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  • 1
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A procedure for the extraction and high performance liquid chromatographic (HPLC) determination of the photodynamic therapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin in human, rat and mouse tissues following intravenous administration of the drug is described. The tissue (tumour, skin, muscle and liver) was homogenized and extracted into a mixture of methanol:dimethyl sulphoxide:water (32:8:1 by vol.) containing, 5,10,15,20-tetra(p-hydroxyphenyl)chlorin as the internal standard. The precipitated proteins were removed by centrifugation and the supernatant was separated by reversed phase HPLC on a Hypersil-ODS column with 77% (v/v) acetonitrile in 0.1% trifluoroacetic acid as the mobile phase. The solute was detected with high sensitivity and specificity by a UV-VIS detector set at 423 nm.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1391-1392 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0269-3879
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: A high performance liquid chromatographic method for the determination of the photodynamic chemotherapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (m-THPC) in human plasma following intravenous infusion is described. The procedure involves extraction of the drug in plasma with methanol/dimethyl sulphoxide (4:1 v/v) containing 5,10,15,20-tetra(p-hydroxyphenyl)clorin as the internal standard and separation on a C18 reversed phase column with acetonitrile:0.1% trifluoroacetic acid (77:23 v/v) as the mobile phase. The drug was detected specifically and sensitively at its absorption maximum of 423 nm with a detection limit of 15 ng/mL (signal-to-noise ratio of 5). The intra- and inter-assay coefficients of variation (CV) on analysis of a plasma spiked with m-THPC (1 μg/mL) were 2.3 and 3.4% (n=6), respectively.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1111-1116 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A photosensitive polysiloxaneimide precursor was synthesized from oxydianiline, bis(p-aminophenoxy)dimethylsilane, and a diacid chloride. This diacid chloride was prepared by the reaction of thionyl chloride with a diacid, which resulted from the reaction of pyromellitic dianhydride with hydroxyethylacrylate in N-methylpyrrolidone (NMP). The adhesion properties between polyimide and substrates such as SiO2 wafer were improved with introduction of siloxane moiety into the polyimide chain. The dielectric constant decreased with increasing siloxane moiety content. The photocrosslinking reaction results show that an 88-90% gel fraction was reached under the irradiation of a high-pressure mercury lamp. © 1995 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2012-10-06
    Description: Author(s): Yuan-Yuan Xiang, Fa Wang, Da Wang, Qiang-Hua Wang, and Dung-Hai Lee In several recent experiments the superconducting gap of a single-unit-cell-thick FeSe film on SrTiO 3 substrate has been observed by scanning tunneling spectroscopy and angle-resolved photoemission spectroscopy. The value of the superconducting gap is about nine times larger than that of the bulk Fe... [Phys. Rev. B 86, 134508] Published Fri Oct 05, 2012
    Keywords: Superfluidity and superconductivity
    Print ISSN: 1098-0121
    Electronic ISSN: 1095-3795
    Topics: Physics
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  • 6
    Publication Date: 2012-10-12
    Description: Correct representations of root functioning, such as root water uptake and hydraulic redistribution, are critically important for modeling the responses of vegetation to droughts and seasonal changes in soil moisture content. However, these processes are poorly represented in global land surface models. In this study, we incorporated two root functions: a root water uptake function which assumes root water uptake efficiency varies with rooting depth, and a hydraulic redistribution function into a global land surface model, CABLE. The water uptake function developed by Lai and Katul (2000) was also compared with the default one (see Wang et al., 2010) that assumes that efficiency of water uptake per unit root length is constant. Using eddy flux measurements of CO2 and water vapor fluxes at three sites experiencing different patterns of seasonal changes in soil water content, we showed that the two root functions significantly improved the agreement between the simulated fluxes of net ecosystem exchange and latent heat flux and soil moisture dynamics with those observed during the dry season while having little impact on the model simulation during the wet seasons at all three sites. Sensitivity analysis showed that varying several model parameters influencing soil water dynamics in CABLE did not significantly affect the model's performance. We conclude that these root functions represent a valuable improvement for land surface modeling and should be implemented into CABLE and other land surface models for studying carbon and water dynamics where rainfall varies seasonally or interannually.
    Print ISSN: 0148-0227
    Topics: Biology , Geosciences
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  • 7
    Publication Date: 2013-05-16
    Description: Author(s): Anzhong Wang, Qiang Wu, Wen Zhao, and Tao Zhu We study primordial gravitational waves in the Horava-Lifshitz theory of quantum gravity, in which high-order spatial derivative operators, including the ones violating parity, generically appear in order for the theory to be power-counting renormalizable and ultraviolet complete. Because of both pa... [Phys. Rev. D 87, 103512] Published Wed May 15, 2013
    Keywords: Astrophysics & Cosmology
    Print ISSN: 0556-2821
    Electronic ISSN: 1089-4918
    Topics: Physics
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  • 8
    Publication Date: 2015-08-08
    Description: A cadmium–thiocyanate complex, poly[(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κ 4 N )octakis-μ 2 -thiocyanato-κ 8 N : S ;κ 8 S : N -tricadmium(II)], [Cd 3 (C 8 H 14 N 3 ) 2 (NCS) 8 ] n , was synthesized by the reaction of 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, there are two independent types of Cd II cation (one on a centre of inversion and one in a general position) and both are in distorted octahedral coordination environments, coordinated by N and S atoms from different ligands. Neighbouring Cd II cations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bonding interactions are involved in the formation of a three-dimensional supramolecular network.
    Print ISSN: 0108-2701
    Electronic ISSN: 1600-5759
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 9
    Publication Date: 2015-10-31
    Description: PM2.5 (Particulate Matter 2.5) samples were collected at Mount Heng and analyzed for polycyclic aromatic hydrocarbons (PAHs). During sampling, a sandstorm from northern China struck Mount Heng and resulted in a mean PM2.5 concentration of 150.61 μg/m3, which greatly exceeded the concentration measured under normal conditions (no sandstorm: 58.50 μg/m3). The average mass of PAHs in PM2.5 was 30.70 μg/g, which was much lower than in the non-sandstorm samples (80.80 μg/g). Therefore, the sandstorm increased particle levels but decreased PAH concentrations due to dilution and turbulence. During the sandstorm, the concentrations of 4- and 5-ring PAHs were below their detection limits, and 6-ring PAHs were the most abundant. Under normal conditions, the concentrations of 2-, 3- and 6-ring PAHs were higher, and 4- and 5-ring PAHs were lower relative to the other sampling sites. In general, the PAH contamination was low to medium at Mount Heng. Higher LMW (low molecular weight) concentrations were primarily linked to meteorological conditions, and higher HMW (high molecular weight) concentrations primarily resulted from long-range transport. Analysis of diagnostic ratios indicated that PM2.5 PAHs had been emitted during the combustion of coal, wood or petroleum. The transport characteristics and origins of the PAHs were investigated using backwards Lagrangian particle dispersion modeling. Under normal conditions, the “footprint” retroplumes and potential source contributions of PAHs for the highest and lowest concentrations indicated that local sources had little effect. In contrast, long-range transport played a vital role in the levels of PM2.5 and PAHs in the high-altitude atmosphere.
    Electronic ISSN: 2073-4433
    Topics: Geosciences
    Published by MDPI Publishing
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  • 10
    Publication Date: 2016-01-15
    Description: The separation of liquid-gas flows is essential for many industrial processes. Computational fluid dynamics method that contains Algebraic Slip Mixture model and Reynolds Stress model is firstly adopted to analyze the impact of number of inlets, column-diameter ratio on the degassing performance of hydrocyclone. For separating the bubbles that are 5-50µm in size, the structures with 1-6 inlets and seven different column-diameter ratios (2.0-5.0) are simulated. The results show that multiport designs are more suitable for liquid-gas separation, particularly separation of small bubbles. However, as the number of inlets increases, the growth trend of separation efficiency becomes slow. In addition, the structure with H c =3.9·D n obtains the optimal separation performance. Moreover, a longer column section is beneficial to small bubbles, but results in a greater loss of fluid energy.
    Print ISSN: 0930-7516
    Electronic ISSN: 1521-4125
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley-Blackwell
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