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  • Cambridge University Press (CUP)  (3)
  • 1
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 50, No. 1 ( 2008), p. 53-73
    Abstract: We present a new method developed for measuring radiocarbon of methane ( 14 CH 4 ) in ancient air samples extracted from glacial ice and dating 11,000–15,000 calendar years before present. The small size (∼20 μg CH 4 carbon), low CH 4 concentrations ([CH 4 ], 400–800 parts per billion [ppb] ), high carbon monoxide concentrations ([CO]), and low 14 C activity of the samples created unusually high risks of contamination by extraneous carbon. Up to 2500 ppb CO in the air samples was quantitatively removed using the Sofnocat reagent. 14 C procedural blanks were greatly reduced through the construction of a new CH 4 conversion line utilizing platinized quartz wool for CH 4 combustion and the use of an ultra-high-purity iron catalyst for graphitization. The amount and 14 C activity of extraneous carbon added in the new CH 4 conversion line were determined to be 0.23 ± 0.16 μg and 23.57 ± 16.22 pMC, respectively. The amount of modern (100 pMC) carbon added during the graphitization step has been reduced to 0.03 μg. The overall procedural blank for all stages of sample handling was 0.75 ± 0.38 pMC for ∼20-μg, 14 C-free air samples with [CH 4 ] of 500 ppb. Duration of the graphitization reactions for small ( 〈 25 μg C) samples was greatly reduced and reaction yields improved through more efficient water vapor trapping and the use of a new iron catalyst with higher surface area. 14 C corrections for each step of sample handling have been determined. The resulting overall 14 CH 4 uncertainties for the ancient air samples are ∼1.0 pMC.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2008
    detail.hit.zdb_id: 2028560-7
    SSG: 11
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  • 2
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 1993
    In:  Quaternary Research Vol. 39, No. 1 ( 1993-01), p. 1-10
    In: Quaternary Research, Cambridge University Press (CUP), Vol. 39, No. 1 ( 1993-01), p. 1-10
    Abstract: In situ -produced cosmogenic helium ( 3 He c ) provides a new tool for constraining histories of Quaternary geomorphic surfaces. Before general application of the technique, however, the systematics and production rates of 3 He c must be well understood. In a companion study, 3 He and 10 Be data from sandstone and granite boulders in the Dry Valleys region of Antarctica have been used to constrain the ages of an important moraine sequence formed by the Taylor Glacier. Data from these deposits also provide information about the systematics of 3 He in quartz that has important implications for geochronology based on 3 Hec. In contrast to previous results from olivine and clinopyroxene, crushing quartz in vacuo releases helium with high 3 He/ 4 He ratios (up to 148 × R a , where R a is the atmospheric 3 He/ 4 He ratio), indicating that crushing cannot be used to determine the isotopic composition of trapped (i.e., noncosmogenic) helium in quartz. Analysis of 3 He in different size fractions of the same samples indicates significant 3 He loss not predicted by existing 3 He diffusion data for quartz. The origin of the discrepancy is not clear, but loss from these samples is not as significant as suggested by the limited data of previous studies.
    Type of Medium: Online Resource
    ISSN: 0033-5894 , 1096-0287
    RVK:
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 1993
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    SSG: 13
    SSG: 14
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  • 3
    In: Quaternary Research, Cambridge University Press (CUP), Vol. 39, No. 1 ( 1993-01), p. 11-23
    Abstract: In situ produced cosmogenic nuclides provide a new technique for constraining exposure ages of glacial deposits. In situ 3 He and 10 Be in quartz sandstone boulders from Arena Valley, southern Victoria Land, Antarctica, provide chronological constraints for a sequence of moraines ("Taylor II-IVb" moraines) related to expansions of Taylor Glacier and the East Antarctic Ice Sheet. Mean 3 He ages are 113,000 ± 45,000 yr, 208,000 ± 67,000 yr, 335,000 ± 187,000 yr, and 1.2 ± 0.2 myr, for Taylor II,III,IVa, and IVb moraines, respectively (mean ± 1σ). Corresponding mean 10 Be ages for Taylor II and IVb moraines are 117,000 ± 51,000 yr and 2.1 ± 0.1 myr. For the older deposits the 3 He ages are probably lower limits due to diffusive loss. Although the exposure ages appear consistent with the few previous age estimates, particularly with an isotope stage 5 age for Taylor II, each moraine exhibits a broad age distribution. The distribution probably results from a variety of factors, which may include prior exposure to cosmic rays, 3 He loss, erosion, postdepositional boulder movement, and radiogenic production of 3 He. Nonetheless, the exposure ages provide direct chronological constraints for the moraine sequence, and suggest a maximum thickening of Taylor Glacier relative to the present ice surface of ∼500 m since the late Pliocene-early Pleistocene.
    Type of Medium: Online Resource
    ISSN: 0033-5894 , 1096-0287
    RVK:
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 1993
    detail.hit.zdb_id: 1471589-2
    detail.hit.zdb_id: 205711-6
    SSG: 13
    SSG: 14
    Location Call Number Limitation Availability
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