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  • Wiley-Blackwell  (4)
  • American Institute of Physics (AIP)  (1)
  • Maputo, Mozambique  (1)
  • Tokyo, Japan  (1)
  • 1
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 82 (1985), S. 3894-3902 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The microwave spectrum of ethyldifluorophosphine, CH3CH2PF2, has been investigated in the region from 18.0 to 39.5 GHz. The spectra of two conformers have been identified. The ground state and seven vibrationally excited states have been assigned for the more stable gauche conformer (phosphorus lone pair with respect to CH3 group), whereas the ground state and one excited state have been assigned for the trans form. Rotational and most quartic centrifugal distortion constants have been determined with A=6784.501(3), B=2930.156(2), C=2352.576(2) MHz for gauche and A=5444.910(3), B=3290.133(3), C=2871.915(3) MHz for trans, both in the ground state. Electric dipole moments were obtained from ground state Stark effect measurements: || μa||=1.990(4), || μb||=0.855(4), || μc||=0.091(7), || μt||=2.168(2) D for gauche and || μa||=1.780(10), || μb||=0, || μc||=1.077(10), || μt||=2.081(10) D for trans. Using a new computer program, a diagnostic least-squares fit of the structural parameters suggests significant structural differences between the conformers, notably the C–C–P angle which changes from 110.7° in the gauche form to 114.9° in the trans form. From a temperature study of the microwave spectrum, it was found that the gauche conformer is at least 80 cm−1 (229 cal/mol) more stable than the trans conformer. These results are compared to similar quantities in some corresponding molecules.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Biospectroscopy 2 (1996), S. 249-258 
    ISSN: 1075-4261
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Physik
    Notizen: The photodegradation of wool keratin is a very complex process that is not well understood. In this work the techniques of Fourier transform Raman and attenuated total reflectance Fourier transform-infrared spectroscopies have been used to study wool samples irradiated in air using a variety of different sources. The spectra obtained from these samples have been compared with those obtained from wool treated with sodium bisulphite, a reagent well known to produce thiol and S-sulfonate groups. As an aid for spectral interpretation the Raman and infrared spectra of cystine and those of the sodium and potassium cysteine-S-sulfonates have also been obtained. The data suggest that there are two different photolytic reaction pathways involving the cystine residues which are dependent on the wavelength of the applied radiation. © 1996 John Wiley & Sons, Inc.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    facet.materialart.
    Unbekannt
    SEACAM | Maputo, Mozambique
    Publikationsdatum: 2021-05-19
    Beschreibung: The project focuses on safeguarding the biodiversity, natural resources and ecological processes in Kiunga Marine and Dodori national Reserves through the development and implementation of a consensus-based management plan, involving full participation of local communities.
    Beschreibung: Published
    Schlagwort(e): Marine resources ; Marine parks ; Protected areas ; Protected resources ; Biodiversity ; Resource conservation ; Resource management
    Repository-Name: AquaDocs
    Materialart: Book Section , Not Known
    Format: pp.51-57
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    facet.materialart.
    Unbekannt
    Japanese Coral Reef Society | Tokyo, Japan
    Publikationsdatum: 2021-05-19
    Beschreibung: Coral reefs in the Kiunga Marine National Reserve (KMNR) (40o 07’ E, 2o 00’ S) are located in a transition ecotone between the warmer East African coral reef bioregion to the south, and colder waters of the Somali Current to the north. The reefs have been monitored annually from 1998 to the present, documenting a range of ecosystem changes from large and small scale threats. Reefs in the area suffered ˜60% loss of coral cover due to mass bleaching in the 1998 El Niño event, and 25-40% loss of coral species at individual site levels. Recovery of coral community structure has been variable, with some reefs showing strong recovery, while others have declined further. A harmful algal bloom and coral disease in early 2002 further impacted these reefs, causing mass mortalities of fish and coral, and failure of coral recruitment in that year. Fishing impacts to the reserve are high, with a strong south-north decline in fish density due to easier access to the migrant and large fishing communities to the south of the reserve. Responsibility for management of the KMNR falls under multiple institutions, including the Kenya Wildlife Service, Fisheries and Forestry Departments, and the local council. Overlapping mandates, unclear relationships, limited information and understanding, and lack of resources have hampered effective management. The monitoring programme reported here is one aspect of new collaborative appro aches to coral reef and fisheries management, and has focused on improving the information and understanding of the biological and resource systems of the area. The ecosystem trends induced by larger scale threats and the south-north fish resource gradient caused by local use patterns will be analyzed in an attempt to develop sustainable management practices for the reserve.
    Beschreibung: Published
    Schlagwort(e): Fisheries management ; Overfishing ; Coral reefs ; Ecosystems ; Mass mortality
    Repository-Name: AquaDocs
    Materialart: Book Section , Refereed
    Format: pp.1381-1390
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Publikationsdatum: 2013-08-20
    Beschreibung: [1]  The evolution of ocean temperature measurement systems is presented with a focus on the development and accuracy of two critical devices in use today (expendable bathythermographs and CTDs – conductivity-temperature-depth instruments used on Argo floats). A detailed discussion of the accuracy of these devices and a projection of the future of ocean temperature measurements are provided. The accuracy of ocean temperature measurements is discussed in detail in the context of ocean heat content, Earth's energy imbalance, and thermosteric sea level rise. Up-to-date estimates are provided for these three important quantities. The total energy imbalance at the top-of-atmosphere is best assessed by taking an inventory of changes in energy storage. The main storage is in the ocean; the latest values of which are presented. Furthermore, despite differences in measurement methods and analysis techniques, multiple studies show that there has been a multi-decadal increase in the heat content of both the upper and deep ocean regions, which reflect the impact of anthropogenic warming. With respect to sea-level rise, mutually reinforcing information from tide gauges and radar altimetry show that presently, sea-level is rising at approximately 3 mm yr -1 with contributions from both thermal expansion and mass accumulation from ice melt. The latest data for thermal expansion sea-level rise are included here and analyzed.
    Print ISSN: 8755-1209
    Thema: Geologie und Paläontologie
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Publikationsdatum: 2017-10-26
    Beschreibung: Several existing statistical and dynamical reconstructions of past regional sea level variability and trends are compared with each other and with tide gauges over the 48-yr period 1960–2007, partially pre-dating the satellite altimetry era. Evaluated statistical reconstructions were built from tide gauge data (TGR), and dynamical reconstructions from ocean data assimilation (ODA) approaches. Although most of the TGRs yield global-mean time series of sea level with trends deviating within only ±0.1 mm yr −1 , the spatial anomalies of the trends deviate substantially between the reconstructions over the period predating altimetry. In contrast, TGRs match observed regional trend patterns fairly well during the satellite altimetry era. TGRs match tide gauge data better than ODA results; however, they exhibit less variability in the open ocean compared to altimetric data. Over the pre-altimetry period, all reconstructed regional sea level trend patterns deviate substantially from each other. In terms of detrended correlations in this earlier period, the reconstructions match tide gauges, and each other, much better in the Pacific than in the Atlantic. An ensemble of all TGR and ODA estimates provides some improvements in correlations and trends to both tide gauges and altimetry. Nevertheless, a lack of independent open-ocean sea surface height data predating altimetry makes impossible the validation of the ensemble for pre-altimetry open ocean sea level trends and variability. Estimating regional sea level changes prior to altimetry therefore remains an unsolved challenge.
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    facet.materialart.
    Unbekannt
    Wiley-Blackwell
    Publikationsdatum: 2016-12-28
    Beschreibung: We note the presence in the literature of two different concepts of the term ‘active layer’ in relation to fluvial sediment transport. It has been used to represent the current dynamically active streambed surface, or to represent the depth of event-scale scour and fill. These concepts involve distinct length and time scales. We propose that, when the distinction is important, the concepts be distinguished as either a ‘dynamical active layer' or an ‘event active layer'. This article is protected by copyright. All rights reserved.
    Print ISSN: 0043-1397
    Digitale ISSN: 1944-7973
    Thema: Architektur, Bauingenieurwesen, Vermessung , Geographie
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
    Standort Signatur Einschränkungen Verfügbarkeit
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