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  • 1
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Hydraulic engineering. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (605 pages)
    Edition: 2nd ed.
    ISBN: 9783319526638
    Series Statement: Springer Series in Synergetics Series
    DDC: 530.417
    Language: English
    Note: Intro -- Preface of the Second Edition -- Preface of the First Edition -- Contents -- 1 Introduction -- 1.1 Interfacial Pattern Formation in Dendritic Growth and Hele-Shaw Flow -- 1.2 A Brief Review of the Theories of Free Dendritic Growth -- 1.2.1 Maximum Velocity Principle (1976) -- 1.2.2 Marginal Stability Hypothesis (1978) -- 1.2.3 Microscopic Solvability Condition (MSC) Theory (1986-1990s) -- 1.2.4 Interfacial Wave (IFW) Theory (1990) -- 1.3 Macroscopic Continuum Model -- 1.3.1 Macroscopic Transport Equations -- 1.3.2 The Interface Conditions -- 1.3.3 The Scaling and the Dimensionless System -- References -- 2 Unidirectional Solidification and Mullins-Sekerka Instability -- 2.1 Solidification with Planar Interface from a Pure Melt -- 2.1.1 Basic Steady-State Solution -- 2.1.2 Unsteady Perturbed Solutions and Mullins-Sekerka Instability -- 2.1.2.1 Zeroth-Order Approximation Solutions -- 2.1.2.2 First-Order Approximation Solutions -- 2.1.3 Asymptotic Solutions in the Long-Wave Regime, k=O() -- 2.1.3.1 O(0) -- 2.1.3.2 O(2) -- 2.1.4 Asymptotic Solutions in the Extremely Short-Wave Regime, k=O(1) -- 2.1.4.1 O(0) -- 2.1.4.2 O(2) -- 2.2 Unidirectional Solidification from a Binary Mixture -- 2.2.1 Mathematical Formulation of the Problem -- 2.2.2 Basic Steady State -- 2.2.3 Unsteady Perturbed Solutions -- 2.2.3.1 Zeroth-Order Approximation Solutions -- 2.2.3.2 First-Order Approximation Solutions -- 2.2.4 Asymptotic Solutions in the Long-Wave Regime, k=O() -- 2.2.5 Asymptotic Solutions in the Extremely Short-Wave Regime, k= O(1/E) -- g=O(1/E) -- 2.2.6 Some Remarks on Unidirectional Solidification -- References -- 3 Mathematical Formulation of Free Dendritic Growth from a Pure Melt -- 3.1 Three-Dimensional Free Dendritic Growth -- 3.2 Axisymmetric Free Dendrite Growth -- 3.3 Two-Dimensional Free Dendritic Growth -- Reference. , 4 Basic Steady State of Axisymmetric Dendritic Growth and Its Regular Perturbation Expansion -- 4.1 The Ivantsov Solution and Unsolved Fundamental Problems -- 4.2 Axially Symmetric Steady Needle Growth with Nonzero Surface Tension -- 4.2.1 Mathematical Formulation -- 4.2.2 Regular Perturbation Expansion Solutions (RPE) as E→0 -- 4.2.2.1 The Zeroth-Order Approximation O(0) -- 4.2.2.2 The First-Order Approximation O(2) -- 4.2.3 The Asymptotic Behavior of the Regular Perturbation Expansion Solution as ξ→∞ -- 4.2.4 Some Numerical Results of the Interface Shape -- 4.3 Summary and Discussion -- References -- 5 The Steady State for Dendritic Growth with Nonzero Surface Tension -- 5.1 The Nash-Glicksman Problem and the Classical Needle Crystal Solution -- 5.2 The Geometric Model and Solutions of NeedleCrystal Growth -- 5.2.1 Geometric Model of Dendritic Growth -- 5.2.2 The Segur-Kruskal Problem -- 5.2.3 Steady Nonclassical Needle Growth Problem -- 5.2.3.1 The Outer Expansion -- 5.2.3.2 The Composite Solution -- 5.2.3.3 The Properties of the Composite Solutions -- 5.2.4 Needle Crystal Formation Problem -- 5.3 The Nonclassical Steady State of Dendritic Growth with Nonzero Surface Tension -- 5.3.1 The Complete Mathematical Formulation for Free Dendrite Growth -- References -- 6 Global Interfacial Wave Instability of Dendritic Growth from a Pure Melt -- 6.1 Linear Perturbed System Around the Basic State of Axisymmetric Dendritic Growth -- 6.2 Outer Solution in the Outer Region Away from the Tip -- 6.2.1 Zeroth-Order Approximation -- 6.2.2 First-Order Approximation -- 6.2.3 Singular Point ζc of the Outer Solution -- 6.3 The Inner Solutions near the Singular Point ζc -- 6.4 Tip Inner Solution in the Tip Region -- 6.5 Global Trapped-Wave Modes and the Quantization Condition -- 6.6 Comparison of Theoretical Predictions with Experimental Data. , 6.6.1 The Dendrite Tip Velocity and Tip Radius -- 6.6.2 The Critical Number * -- 6.6.3 The Universal Scaling Parameter, * or σ*? -- 6.6.4 The Nature of the Dendrite-Tip: Steady or Oscillatory? -- 6.7 Three-Dimensional Nonaxisymmetric Spiral Dendritic Modes of Perturbed States -- 6.7.1 Mathematical Formulation of General Three-Dimensional Unsteady Dendritic Growth -- 6.7.2 The Basic State for Dendritic Growth with Nonzero Surface Tension -- 6.7.3 3D Linear Perturbed System -- 6.7.4 Multiple Variables Expansion Solution in the Outer Region -- 6.7.5 Zeroth-Order Approximation of Outer Solution -- 6.7.6 First-Order Approximation of the Outer Solution -- 6.7.7 The Inner Solution near the Singular Point ζc of the Outer Solution -- 6.7.8 Tip Inner Solution in the Tip Region -- 6.7.9 Global Trapped-Wave (GTW) Modes and Quantization Condition -- 6.8 A Brief Summary -- References -- 7 Free Dendritic Growth with Anisotropy -- 7.1 Mathematical Formulation for 2D Dendritic Growth with Anisotropy of Surface Tension -- 7.2 RPE for Basic Steady-State Solutions -- 7.2.1 The Zeroth-Order Approximation (=0) -- 7.2.2 The First-Order Approximation, O(2) -- 7.2.3 Asymptotic Behavior of the Regular Perturbation Expansion Solution as ξ→∞ -- 7.3 Global Interfacial Wave Instabilities of Two-Dimensional Dendritic Growth -- 7.3.1 Linear Perturbed System Around the Basic State -- 7.3.2 Multivariable Expansion Solution in the Outer Region -- 7.3.2.1 Zeroth-Order Approximation -- 7.3.2.2 First-Order Approximation -- 7.3.3 The Inner Equation near the Singular Point ζc -- 7.3.3.1 Case I: |σ0| = O(1) -- 7.3.3.2 Case II: |σ0| 1 -- 7.3.3.3 A Brief Summary -- 7.3.4 Matching Procedure and Connection Conditions -- 7.4 The Quantization Condition of Global Trapped-Wave Modes -- 7.5 The Quantization Condition of Global Low-FrequencyModes. , 7.6 The Selection Conditions for 2D Dendritic Growth -- 7.7 The Effect of Kinetic Attachment at the Interface on Dendritic Growth -- 7.7.1 Linear Perturbed System Around the Basic State -- 7.7.2 The Complex Spectrum of Eigenvalues with |σ0|=O(1) and GTW Instability -- 7.7.2.1 Zeroth-Order Approximation Solutions for GTW Instability -- 7.7.2.2 First-Order Approximation Solutions for GTW Instability -- 7.7.3 The Real Spectrum of Eigenvalues with |σ0|1 and LF Instability -- 7.8 Axially Symmetric Dendritic Growth with Anisotropy -- References -- 8 Three Dimensional Dendritic Growth from an Undercooled Binary Mixture -- 8.1 Mathematical Formulation of the Problem -- 8.2 Basic Steady-State Solution of the System -- 8.2.1 The Zeroth-Order Approximation Solution -- 8.3 Three-Dimensional Linear Perturbed States Around the Basic State -- 8.4 Multiple Variables Expansion Solution in the Outer Region -- 8.5 The MVE Solutions in the Outer Region -- 8.5.1 The Zeroth-Order Approximation -- 8.5.2 First-Order Approximation -- 8.6 The Inner Solutions near the Singular Point ζc -- 8.6.1 Leading-Order Approximation -- 8.7 Tip Inner Solution in the Tip Region -- 8.8 Global Trapped-Wave (GTW) Modes and QuantizationCondition -- 8.9 Axisymmetric Global Modes (m=0) -- 8.10 Comparisons of Theoretical Results with Experimental Data -- References -- 9 Viscous Fingering in a Hele-Shaw Cell -- 9.1 Introduction -- 9.2 Mathematical Formulation of the Problem -- 9.3 The Smooth Finger Solution with Zero Surface Tension -- 9.4 Mathematical Formulation of the Problem with Zero Surface Tension -- 9.4.1 The System of Curvilinear Coordinates (ξ, η) -- 9.4.2 Mathematical Formulation of the Problem in the (ξ,η) Coordinate System -- 9.4.3 The Regular Perturbation Expansion Solution for the Basic State as →0 -- 9.5 The Linear Perturbed System and the Outer Solutions. , 9.5.1 The Linear Perturbed System and the Multiple Variables Expansions -- 9.5.2 The Zeroth-Order Approximation Solutions -- 9.6 The Inner Equation near the Singular Point ζc -- 9.6.1 Case I: |σ0| = O(1) -- 9.6.2 Case II: |σ0| 1 -- 9.7 Eigenvalue Spectra and Instability Mechanisms -- 9.7.1 The Spectrum of Complex Eigenvalues and GTW Instability -- 9.7.1.1 Range 1: 12 ≤λ0 < -- 1 or 0 ≤a< -- 1 -- 9.7.1.2 Range 2: 0 < -- λ0 < -- 12 or a > -- 1 -- 9.7.2 The Spectrum of Real Eigenvalues and LF Instability -- 9.8 Fingering Flow with a Nose Bubble -- 9.8.1 The Basic State of Finger Formation with a Nose Bubble and Its Linear Perturbation -- 9.8.2 The Quantization Conditions for the System with a Nose Bubble -- 9.8.2.1 The GTW Mechanism -- 9.8.2.2 The LF Mechanism -- 9.9 The Selection Criteria of Finger Solutions -- Appendix: The Forms of Some Operators in the System of the Curvilinear Coordinate System (ξ,η) -- References -- 10 Spatially Periodic Deep-Cellular Growth -- 10.1 Introduction -- 10.2 Steady State of the System of Deep-Cellular Growth from a Binary Mixture -- 10.2.1 Mathematical Formulation of the Problem -- 10.2.2 Mathematical Formulation of the Problem in a Curvilinear Coordinate System (ξ, η) -- 10.2.3 The Basic Steady-State Solutions in the Far Field -- 10.2.4 The Mathematical Formulation of the Problem in the Near Field -- 10.2.5 Generalized Asymptotic Solution in the Outer Region -- 10.2.6 Regular Perturbation Expansion of the Solution in the Outer Region -- 10.2.6.1 Zeroth-Order Approximation O(ε0) -- 10.2.6.2 First-Order Approximation O(ε1) -- 10.2.6.3 The Second-Order Approximation O(ε2) -- 10.2.6.4 The Third-Order Approximation O(ε3) -- 10.2.7 Singular Perturbation Expansion Part of the Solution in the Outer Region -- 10.3 The Inner Steady-State Solution in the Root Region and Interface Closure of Deep Cellular Growth. , 10.3.1 Mathematical Formulation of the Problem in the Root Region.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 19 (1998), S. 115-118 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Ultrahigh or high molecular weights of polyethylenes (PE) and their distributions are for the first time determined at 160° or 170°C by gel permeation chromatography (GPC). The thermostability of PE at high temperatures is discussed. In order to calculate the real molecular weight of PE, a new calibration curve is established. For PE with high molecular weight more reliable and accurate results can be obtained by GPC measurements at these temperatures. The application of ultrahigh temperature GPC for polymer characterization is demonstrated in this paper.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 18 (1997), S. 601-607 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A new theoretical formula, used for the determination of the chemical composition distribution of copolymers, is proposed in this paper. The composition distribution of styrene in chlorinated butyl rubber/polystyrene comb graft copolymer was obtained by gel permeation chromatography utilising a combination of refractive index and ultraviolet detection. It is a more convenient and time-saving method for the characterization of the molecular structure parameters of a copolymer compared to the conventional experimental method.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 827-830 
    ISSN: 0887-6266
    Keywords: conformation ; copolymer surfactant ; amphiphilic branch chain ; oxyethylene segment ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The conformation of amphiphilic branch chain in a new type of copolymer surfactants on interface was studied. The results of laser light scattering demonstrated that the branch chain can only lie on the air/water interface. By means of XPS measurement with variable angles, the molecular conformations in different thickness of the copolymer layer were obtained. Depending on the chemical nature of the copolymer surfactants, the oxyethylene segments of the branch chains will have loop-train, train, or loop molecule conformations on the surface. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 827-830, 1997
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2011-12-07
    Description: Two coordination polymers based on 1,6-bis(2-methyl-imidazole-1-yl)-hexane (bimh), namely {[Zn 3 (BTC) 2 (bimh)] · (bimh)} n ( 1 ) and {[Zn(IPA)(bimh)] · (CH 3 CH 2 OH) 0.5 } n ( 2 ) (H 3 BTC = trimesic acid, H 2 IPA = isophthalic acid), were synthesized through hydrothermal reactions. In compound 1 , the zinc(II) ions are bridged by BTC 3– ligands to form an undulating infinite two-dimensional (2D) polymeric network. The 3D networks of 1 show a twofold interpenetrating net. In compound 2 , zinc(II) ions are bridged by IPA 2– ligands to form one-dimensional (1D) helical structures. The 2D structures of 2 are further assembled into 3D networks through aromatic π–π stacking interactions. Both compounds exhibit strong photoluminescence at room temperature and may be good candidates for potential luminescence materials.
    Print ISSN: 0044-2313
    Electronic ISSN: 1521-3749
    Topics: Chemistry and Pharmacology
    Published by Wiley-Blackwell
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  • 6
    Publication Date: 2013-05-25
    Description: In the crystal structure of the title two-dimensional metal–organic polymeric complex, [Cd 2 Cl 4 (C 8 H 14 N 2 O 4 )(H 2 O) 2 ] n , the asymmetric unit contains a crystallographically independent Cd II cation, two chloride ligands, an aqua ligand and half a 2,2′-(piperazine-1,4-diium-1,4-diyl)diacetate (H 2 PDA) ligand, the piperazine ring centroid of which is located on a crystallographic inversion centre. Each Cd II centre is six-coordinated in an octahedral environment by an O atom from an H 2 PDA ligand and an O atom from an aqua ligand in a trans disposition, and by four chloride ligands arranged in the plane perpendicular to the O—Cd—O axis. The complex forms a two-dimensional layer polymer containing [CdCl 2 ] n chains, which are interconnected into an extensive three-dimensional hydrogen-bonded network by C—H...O, C—H...Cl and O—H...O hydrogen bonds.
    Print ISSN: 0108-2701
    Electronic ISSN: 1600-5759
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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  • 7
    Publication Date: 2014-12-28
    Description: Analytical Chemistry DOI: 10.1021/ac503287u
    Print ISSN: 0003-2700
    Electronic ISSN: 1520-6882
    Topics: Chemistry and Pharmacology
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  • 8
    Publication Date: 2015-03-10
    Description: The Journal of Organic Chemistry DOI: 10.1021/jo5027707
    Print ISSN: 0022-3263
    Electronic ISSN: 1520-6904
    Topics: Chemistry and Pharmacology
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  • 9
    Publication Date: 2015-02-20
    Description: Journal of Medicinal Chemistry DOI: 10.1021/jm5012484
    Topics: Chemistry and Pharmacology
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  • 10
    Publication Date: 2015-04-11
    Description: Journal of the American Chemical Society DOI: 10.1021/jacs.5b01705
    Print ISSN: 0002-7863
    Electronic ISSN: 1520-5126
    Topics: Chemistry and Pharmacology
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