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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1914-1922 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present a new ion spectroscopic technique by which it is possible to investigate larger molecular ions by scanning an entire electronic state and coincidentally measuring and, hence, fixing the mass of the fragment ion observed. The technique involves primary resonance excitation together with secondary absorption followed by dissociation as detection process, employing the absorption of two photons in the ion. This method accesses the nondissociating vibronic levels of an electronic state rather than just the narrow range of predissociating levels, as in one-photon dissociation spectroscopy. Spectra of CH3I+ and CD3I+ over a range of 7000 cm−1, beginning at the origin of the A˜ state, were recorded with progression bands up to n=21. These spectra allow for the first time an unambiguous assignment of the A˜←X˜ transition of CH3I+ and CD3I+. The exact positions of the electronic origin as well as of the origin of several progressions and new values for several vibrational constants of methyl iodide cations are reported. Some 300 bands in both ions were measured and assigned with this technique.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 3816-3821 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: AgInSbTe films have recently attracted considerable interest as advanced materials for phase change recording. For this application the determination of crystallization kinetics is of crucial importance. In this work the temperature dependence of structural and electrical properties of sputtered AgInSbTe films has been determined. Temperature dependent measurements of the electrical resistance have been employed to study the kinetics of structural changes of these films. Upon annealing a major resistivity drop is observed at around 160 °C which can be attributed to a structural change as corroborated by x-ray diffraction. X-ray diffraction shows an amorphous phase for as-deposited films, while crystalline films with hexagonal structure (a=4283 Å, c=16 995 Å) are obtained upon annealing above 160 °C. By applying Kissinger's method, an activation energy of 3.03±0.17 eV is obtained for the crystallization. X-ray reflection measurements reveal a density increase of 5.2%±0.2% and a thickness decrease of 5.5%±0.2% upon crystallization. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4176-4183 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the formation of surface blisters in 〈100〉 n-type silicon following co-implantation with boron and hydrogen. The silicon substrates had four different n-type dopant levels, ranging from 1014 to 1019 cm−3. These substrates were implanted with 240 keV B+ ions to a dose of 1015 cm−2, followed by a rapid thermal anneal at 900 °C for 30–60 s to force the boron atoms into substitutional lattice positions (activation). The samples were then implanted with 40 keV H+ to a dose of 5×1016 cm−2. The implanted H+ distribution peaks at a depth of about 475 nm, whereas the distribution in the implanted B+ is broader and peaks at about 705 nm. To evaluate the role of the B+ implantation, control samples were prepared by implanting with H+ only. Following the H+ implantation, all the samples were vacuum annealed at 390 °C for 10 min. Blisters resulting from subsurface cracking at depths of about 400 nm, were observed in most of the B+ implanted samples, but not in the samples implanted with H+ only. This study indicates that the blistering results from the coalescence of implanted H into bubbles. The doping with B facilitates the short-range migration of the H interstitials and the formation of bubbles. A comparison of the observed crack depth with the depth of the damage peak resulting from the H+ implantation (evaluated by the computer code TRIM) suggests that the nucleation of H bubbles occurs at the regions of maximum radiation damage, and not at the regions of maximum H concentration. For given values of B+ and H+ doping, the blister density was found to decrease with increasing n-type doping, when the boron is activated. Blister formation was also observed in B+ implanted samples which had not been activated. In this case, the blister density was found to increase with increasing value of n-type doping. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Diamondlike carbon (DLC) was deposited on silicon using a plasma immersion ion deposition (PIID) method. Inductive radio-frequency plasma sources were used to generate Ar and C2H2 plasmas at low gas pressures ranging from 0.04 to 0.93 Pa. The film stress and hardness were sharply dependent upon bias voltage at an operating pressure of 0.04 Pa. A maximum hardness of 30 GPa and compressive stress of 9 GPa was observed at a pulsed bias of −150 V bias (carbon energy of 80 eV). The mechanical properties of DLC films are correlated with UV Raman peak positions which infer sp3-bonded carbon contents. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 71 (1997), S. 1320-1322 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron field emission from allotropes of carbon (graphite, diamondlike carbon, and diamond) have been reported many times in the literature. This work explores the use of ion irradiation for improving electron field emission from carbon fibers. Carbon fibers have been irradiated with H, C, Ar, and Xe ions. Field emission characteristics have been measured as a function of ion dose. A reversible reduction in the required field for a fixed current level has been observed. The critical dose, Dc, defines the dose corresponding to the lowest field necessary to emit a fixed current (5 μA). The critical dose appears to correlate with the nuclear energy loss (collisions with atoms) of the ion in the carbon fiber. Transmission electron microscopy and parallel electron energy loss spectroscopy analysis indicate an amorphous surface, and an increase in the sp3 content of the fiber surface to 20%–30%. A corresponding decrease in the work function is expected and may account for the improvement in electron emission. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Flow-through microcosms were constructed to conduct ecological experiments on aquifer organisms. The two 5-channel microcosms were simple to construct, were fed by an artesian spring, and maintained close to in situ temperature and O2 concentrations. They were used to test relative microbial colonization of three substrate sizes: silt (0.063 mm), sand (0.9 mm), and gravel (3 mm). After 96 days of incubation, O2 microelectrode measurements revealed the lowest O2 tension in the silt, the highest in the gravel, and intermediate values in the sand. Microbial activity (3[H]-thymidine incorporation) was greatest in the gravel, followed by sand and then silt. Denitrification was greatest in the silt, followed by sand and then gravel. Microbial activity may be greatest with the largest particle size because of increased water exchange through pores, and denitrification may be greatest with the smallest particle sizes because of the occurrence of anaerobic microzones.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Freshwater biology 20 (1988), S. 0 
    ISSN: 1365-2427
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: SUMMARY 1. A sampler was developed that displaces surface water which is replaced with water from a sampling tube at a set depth.2. The displacement sampler is inexpensive, easy to build, and is capable of collecting water at 7.5 I min−1.3. Phytoplankton photosynthesis was higher in water from the displacement sampler than in water collected with a Van-Dorn bottle. Subsequent experiments indicated this was due to inhibition caused by the Van-Dorn bottle.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Freshwater biology 25 (1991), S. 0 
    ISSN: 1365-2427
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: SUMMARY. 1. Filamentous algae in flowing freshwaters can represent a spatially and temporally distinct sub-habitat for epiphytic diatom communities. This sub-habitat is described in a low discharge, spring-fed stream with extensive filamentous green algal mats, and in a tuft of Cladophora glomerata (L.) Kützing from a large river.2. Oxygen micro-electrodes, a thermistor current velocity probe, a standard pH probe and water chemistry were employed to assess spatial heterogeneity. Temporal patterns of epiphyte colonization were evaluated on filamentous artificial substrates.3. There were steep spatial gradients in the low discharge stream. At mid-day, O2 ranged from 0–1.5 times air-saturated O2 concentrations, pH varied from 7.25–8.0, and current velocity spanned 0–0.5 m s−1. Areas near the surface of algal mats had high O2, pH and current velocity. These patterns were correlated with epiphyte community structure.4. In the interior of C. glomerata tufts O2 concentration was raised and current velocity depressed compared to the surrounding water, even when external current velocity was as high as 0.4 m s−1.5. After thirty-five days of colonization of artificial substrate in the low discharge environment, epiphyte communities were similar to those on filamentous atgae. Epiphyte diversity on artificial substrates subsequently decreased compared to natural substrates as did the similarity between the types on substrates, suggesting that microscale renewal of epiphyte habitat (growth of filamentous algae) maintains high epiphytic diversity.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 19 (1981), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Two bedrock valleys, filled with glacial outwash material, were investigated with Schlumberger resistivity soundings. Aquifer electrical resistivities were determined for 16 vertical electrical soundings at seven sites in southern Rhode Island where pumping tests had been run previously. Resistivities for the different aquifer materials were derived with boring log control. The auxiliary point methods were used to reduce the aquifer layering to a single representative resistivity value. Relationships between the representative aquifer resistivity and aquifer permeability and transmissivity were derived.
    Type of Medium: Electronic Resource
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