Description: Direct observations indicate that the global ocean oxygen inventory is decreasing. Climate models consistently confirm this decline and predict continuing and accelerating ocean deoxygenation. However, current models (1) do not reproduce observed patterns for oxygen changes in the ocean’s thermocline; (2) underestimate the temporal variability of oxygen concentrations and air–sea fluxes inferred from time-series observations; and (3) generally simulate only about half the oceanic oxygen loss inferred from observations. We here review current knowledge about the mechanisms and drivers of oxygen changes and their variation with region and depth over the world’s oceans. Warming is considered a major driver: in part directly, via solubility effects, and in part indirectly, via changes in circulation, mixing and oxygen respiration. While solubility effects have been quantified and found to dominate deoxygenation near the surface, a quantitative understanding of contributions from other mechanisms is still lacking. Current models may underestimate deoxygenation because of unresolved transport processes, unaccounted for variations in respiratory oxygen demand, or missing biogeochemical feedbacks. Dedicated observational programmes are required to better constrain biological and physical processes and their representation in models to improve our understanding and predictions of patterns and intensity of future oxygen change.

Description: Simulated transient-tracer distributions (tritium, 3H3, freons) on the isopycnal horizons σ0=26.5 and 26.8 kg m−3 are presented for the East Atlantic, 10° −40°N. Tracer transport is modeled by employing a baroclinic flow field based on empirical data in a kinematic isopycnal advection-diffusion numerical model, in which winter convection is taken as the mechanism of communication with the ocean surface layer, and the isopycnal diffusivity is a free parameter. Diapucnic transport is ignored. The simulations employ time-dependent tracer boundary conditions, which are constructed on the basis of available observations. Simulations are compared to data obtained on a meridional section in 1981 (F/S Meteor, cruise 56/5). Best simulations were obtained by means of a subjective optimization procedure. On both levels, the observed distributions and the best simulated distributions agree well. The fact that the surface boundary conditions and interior distributions of the tracers are distinctly different leads us to the conclusion that our model provides a consistent description of upper main-thermocline ventilation and interior transport Surface-water densities in February are found to represent adequately the winter outcrop boundaries with an uncertainty of about ±300 km across. The required isopycnal diffusivity south of 29°N is 1700 m2 s−1, and 2900 m2 s−1 further north (+70/−40%). Interior transport is found to be predominantly advective. Advective ventilation across 30.5°N east of 33°W amounts to only 12% and 40% for the 26.5 and 26.8 horizons of the total ventilation rates reported by Sarmiento. The North Atlantic/South Atlantic Central Water boundary near 15°N is found to be predominantly determined by advection.

Description: Changes in the ventilation of the oxygen minimum zone (OMZ) of the tropical North Atlantic are studied using oceanographic data from 18 research cruises carried out between 28.5° and 23°W during 1999–2008 as well as historical data referring to the period 1972–85. In the core of the OMZ at about 400-m depth, a highly significant oxygen decrease of about 15 μmol kg−1 is found between the two periods. During the same time interval, the salinity at the oxygen minimum increased by about 0.1. Above the core of the OMZ, within the central water layer, oxygen decreased too, but salinity changed only slightly or even decreased. The scatter in the local oxygen–salinity relations decreased from the earlier to the later period suggesting a reduced filamentation due to mesoscale eddies and/or zonal jets acting on the background gradients. Here it is suggested that latitudinally alternating zonal jets with observed amplitudes of a few centimeters per second in the depth range of the OMZ contribute to the ventilation of the OMZ. A conceptual model of the ventilation of the OMZ is used to corroborate the hypothesis that changes in the strength of zonal jets affect mean oxygen levels in the OMZ. According to the model, a weakening of zonal jets, which is in general agreement with observed hydrographic evidences, is associated with a reduction of the mean oxygen levels that could significantly contribute to the observed deoxygenation of the North Atlantic OMZ.

Description: Chlorofluorocarbon (component CFC-11) and hydrographic data from 1997, 1999, and 2001 are presented to track the large-scale spreading of the Upper Labrador Sea Water (ULSW) in the subpolar gyre of the North Atlantic Ocean. ULSW is CFC rich and comparatively low in salinity. It is located on top of the denser “classical” Labrador Sea Water (LSW), defined in the density range σΘ = 27.68–27.74 kg m−3. It follows spreading pathways similar to LSW and has entered the eastern North Atlantic. Despite data gaps, the CFC-11 inventories of ULSW in the subpolar North Atlantic (40°–65°N) could be estimated within 11%. The inventory increased from 6.0 ± 0.6 million moles in 1997 to 8.1 ± 0.6 million moles in 1999 and to 9.5 ± 0.6 million moles in 2001. CFC-11 inventory estimates were used to determine ULSW formation rates for different periods. For 1970–97, the mean formation rate resulted in 3.2–3.3 Sv (Sv ≡ 106 m3 s−1). To obtain this estimate, 5.0 million moles of CFC-11 located in 1997 in the ULSW in the subtropical/tropical Atlantic were added to the inventory of the subpolar North Atlantic. An estimate of the mean combined ULSW/LSW formation rate for the same period gave 7.6–8.9 Sv. For the years 1998–99, the ULSW formation rate solely based on the subpolar North Atlantic CFC-11 inventories yielded 6.9–9.2 Sv. At this time, the lack of classical LSW formation was almost compensated for by the strongly pronounced ULSW formation. Indications are presented that the convection area needed in 1998–99 to form this amount of ULSW exceeded the available area in the Labrador Sea. The Irminger Sea might be considered as an additional region favoring ULSW formation. In 2000–01, ULSW formation weakened to 3.3–4.7 Sv. Time series of layer thickness based on historical data indicate that there exists considerable variability of ULSW and classical LSW formation on decadal scales.

Description: The Southern Hemisphere Subtropical Front (STF) is a narrow zone of transition between upper-level subtropical waters to the north and subantarctic waters to the south. It is found near 40 degrees S across the South Atlantic and South Indian Oceans and is associated with an eastward geostrophic current band, The current band in each basin is found at or just north of the surface front except near the eastern boundaries where most of the subtropical waters turn north into the eastern limbs of the subtropical gyres. The bands associated with the STF are thus distinct features separated from the strong zonal flows of the Antarctic Circumpolar Current farther south. The authors have referred to the current bands in the two respective oceans as the South Atlantic Current and the South Indian Ocean Current. In this paper the authors use the historical database from the South Pacific Ocean to investigate the geostrophic flow associated with the STF there. The STF extends across the southern Tasman Sea from south of Tasmania to southern New Zealand, and a weak eastward flow appears to be associated with it. The transport amounts to only about 3 Sv (1Sv = 10(6) m(3) s(-1)), little of which passes south of New Zealand. Mixing within the eddy-rich Tasman Sea may account for this weakness, while also setting up another more significant front in the northern Tasman Sea, the Tasman Front. It branches off from the East Australian Current toward the north of New Zealand, along which moves a flow of about 14 Sv. After passing north of New Zealand, a portion of this current flows east to contribute to a current band near 30 degrees S, while another portion turns south as the East Auckland Current and meets with subantarctic waters near Chatham Rise (44 degrees S), thus reestablishing the STF. An enhanced eastward current band is associated with the front there, one that extends across the remainder of the South Pacific and is referred to as the South Pacific Current. In comparison with its counterparts in the other basins, which typically begin by carrying 30 Sv (Atlantic) to 60 Sv (Indian) in the upper 1000 m in their western portions before weakening to 10-15 Sv in the east, the South Pacific Current is weak. Near Chatham Rise, it starts with a transport of approximately 5 Sv, and it remains near this strength as it shifts gradually north across the basin toward South America. The current appears to split into two smaller bands in the region of 115 degrees-85 degrees W, while near 28 degrees 5, 83 degrees W it begins to turn more strongly north and becomes shallower and weaker. Potential vorticity distributions indicate that this current acts as an impediment toward the northward spreading of Antarctic Intermediate Water, But why the South Pacific Current east of New Zealand should be so much weaker than its counterparts in the other basins is not particularly clear. It may be due to the presence of New Zealand and other topographic barriers to deep now east of Australia, to the axis of the subtropical gyre in the South Pacific shifting more rapidly southward with depth than those elsewhere, thus causing greater reductions in the underlying zonal velocities, and to strong poleward eddy heat and salt fluxes in the other two basins leading to smaller cross-STF gradients in the Pacific.

Description: Ocean models predict a decline in the dissolved oxygen inventory of the global ocean of one to seven per cent by the year 2100, caused by a combination of a warming-induced decline in oxygen solubility and reduced ventilation of the deep ocean1, 2. It is thought that such a decline in the oceanic oxygen content could affect ocean nutrient cycles and the marine habitat, with potentially detrimental consequences for fisheries and coastal economies3, 4, 5, 6. Regional observational data indicate a continuous decrease in oceanic dissolved oxygen concentrations in most regions of the global ocean1, 7, 8, 9, 10, with an increase reported in a few limited areas, varying by study1, 10. Prior work attempting to resolve variations in dissolved oxygen concentrations at the global scale reported a global oxygen loss of 550 ± 130 teramoles (1012 mol) per decade between 100 and 1,000 metres depth based on a comparison of data from the 1970s and 1990s10. Here we provide a quantitative assessment of the entire ocean oxygen inventory by analysing dissolved oxygen and supporting data for the complete oceanic water column over the past 50 years. We find that the global oceanic oxygen content of 227.4 ± 1.1 petamoles (1015 mol) has decreased by more than two per cent (4.8 ± 2.1 petamoles) since 1960, with large variations in oxygen loss in different ocean basins and at different depths. We suggest that changes in the upper water column are mostly due to a warming-induced decrease in solubility and biological consumption. Changes in the deeper ocean may have their origin in basin-scale multi-decadal variability, oceanic overturning slow-down and a potential increase in biological consumption11, 12.

Description: In this paper, the historical hydrographic database for the south Indian Ocean is used to investigate (i) the hydrographic boundary between the subtropical gyre and the Antarctic Circumpolar Current (ACC), the subtropical front (STF), and especially (ii) the southern current band of the gyre. A current band of increased zonal speeds in the upper 1000 m is found just north of the STF in the west near South Africa and at the surface STF in the open Indian Ocean until the waters off the coast of Australia are reached. As neither any other investigation of this current nor a name for it are known, the flow has been called the South Indian Ocean Current (SIOC). This name is anologous to the same current band in the South Atlantic Ocean, the South Atlantic Current. The STF is located in the entire south Indian Ocean near 40-degrees-S. The associated current band of increased zonal speeds is the SIOC, which is found at or north of the STF. East of 100-degrees-E the SIOC separates from the STF and continues to the northeast. The zonal flow south of the STF is normally weak and serves to separate the South Indian Ocean and Circumpolar currents. Near Africa the SIOC has a typical volume transport of 60 Sv (1 Sv = 10(6) m3 s-1) in the upper 1000 m relative to deep potential density surfaces of sigma(4) = 45.87 kg m-3 (2800-3500 m) or sigma(2) = 36.94 kg m-3 (1500-2500 m). Near western Australia the SIOC is reduced to about 10 Sv as it turns to the northeast.

Description: Historical data from the region between the Greenwich meridian and the African continental shelf are used to compute the offshore geostrophic transport of the Benguela Current. At 32°S, the Benguela Current is located near the African coast, transporting about 21 Sv (1 Sv = 106 m3 s−1) of surface water toward the north relative to a potential density surface lying between the upper branch of Circumpolar Deep Water and the North Atlantic Deep Watar. Two warm core eddies of probable Agulhas Current origin an observed west of the Benguela Current at 32°S. Near 30°S, the Benguela Current turns toward the northwest and begins to separate from the eastern boundary. It carries about 18 Sv of surface water across 28°S. The current then turns mainly toward the west to flow over a relatively deep segment of the Walvis Ridge south of the Valdivia Bank. A surface current with northward surface of about 10 cm s−1 flows along the western side of the Valdivia Bank, while another northward surface current flows at about 20 cm s−1 some 300 km west of the bank. About 3 Sv of surface now do not leave the Cape Basin south of the Vaidivia Bank, but instead drift northward as a wide. sluggish flow out of the northern end of the Cape Basin. Because of the more southerly seaward extensions of most of the Benguela Current, there are no deep-reaching interactions observed between this current and the cyclonic gyre in the Angola Basin east of the Greenwich meridian. Beneath the surface layer, about 4–5 Sv of Antarctic Intermediate Water are carried northward across 32° and 28°S by the Benguela Current, essentially all of which turns westward to cross the Greenwich meridian south of 24°S.

Description: Data from a surface mooring located in the Sargasso Sea at 34°N, 70°W between May 1982 and May 1984 were compared with satellite data to investigate large diurnal sea surface temperature changes. Mooring and satellite measurements are in excellent agreement for those days on which no clouds covered the site at the time of the satellite pass. During the summer half-year at this site, there is a 20% charm of diurnal warming of more than 0.5°C, with values of up to 3.5°C observed in the two-year period. Diurnal warming observed at the mooring has been simulated well by a one-dimensional model driven by local beat and momentum fluxes. Under the conditions of very light wind and strong insolation that produce the Largest surface warming, the surface mixed-layer depth reduces to the convection depth, and wind-mixing becomes unimportant. The thermal response is then limited to depths between 1 and 2 m, making it likely that such events have been underreported in routine ship observations. In all cases observed, the spatial extent of warming events as determined by satellite data are well correlated with the corresponding atmospheric pressure patterns. Conditions giving rise to the largest diurnal warming events are often associated with a westward-extending ridge of the Bermuda high. In the region studied, 57°–75°W and 29°–43°N, diurnal warming of more than 1°C was found on occasion to cover areas in excess of 300 000 km2, with warming of more than 2°C coveting areas in excess of 130 000 km2.

Description: In this paper we use the historical hydrographic data base for the South Atlantic Ocean to investigate (i) the hydrographic boundary between the subtropical gyre and the Antarctic Circumpolar Current (ACC), the Sub-tropical Front (STF), and (ii) the southern current band of the gyre, which is called the South Atlantic Current (SAC). The STF begins in the west in the Brazil-Falkland (Malvinas) confluence zone, but at locations at and west of 45°W this front is often coincident with the Brazil Current front. East of 45°W the STF appears to be a distinct feature to at least the region south of Africa, whereupon it continues into the Indian Ocean. The associated current band of increased zonal speed is the SAC, which, except for one instance, is found at or north of the surface STF until Indian Ocean water from the Agulhas retroflection is reached. A reversal of baroclinicity in the STF is observed south of a highly saline Agulhas ring, causing the SAC to separate from the STF and turn north into the Benguela Current. Zonal flow south of the STF is generally weak and serves to separate the South Atlantic and circumpolar currents. In the Argentine Basin, the SAC has a typical volume transport of 30 Sv (1 Sv = 106m3s−1) in the upper 1000 m relative to a deep potential density surface (σ4 = 45.87 kg m−3), and can be as high as 37 Sv. It is thus comparable to, or stronger than, the Brazil Current. In the Cape Basin, the transport of the SAC is reduced to about 15 SY before it turns north to feed the Benguela Current. In late 1983 this flow was joined by about 8 Sv of water from the Agulhas Current.