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  • Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences  (87)
  • 1
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 69, No. 13 ( 2020), p. 136101-
    Abstract: Silica glasses are composed of multi-oxides, apart from the major component silica. Though it is a general practice in the industries to prepare glasses at specific oxide ratios, the composition rule is largely missing, complicated by the implication of multi-oxides. Necessarily, their interpretation is rooted in chemical units, on which the specific compositions depend. However, in silica glasses the inter-atomic bonding network is continuous and there is no weak bonds, like the inter-molecular ones in molecular compounds, to define molecular entities that carry the chemical information of the materials. As the first stage towards understanding the composition rule, the present paper introduces a new method, so-called the cluster-plus-glue-atom model, to unveil the molecule-like structural units of the glass-relevant oxides. It is pointed out that their respective contributions to the construction of glass networks originate from their characteristic cluster structures, and from which molecule-like structural units are proposed that represent the smallest structural units of these oxides. Oxides participating in the glass network formation mainly present triangular or tetrahedral clusters which are required for a three-dimensional glassy network. For example, the basic network former SiO〈sub〉2〈/sub〉 is formulated as [Si-O〈sub〉4〈/sub〉]Si and contains 32 valence electrons. The intermediate oxides are characterized by the simultaneous formation of both octahedra and tetrahedra. The network modifiers present mainly cubes and octahedra. It is confirmed that the molecule-like structural units of the glass-formation oxides all meet octet rule (that is, the total number of valence electrons contained in each structural unit is an integer multiple of 8), just like common molecules. The proposed concept of molecular structural units sheds a new light on understanding the composition rule of silicate glasses and can eventually solve the long-standing problem of composition design of silica glasses.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2020
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  • 2
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 65, No. 12 ( 2016), p. 127401-
    Abstract: Single-layer FeSe film grown on SrTiO3(001) surface (STO surface) by molecular beam epitaxy has aroused a great research boom ever since the discovery of its huge superconductive energy gap which indicates a possible critical temperature (Tc) higher than the liquid nitrogen temperature. The interface enhanced superconductivity with a Tc above 100 K is revealed in an in situ electrical transport measurement by using a four-point probe installed in a scanning tunneling microscope (STM). Consequent research interest in multi-layer FeSe films grown on STO surface is also increasing. The quality of thick FeSe film, however, has not been well studied yet in previous studies, although it is related to the sample properties including superconductivity. Here, reflection high-energy electron diffraction (RHEED) is used to monitor the growths of multi-layer FeSe thin films on STO surface under different growth conditions. Combing the RHEED results with STM observations taken at various FeSe coverages, we find that the intensity evolution of the RHEED pattern in the early growth stage can be well explained by the step density model but not by the widely known facet model. The intensity evolution of the FeSe(02) diffraction streak exhibits a single-peak oscillation in the growing of the first layer of FeSe. As the oscillation does not depend on the grazing angle of the high-energy electron beam, the FeSe(02) diffraction streak is very suitable for calibrating the FeSe growth rate. In contrast, the intensity of the specular spot exhibits different evolution pattern when the grazing angle of electron beam is changed. It is found in STM observations that only at an appropriate substrate temperature and a growth rate can the high-quality multi-layer FeSe films be grown on STO substrates. If the growth temperature is too high, the FeSe molecules nucleate into islands so that FeSe films with various thickness values eventually come into being on the STO surface. If the growth temperature is too low, a different phase of FeSe film is formed. The optimal growth temperature is in a range from 400 ℃ to 430 ℃, within which a two-layer FeSe film grown at a low rate (0.15 layer/min) coveres the whole STO surface with a negligible number of small FeSe islands. In contrast, a larger growth rate is necessary for growing thicker FeSe film. This is because FeSe islands tend to come into form at steps when the growth rate is too low, which is more distinct in a thicker FeSe film. An STM image of 80-layer FeSe film grown under an optimal condition, i.e., the substrate temperature of 420 ℃ and the growth rate of 2.3 layer/min, shows that it is in a perfect layer-by-layer growth mode. These experimental results are useful for growing high-quality multi-layer FeSe films on STO substrates, which could be critical for studying their physical properties and relevant physical phenomena.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2016
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  • 3
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 65, No. 2 ( 2016), p. 024203-
    Abstract: Time fiducial laser is an important timing marker for different diagnostic instruments in high energy density physics experiments. The probe laser in velocity interferometer system for any reflector (VISAR) is also vital for precise shock wave diagnosis in inertial confinement fusion (ICF) research. Here, time fiducial laser and VISAR probe laser are generated from one source in SG-III laser facility. After generated from a 1064 nm DFB laser, the laser is modulated by an amplitude modulator driven by a 10 GS/s arbitrary waveform generator. Using time division multiplexing technology, the ten-pulse time fiducial laser and the 20 ns pulse width VISAR probe laser are split by a 12 multiplexer and then the time fiducial and VISAR pulses will be selected individually by acoustic-optic modulators. Using this technology, the cost for the system can be reduced. The technologies adopted in the system also include pulse polarization stabilization, high stable Nd: YAG amplification, high precision thermally controlled frequency conversion, fiber coupling, and energy transmission. The fiber laser system is connected to the Nd: YAG rod amplifier stage with polarizing (PZ) fibers to maintain the polarization state. The output laser of Nd: YAG amplification stage is coupled with different kinds of energy transfer fibers to propagate enough energy and maintain the pulse shape for the time fiducial and VISAR probe laser. The input and output fibers are all coupled to the rod amplifiers with high precision and being easy to plug and play for users. Since the time fiducial and imaging VISAR laser system is far from the front end room and located in the target area, the system also uses an arbitrary waveform generator (AWG) to generate the shaped ten-pulse time fiducial laser and 20 ns VISAR laser. This AWG and the other three AWGs used for the main laser pulse of SG-III laser facility will be all synchronized by 10 GHz clock inputs, realizing the smaller than 7 ps (RMS) jitter between the main laser pulse, time fiducial laser and VISAR pulse. After amplification and frequency conversion, the time fiducial laser finally generates 12 beam 2 and 4-beam 3 laserbeams, providing important reference marks for different detectors in the ICF experiments and making it convenient for the analysis of multiple diagnostic data. The VISAR laser pulse is also amplified by the Nd: YAG amplifiers and frequency-converted to 532 nm green light by a thermally controlled LBO crystal, with output energy larger than 20 mJ. Finally, the 532 nm VISAR probe laser beam is coupled with a 1-mm core diameter fused silica optical fiber, and then propagates 30 meters to the imaging VISAR system. The VISAR probe laser has been used in many high energy density physics experiments. The shock wave loading and slowdown processes are measured. Function for measuring velocity history of shock wave front movement in different kinds of materials can be also added to the SG-III laser facility.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2016
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  • 4
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 65, No. 6 ( 2016), p. 068201-
    Abstract: Solid oxide fuel cell (SOFC) is expected to be a crucial technology in future power generation due to its advantages of high efficiency, fuel adaptability, all-solid state, modular assembly, and low pollution. The Ni/YSZ (yttrium-stabilized zirconia) cermet is the most popular anode material in SOFCs. However, a major problem is that it can be easily oxidized, thus resulting in the decline of long-term stability and activity as an anode catalyst. A better performance of the Ni/YSZ cermet can be obtained by improving its microstructure as well as the Ni distribution in it. Interactions between Ni and the yttria-stabilized zirconia (YSZ) (111) or oxygen-enriched YSZ(111) (YSZ+O) surface are studied in terms of the first-principles method based on the density functional theory with particular focus put on the activity of the Ni atom at the interface. The geometric and electronic structures of CO and O2 on the Ni1 (the single Ni atom)/YSZ and Ni1/YSZ+O surfaces are also studied. It is found that the Ni atom tends to be adsorbed to O sites and away from the Y atoms on both the surfaces. The most favorable adsorption site is the oxygen vacancy, which has an adsorption energy of 2.85 eV. Compared with YSZ, the single Ni atom loses 1.06 electrons and is oxidized as Ni+ on YSZ+O, which produces a strong interaction between the Ni atom and YSZ+O. Strong adsorption is mainly attributed to the interaction between Ni 3d and Ou 2p orbitals. And the oxidation of Ni can lead to the decrease of electrocatalytic activity of the Ni catalyst. The d-band DOS (density of states) peaks of the Ni1/YSZ+O are lower than that of the Ni1/YSZ, and the corresponding d-band centers are shifted away from the Fermi level to lower energy with the d value of -3.69 eV; therefore the CO and O2 adsorption is weakened. While the adsorption energy for CO on the Ni1/YSZ+O (0.42 eV) is much lower than that on the Ni1/YSZ surface (1.78 eV). In addition, the adsorbed CO gains 0.07 electrons, less than those on the Ni1/YSZ surface (0.34 e). The adsorption energy of O2 on Ni1/YSZ+O also decreases (0.34 eV) and gains fewer electrons (0.24 e) as compared with the corresponding values (2.57 eV, 1.15 eV) on Ni1/YSZ. Results would improve our understanding on the mechanism of oxidation of Ni on the Ni/YSZ anode of SOFCs and would be of great importance for designing highly active catalysts used for fuel cells.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2016
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  • 5
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2012
    In:  Acta Physica Sinica Vol. 61, No. 21 ( 2012), p. 214201-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 61, No. 21 ( 2012), p. 214201-
    Abstract: A novel optical element, vaulted axicon, is proposed for the first time in this paper. We analyze the distribution of light field with diffraction theory, and simulate the intensity distribution behind vaulted axicon. The result shows that multi-bottle beam can be obtained after a plane wave has passed through an vaulted axicon, moreover the intensity of the bottle beam is very high in the focal region because of the energy of spherical wave is significant concentrated in this region. The simulation and comparison show that the intensity around the bottle beam generated by vaulted axicon is far higher than that generated by superposition of two Bessel beams, therefore the particle trapping efficiency can be significantly increased. By comparing the scattering forces of bottle beam generated by the two methods, we demonstrate that the bottle beam generated by vaulted axicon is superior in particle trapping.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2012
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  • 6
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 63, No. 13 ( 2014), p. 133203-
    Abstract: Low-frequency collective vibrational modes of biomolecules which often lie in terahertz (THz) band, make the terahertz time-domain spectroscopy (THz-TDS) an important technique for molecular identification and medicine quality inspection. Distinctive THz spectra between L-asparagine and its monohydrate were observed and the dehydration process of L-asparagine monohydrate was tracked by THz-TDS. Experiments indicate that THz wave is sensitive to phase transitions in crystals, dehydration process, and weak molecular interactions. Multi-techniques including differential scanning calorimetry and thermogravimetry, Fourier transform infrared spectroscopy, and powder X-ray diffraction are performed to investigate the thermodynamic properties, intermolecular and intramolecular vibrations, and molecular packing patterns of L-asparagine and its monohydrate. These measurements support the reliability of THz spectroscopy. To simulate and analyse the vibration modes of L-asparagine monohydrate, density functional theory calculations are performed using a Perdew Burke and Ernzerhof generalized gradient approach; the results agree well with the experimental observations.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2014
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  • 7
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 62, No. 10 ( 2013), p. 104219-
    Abstract: Based on the Hankel wave theory, reconstruction property of Bessel beam generated by incoherent source is analyzed. The section light intensity distribution of Bessel beam after on-axis circular obstacle is simulated by optical design software ZEMAX. Light emitting diode (LED) has a certain spectrum width, therefore we describe it by using a continuous spectrum with a certain range of spectral width. From the simulation results we can see visually that Bessel beam gradually realizes the reconstruction after circular obstacles on-axial shelter. It is proved that LED has the reconstruction property. We use LED and axcion element to generate Bessel beam. This Bessel beam passes though an on-axis circular obstacle and an on-axis square obstacle. We take the pictures of the section light intensity distribution at different positions. The reconstruction properties of the LED incoherent source are verified. Experimental results accord well with the simulation results.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2013
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  • 8
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 69, No. 12 ( 2020), p. 127701-
    Abstract: As the electric field can affect the polarization and dielectric constant, the phenomenological coefficient 〈i〉a〈/i〉〈sub〉0〈/sub〉 is an implicit function of electric field. The phenomenological coefficient 〈i〉a〈/i〉〈sub〉0〈/sub〉 is determined by the polarization and the reciprocal of permittivity, and a nonlinear function of electric field in the ferroelectric phase regime. In the paraelectric phase regime, however, 〈i〉a〈/i〉〈sub〉0〈/sub〉 is merely subjected to the reciprocal of permittivity, and also a nonlinear function of electric field. In this paper, we investigate the electric field dependence of phenomenological coefficient in ferroelectric copolymers, terpolymers and Ba〈sub〉0.85〈/sub〉Ca〈sub〉0.05〈/sub〉Sr〈sub〉0.1〈/sub〉TiO〈sub〉3〈/sub〉 ceramics. It is indicated that the phenomenological coefficient increases with the increasing electric field, the maximum value is obtained to be about 2 times the original value. Moreover, the electrocaloric strength is used to measure the magnitude of electrocaloric effect of electrocaloric materials in an external electric field. It can be used to find out novel and efficient electrocaloric materials through studying the electrocaloric strength. Based on the thermodynamic theory, the analytical expression of electrocaloric strength is deduced. It is found that the phenomenological coefficient, phase transition, specific heat capacity, and permittivity versus temperature peak value at the phase transition temperature have a clear influence on the electrocaloric strength. The expression can be applied to 1〈sup〉st〈/sup〉 order, 2〈sup〉nd〈/sup〉 order phase transition materials and relaxor ferroelectrics.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2020
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  • 9
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2016
    In:  Acta Physica Sinica Vol. 65, No. 6 ( 2016), p. 060301-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 65, No. 6 ( 2016), p. 060301-
    Abstract: In this paper, the resonance transmission of discrete time quantum walk is studied when it walks on one-dimensional lattice in which two-phase defects or a piece of phase defects exists. The quasi energy of discrete time quantum walk has a unique dispersion relation with the momentum, from which we first discuss the wave velocity direction versus the values of momentum, and distinguish the incident wave and the reflected wave. The gap between two energy bands depends on the parameters of coincident operator, so the phase defects, which break down the translation invariance of quantum walk on uniform lattices, can be regarded as an analogue of quantum potential. Then we use the condition of energy conversion at the boundary points to obtain the transmission rate and discuss its variation with the incident momentum for different strengths and widths of defects in detail. The multiple resonant peaks are observed due to the enhanced interference effect. Different resonant behaviors are shown when the strength of defect is less or greater than /2, correspondingly the resonances occur in a wide region of incident momentum or the sharp resonant peaks appear at discrete values of momentum. Under the condition of strong defect strength, i.e., approaching to , the qualitative relation between the number of resonant peaks and the widths of defect region is given. The number of resonant peaks is 2(N-1) when the two phase defects are located at N sites symmetric about the origin, while the number is 2N when a piece of phase defects is located at -N to N sites. In the case of a piece of phase defects, we also present the phase diagram in parameter space of (k, ) to show the discrete time of quantum walk propagating or tunneling through the defect region. In terms of this phase diagram, the variations of transmission rate with the incident momentum are reasonably explained. One special phenomenon is that the quantum walk is almost totally reflected in the tunneling case except for =/2 and k being slightly off -/2. Moreover, this behavior seems little affecting the defect strength, just similar to a classical particle. As a result of this research, we hope to deepen the insight of the quantum walk and provide methods to control the spreading of quantum walk through artificial defects.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2016
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  • 10
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 61, No. 24 ( 2012), p. 244104-
    Abstract: In this paper, the self-reconstructing property of periodic bottle beam generated by the Bessel beam interfering behind obstacle is analyzed. Based on the Hankel wave theory, we analyze the principle of self-reconstruction. According to the diffraction theory, we derive the evolution of beam behind an on-axis circular obstacle. The results show that the periodic bottle beam has the self-reconstructing property and the reconstructed beam maintains the beam intensity distribution. The research results are significant for realizing the multi-plane micro-manipulation by using a periodic bottle beam.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2012
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