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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 2471-2475 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We investigated theoretically the geminate electron–ion recombination in the limit of large electron mean free path by using the concept of diffusion in energy space. The energy diffusion equation is derived and the energy diffusion coefficient is evaluated. An analytical expression for the escape probability of the electron–ion pair is derived. It reproduces the numerical results very well which were obtained previously by using a Monte Carlo method. Experimental implications of the present theoretical findings are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3003-3010 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Significant large-scale modification of the surface of Al–Si conductors was observed, due to electromigration in wide lines and under low stress conditions. After electromigration stressing the Al layers showed local thickness variations, i.e., damage by thinning. The mechanism underlying this damage causes substantial metal transport. Nevertheless, damage by thinning has received little attention in the past. Thinning was observed: (1) in a number of different alloys (Al–Si, Al–Cu, Al–Si–V, and Al–Si–V–Pd), (2) with a number of different underlayers [SiO2, W–Ti (no vacuum break after Al deposition) and W–Ti (oxidized surface before Al deposition)], (3) over an extended temperature range, (4) over a range of current density, and (5) in structures with and without passivation. The results show that thinning is a general phenomenon. An activation energy of approximately 0.5 eV was determined for the temperature dependence of a combined mechanism of concurrent thinning plus voiding in Al99Si1. Several alternatives are examined to explain the observations, namely mass movement along dislocations, Al bulk diffusion, and diffusion at the interface between the Al and its oxide. It is shown that diffusion at the Al/Al oxide interface most probably plays an important role in the damage mechanism, even under stress conditions where grain boundary diffusion is traditionally thought to dominate. Results also showed that alloying of Al with Pd can reduce the effects of damage by thinning. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 55-57 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The energy levels of very short-period (GaAs)n-(AlAs)n superlattices (n≤4) were investigated by photoluminescence (PL). The results show that these superlattices are type II but the lowest conduction bands are Xx,y for n≤3 and Xz for n=4, respectively. (Here Xz is the valley with k parallel to the growth axis.) In both cases the X valleys are very close to each other. PL decay, PL excitation, and PL under uniaxial stress confirm this identification. Al0.5Ga0.5As shows very different behavior, showing that even for n=1 our samples are true superlattices.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 953-962 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The exact eigenvalues for the ground state and the excitation spectra were obtained for a system with two electrons on two sites, taking into account the transfer energy, the Coulomb repulsion on the same site, and the intersite correlation energy. The vibrational modes couple linearly to the electronic density. We discuss the interplay of these interactions resulting in different phases of distorted and undistorted eigenstates with corresponding localized and delocalized electronic wave functions and accompanying charge transfer. Several simple approximation schemes generalizable to larger systems are evaluated. The comparison with the exact results shows that their validity depends strongly on the system parameters. The according limits of applicability are discussed.
    Type of Medium: Electronic Resource
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