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  • American Institute of Physics (AIP)  (1)
  • GEOMAR Helmholtz-Zentrum für Ozeanforschung  (1)
  • Taylor & Francis  (1)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 8520-8529 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Multiple spin echoes arise after "nonlinear" evolution of coherences in the presence of modulated demagnetizing fields. Such modulations can be prepared, for example, with the aid of a sequence of two 90° radio-frequency pulses in the presence of pulsed or steady field gradients. The echo amplitudes are sensitively attenuated by translational diffusion so that diffusivities can be determined on this basis. Homo- and heteronuclear variants of multiple-echo pulse sequences are considered here. A formalism based on the Bloch/Torrey equations is presented that describes the features displayed by the experimental data. The resulting attenuation formula for the homonuclear case generally accounts for all radio-frequency and field gradient pulse intervals occurring in the frame of this "pulsed gradient nonlinear spin echo" technique. Furthermore, an analogous formalism is reported for the heteronuclear case where the two nuclear species may populate different molecules with different diffusivities. It is shown that, apart from the conventional attenuation mechanism due to incomplete refocusing of the coherences, there are three additional processes contributing to homo- and heteronuclear multiple-echo attenuation by diffusion: Leveling of the magnetization helix and hence of the z magnetization grid formed by the second radiofrequency pulse, further leveling of that z magnetization grid by displacements of the dipoles producing the grid, and molecular displacements relative to the spatially modulated demagnetizing field. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-05-03
    Description: GEOMAR's project was integrated into the large-scale collaborative project SUGAR-III with 19 partners from industry and academia that was also coordinated by GEOMAR. The ain of the project was to characterize the gas hydrate accumulations in the Danube deep-sea fan geophysically and geochemically, to develop a three-dimensional geological model of the deposit and simulate its formation over geological time scales using the hydrate module developed in the PetroMod software, to investigate the problem of geomechanical destabilization and sand production occurring during hydrate exploitation by means of high-pressure experiments, to further develop the SUGAR gas hydrate technologies on geophysical data analysis, geological basin modelling and geomechanical test units in collaboration with the industrial project partners.
    Type: Report , NonPeerReviewed
    Format: text
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  • 3
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    Taylor & Francis
    In:  In: Energy Geotechnics. , ed. by Wuttke, F., Bauer, S. and Sanchez, M. Taylor & Francis, London, pp. 437-443. ISBN 978-1-138-03299-6
    Publication Date: 2020-07-27
    Description: Results from two recent field trials, onshore in the Alaska permafrost and in the Nankai Trough offshore Japan, suggest that natural gas could be produced from marine gas hydrate reservoirs at compatible yields and rates. However, both field trials were accompanied by different technical issues, the most striking problems resulting from un-predicted geomechanical behaviour, sediment destabilization and catastrophic sand production. So far, there is a lack of experimental data which could help to understand relevant mechanisms and triggers for potential soil failure in gas hydrate production, to guide model development for simulation of soil behaviour in large-scale production, and to identify processes which drive or, further, mitigate sand production. We use high-pressure flow-through systems in combination with different online and in situ monitoring tools (e.g. Raman microscopy, MRI) to simulate relevant gas hydrate production scenarios. Key components for soil mechanical studies are triaxial systems with ERT (Electric resistivity tomography) and high-resolution localstrain analysis. Sand production control and management is studied in a novel hollow-cylinder-type triaxial setup with a miniaturized borehole which allows fluid and particle transport at different fluid injection and flow conditions. We further apply a novel large-scale high-pressure flow-through triaxial test system equipped with μ-CT to evaluate soil failure modes and triggers relevant to gas hydrate production and slope stability. The presentation will emphasize an in-depth evaluation of our experimental approach, and it is our concern to discuss important issues of translating laboratory results to gas hydrate reservoirs in nature. We will present results from high-pressure flow-through experiments which are designed to systematically compare soil mechanical behaviour of gas hydrate-bearing sediments in relevant production scenarios focusing on depressurization and CO2 injection. Experimental datasets are analyzed based on numerical models which are able to simulate coupled process dynamics during gas hydrate formation and gas production.
    Type: Book chapter , NonPeerReviewed
    Format: text
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