In:
Current Organic Chemistry, Bentham Science Publishers Ltd., Vol. 25, No. 18 ( 2021-10-22), p. 2046-2067
Abstract:
The Pd II -mediated cross-coupling of (hetero)arenes with alkenes may be an effective
method for the formation of a C–C bond from two C–H bonds. This reaction was discovered by Fujiwara and his co-workers in 1967, which led to a number of reports that we first
highlighted in 2011 (review with references till June 2010) and for which we retained the name “Dehydrogenative Heck Reaction” (DHR). The DHR of six-membered heteroarenes
has been the subject of intensive research over the last ten years. The present review is limited to these dehydrogenative Heck reactions published since 2010, underlining the diversity of
the procedures, mechanisms and intermediates that have been proposed along with some personal comments.
Type of Medium:
Online Resource
ISSN:
1385-2728
DOI:
10.2174/1385272825666210412160959
Language:
English
Publisher:
Bentham Science Publishers Ltd.
Publication Date:
2021
Permalink