 1968
    detail.hit.zdb_id: 1482256-8
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  • 6
    Online Resource
    Online Resource
    Canadian Science Publishing ; 1968
    In:  Canadian Journal of Chemistry Vol. 46, No. 22 ( 1968-11-15), p. 3511-3516
    In: Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 46, No. 22 ( 1968-11-15), p. 3511-3516
    Abstract: The γ-radiolysis of cyclohexane has been examined in the vapor phase using N 2 O and SF 6 as electron scavengers. Both N 2 O and SF 6 reduce the hydrogen yield from 4.6 to 3.0 G units, indicating that 3.0 G units of hydrogen have neutral species as precursors, while 1.6 G units have electrons as precursors.Radiolysis of cyclohexane vapor with more than 2% N 2 O produces 10.4 G units of cyclohexene and 11.5 of nitrogen. Carbon dioxide reduces both these yields; the extrapolated value of G(N 2 ) is equal to G(electrons) at infinite CO 2 concentration. Thus O − is likely a precursor of that part of the nitrogen yield in excess of G(electrons), and of the cyclohexene yield associated with this nitrogen yield.The first order molecular detachment of hydrogen is unaffected by electron scavengers, showing that most of this first order yield has neutral precursors. The implications for Dyne's general mechanism of hydrocarbon radiolysis are discussed.
    Type of Medium: Online Resource
    ISSN: 0008-4042 , 1480-3291
    RVK:
    Language: English
    Publisher: Canadian Science Publishing
    Publication Date: 1968
    detail.hit.zdb_id: 1482256-8
    Location Call Number Limitation Availability
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