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  • CSIRO Publishing  (2)
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  • CSIRO Publishing  (2)
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  • 1
    Online Resource
    Online Resource
    CSIRO Publishing ; 1999
    In:  Marine and Freshwater Research Vol. 50, No. 4 ( 1999), p. 367-
    In: Marine and Freshwater Research, CSIRO Publishing, Vol. 50, No. 4 ( 1999), p. 367-
    Abstract: The effects of pH and major ion composition on the chemical speciation of the divalent cations of Co, Ni, Cu, Zn, Pb and Cd have been examined after consideration of the available thermodynamic database for solution complexes of these ions. Calculations were made for two model river waters representing the 1% and 99% extremes in composition of global river waters. The results show that inorganic speciation behaviour is of two characteristic types: (a) Cu, Zn and Co are dominated by bis-hydroxy- complexes at high pH and show the greatest reduction in the fraction of free aquo ion with increasing pH; (b) Pb, Ni and Cd are dominated by carbonato- complexes at high pH and show a more gradual decrease in the fraction of free aquo ion with increasing pH. For Cu, Pb and Ni significant fractions of the labile forms of these metal ions are present as inorganic complexes in the pH range of most natural waters, whereas for Zn, Co and Cd this is true only at moderately high pH (pH 〉 7.5). Complexing with the major ions SO42– and Cl– is important only at low pH in river waters of high ionic strength.
    Type of Medium: Online Resource
    ISSN: 1323-1650
    Language: English
    Publisher: CSIRO Publishing
    Publication Date: 1999
    detail.hit.zdb_id: 1283028-8
    SSG: 12
    SSG: 21,3
    Location Call Number Limitation Availability
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  • 2
    Online Resource
    Online Resource
    CSIRO Publishing ; 1999
    In:  Marine and Freshwater Research Vol. 50, No. 7 ( 1999), p. 699-
    In: Marine and Freshwater Research, CSIRO Publishing, Vol. 50, No. 7 ( 1999), p. 699-
    Abstract: The major ion (Na+ , K+ , Mg2+ , Ca2+ , Cl− , SO42− and reactive SiO2 ) compositions of seven rivers in the South Island, New Zealand (Manuherikia, Clutha, Takaka–Cobb, Haast, Grey, Aorere and Rakaia rivers) are reported. All the rivers were pristine in comparison with global average river waters, and the concentrations of most major ions were close to the 1% percentile levels for global river water compositions. A geochemical model that attributes ion compositions to both rain input and to the weathering of various simple mineral types in the catchment was applied to these data, and to data already published. This model, although simplistic, accounts for the main features of major ion composition in the rivers studied. The dominant sources of major ions were the weathering of limestones and feldspars. Atmospheric input was relatively small except for Na+ and Cl− .
    Type of Medium: Online Resource
    ISSN: 1323-1650
    Language: English
    Publisher: CSIRO Publishing
    Publication Date: 1999
    detail.hit.zdb_id: 1283028-8
    SSG: 12
    SSG: 21,3
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
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