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  • 1
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 47, No. 3 ( 2005), p. 425-432
    Abstract: As a result of the growing use of multiple geochemical proxies to reconstruct ocean and climate changes in the past, there is an increasing need to establish temporal relationships between proxies derived from the same marine sediment record and ideally from the same core sections. Coupled proxy records of surface ocean properties, such as those based on lipid biomarkers (e.g. alkenone-derived sea surface temperature) and planktonic foraminiferal carbonate (oxygen isotopes), are a key example. Here, we assess whether 2 different solvent extraction procedures used for isolation of molecular biomarkers influence the radiocarbon contents of planktonic foraminiferal carbonate recovered from the corresponding residues of Bermuda Rise and Cariaco Basin sediments. Although minor Δ 14 C differences were observed between solvent-extracted and unextracted samples, no substantial or systematic offsets were evident. Overall, these data suggest that, in a practical sense, foraminiferal shells from a solvent-extracted residue can be reliably used for 14 C dating to determine the age of sediment deposition and to examine age relationships with other sedimentary constituents (e.g. alkenones).
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2005
    detail.hit.zdb_id: 2028560-7
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  • 2
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2016
    In:  Radiocarbon Vol. 58, No. 3 ( 2016-09), p. 505-515
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 58, No. 3 ( 2016-09), p. 505-515
    Abstract: The radiocarbon content of dissolved organic carbon (DOC) in rivers, lakes, and other non-saline waters can provide valuable information on carbon cycling dynamics in the environment. DOC is typically prepared for 14 C analysis by accelerator mass spectrometry (AMS) either by ultraviolet (UV) oxidation or by freeze-drying and sealed tube combustion. We present here a new method for the rapid analysis of 14 C of DOC using wet chemical oxidation (WCO) and automated headspace sampling of CO 2 . The approach is an adaption of recently developed methods using aqueous persulfate oxidant to determine the δ 13 C of DOC in non-saline water samples and the 14 C content of volatile organic acids. One advantage of the current method over UV oxidation is higher throughput: 22 samples and 10 processing standards can be prepared in one day and analyzed in a second day, allowing a full suite of 14 C processing standards and blanks to be run in conjunction with samples. A second advantage is that there is less potential for cross-contamination between samples.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2016
    detail.hit.zdb_id: 2028560-7
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    SSG: 13
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  • 3
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2005
    In:  Radiocarbon Vol. 47, No. 3 ( 2005), p. 401-412
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 47, No. 3 ( 2005), p. 401-412
    Abstract: The chemical and isotopic compositions of long-chain (C 36 –C 39 ) unsaturated ketones (alkenones), a unique class of algal lipids, encode surface ocean properties useful for paleoceanographic reconstruction. Recently, we have sought to extend the utility of alkenones as oceanic tracers through measurement of their radiocarbon contents. Here, we describe a method for isolation of alkenones from sediments as a compound class based on a sequence of wet chemical techniques. The steps involved, which include silica gel column chromatography, urea adduction, and silver nitrate-silica gel column chromatography, exploit various structural attributes of the alkenones. Amounts of purified alkenones estimated by GC/FID measurements were highly correlated with CO 2 yields after sample combustion, indicating purities of greater than 90% for samples containing ≥ 100 μg C. The degree of alkenone unsaturation ( U 37 K′ ) also varied minimally through the procedure. We also describe a high-performance liquid chromatography (HPLC) method to isolate individual alkenones for molecular-level structural and isotopic determination.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2005
    detail.hit.zdb_id: 2028560-7
    SSG: 11
    SSG: 13
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  • 4
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 61, No. 2 ( 2019-04), p. 395-413
    Abstract: In practice, obtaining radiocarbon ( 14 C) composition of organic matter (OM) in sediments requires first removing inorganic carbon (IC) by acid-treatment. Two common treatments are acid rinsing and fumigation. Resulting 14 C content obtained by different methods can differ, but underlying causes of these differences remain elusive. To assess the influence of different acid-treatments on 14 C content of sedimentary OM, we examine the variability in 14 C content for a range of marine and river sediments. By comparing results for unacidified and acidified sediments [HCl rinsing (Rinse HCl ) and HCl fumigation (Fume HCl )], we demonstrate that the two acid-treatments can affect 14 C content differentially. Our findings suggest that, for low-carbonate samples, Rinse HCl affects the Fm values due to loss of young labile organic carbon (OC). Fume HCl makes the Fm values for labile OC decrease, leaving the residual OC older. High-carbonate samples can lose relatively old organic components during Rinse HCl , causing the Fm values of remaining OC to increase. Fume HCl can remove thermally labile, usually young, OC and reduce the Fm values. We suggest three factors should be taken into account when using acid to remove carbonate from sediments: IC abundance, proportions of labile and refractory OC, and environmental matrix.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2019
    detail.hit.zdb_id: 2028560-7
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  • 5
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2017
    In:  Radiocarbon Vol. 59, No. 3 ( 2017-06), p. 893-903
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 59, No. 3 ( 2017-06), p. 893-903
    Abstract: Studies using carbon isotopes to understand the global carbon cycle are critical to identify and quantify sources, sinks, and processes and how humans may impact them. 13 C and 14 C are routinely measured individually; however, there is a need to develop instrumentation that can perform concurrent online analyses that can generate rich data sets conveniently and efficiently. To satisfy these requirements, we coupled an elemental analyzer to a stable isotope mass spectrometer and an accelerator mass spectrometer system fitted with a gas ion source. We first tested the system with standard materials and then reanalyzed a sediment core from the Bay of Bengal that had been analyzed for 14 C by conventional methods. The system was able to produce %C, 13 C, and 14 C data that were accurate and precise, and suitable for the purposes of our biogeochemistry group. The system was compact and convenient and is appropriate for use in a range of fields of research.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2017
    detail.hit.zdb_id: 2028560-7
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  • 6
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2019
    In:  Radiocarbon Vol. 61, No. 4 ( 2019-08), p. 905-926
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 61, No. 4 ( 2019-08), p. 905-926
    Abstract: The radiocarbon ( 14 C) content of simultaneously deposited substrates in lacustrine archives may differ due to reservoir and detrital effects, complicating the development of age models and interpretation of proxy records. Multi-substrate 14 C studies quantifying these effects remain rare, however, particularly for large, terminal lake systems, which are excellent recorders of regional hydroclimate change. We report 14 C ages of carbonates, brine shrimp cysts, algal mat biomass, total organic carbon (TOC), terrestrial macrofossils, and n -alkane biomarkers from Holocene sediments of the Great Salt Lake (GSL), Utah. 14 C ages for co-deposited aquatic organic substrates are generally consistent, with small offsets that may reflect variable terrestrial organic matter inputs to the system. Carbonates and long-chain n -alkanes derived from vascular plants, however, are ∼1000–4000 14 C years older than other substrates, reflecting deposition of pre-aged detrital materials. All lacustrine substrates are 14 C-depleted compared to terrestrial macrofossils, suggesting that the reservoir age of the GSL was 〉 1200 years throughout most of the Holocene, far greater than the modern reservoir age of the lake (∼300 years). These results suggest good potential for multi-substrate paleoenvironmental reconstruction from Holocene GSL sediments but point to limitations including reservoir-induced uncertainty in 14 C chronologies and attenuation and time-shifting of some proxy signals due to detrital effects.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2019
    detail.hit.zdb_id: 2028560-7
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  • 7
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2005
    In:  Radiocarbon Vol. 47, No. 3 ( 2005), p. 413-424
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 47, No. 3 ( 2005), p. 413-424
    Abstract: We evaluate potential process blanks associated with radiocarbon measurement of microgram to milligram quantities of alkenones at the National Ocean Sciences Accelerator Mass Spectrometry (NOSAMS) facility. Two strategies to constrain the contribution of blanks to alkenone 14 C dates were followed: 1) dating of samples of known age and 2) multiple measurements of identical samples. We show that the potential contamination associated with the procedure does not lead to a systematic bias of the results of alkenone dating to either younger or older ages. Our results indicate that alkenones record Δ 14 C of ambient DIC with an accuracy of approximately 10‰. A conservative estimate of measurement precision is 17‰ for modern samples. Alkenone 14 C ages are expected to be reliable within 500 yr for samples younger than 10,500 14 C yr.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2005
    detail.hit.zdb_id: 2028560-7
    SSG: 11
    SSG: 13
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  • 8
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2018
    In:  Radiocarbon Vol. 60, No. 3 ( 2018-06), p. 791-800
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 60, No. 3 ( 2018-06), p. 791-800
    Abstract: Inland water bodies contain significant amounts of carbon in the form of dissolved inorganic carbon (DIC) derived from a mixture of modern atmospheric and pre-aged sources, which needs to be considered in radiocarbon-based dating and natural isotope tracer studies. While reservoir effects in hardwater lakes are generally considered to be constant through time, a comparison of recent and historical DI 14 C data from 2013 and 1969 for Lake Constance reveals that this is not a valid assumption. We hypothesize that changes in atmospheric carbon contributions to lake water DIC have taken place due to anthropogenically forced eutrophication in the 20th century. A return to more oligotrophic conditions in the lake led to reoxygenation and enhanced terrigenous organic matter remineralization, contributing to lake water DIC. Such comparisons using DI 14 C measurements from different points in time enable nonlinear changes in lake water DIC source and signature to be disentangled from concurrent anthropogenically induced changes in atmospheric 14 C. In the future, coeval changes in lake dynamics due to climate change are expected to further perturb these balances. Depending on the scenario, Lake Constance DI 14 C is projected to decrease from the 2013 measured value of 0.856 Fm to 0.54–0.62 Fm by the end of the century.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2018
    detail.hit.zdb_id: 2028560-7
    SSG: 11
    SSG: 13
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  • 9
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2018
    In:  Radiocarbon Vol. 60, No. 3 ( 2018-06), p. 775-790
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 60, No. 3 ( 2018-06), p. 775-790
    Abstract: Organic carbon (OC) radiocarbon ( 14 C) signatures in marine surface sediments are highly variable and the causes of this heterogeneity remain ambiguous. Here, we present results from a detailed 14 C-based investigation of an Arabian Sea sediment, including measurements on organic matter (OM) in bulk sediment, specific grain size fractions, and OC decomposition products from ramped-pyrolysis-oxidation (RPO). Our results show that 14 C ages of OM increase with increasing grain size, suggesting that grain size is an important factor controlling the 14 C heterogeneity in marine sediments. Analysis of RPO decomposition products from different grain size fractions reveals an overall increase in age of corresponding thermal fractions from finer to coarser fractions. We suggest that hydrodynamic properties of sediment grains exert the important control on the 14 C age distribution of OM among grain size fractions. We propose a conceptual model to account for this dimensionality in 14 C variability that invokes two predominant modes of OM preservation within different grain size fractions of Arabian Sea sediment: finer ( 〈 63 µm) fractions are influenced by OM-mineral grain aggregation processes, giving rise to relatively uniform 14 C ages, whereas OM preserved in coarser ( 〉 63 µm) fractions includes materials encapsulated within microfossils and/or entrained fossil ( 14 C-depleted) OC hosted in detrital mineral grains. Our findings highlight the value of RPO for assessment of 14 C age variability in sedimentary OC, and for assessing mechanisms of OM preservation in aquatic sediments.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2018
    detail.hit.zdb_id: 2028560-7
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  • 10
    In: Radiocarbon, Cambridge University Press (CUP), Vol. 61, No. 03 ( 2019-06), p. 749-764
    Abstract: Speleothem organic matter can be a powerful tracer for past environmental conditions and karst processes. Carbon isotope measurements (δ 13 C and 14 C) in particular can provide crucial information on the provenance and age of speleothem organic matter, but are challenging due to low concentrations of organic matter in stalagmites. Here, we present a method development study on extraction and isotopic characterization of speleothem organic matter using a rapid procedure with low laboratory contamination risk. An extensive blank assessment allowed us to quantify possible sources of contamination through the entire method. Although blank contamination is consistently low (1.7 ± 0.34 – 4.3 ± 0.86 μg C for the entire procedure), incomplete sample decarbonation poses a still unresolved problem of the method, but can be detected when considering both δ 13 C and 14 C values. We test the method on five stalagmites, showing reproducible results on samples as small as 7 μg C for δ 13 C and 20 μg C for 14 C. Furthermore, we find consistently lower non-purgeable organic carbon (NPOC) 14 C values compared to the carbonate 14 C over the bomb spike interval in two stalagmites from Yok Balum Cave, Belize, suggesting overprint of a pre-aged or even fossil source of carbon on the organic fraction incorporated by these stalagmites.
    Type of Medium: Online Resource
    ISSN: 0033-8222 , 1945-5755
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2019
    detail.hit.zdb_id: 2028560-7
    SSG: 11
    SSG: 13
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