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  • AIP Publishing  (6)
  • 1
    In: Journal of Applied Physics, AIP Publishing, Vol. 79, No. 8 ( 1996-04-15), p. 4236-4241
    Abstract: A large and highly oriented Bi2Sr2CaCu2Oy crystal with only a single domain was progressively air annealed at 500 and 750 °C for 4 and 8 h. Measurements of ac susceptibility showed that Tc (onset) and ΔTc (10%–90% of the complete transition) of the crystal were 74 and 3 K (as grown), 85 and 0.6 K (annealed at 500 °C for 4 h), and 89 and 2.5 K (annealed at 750 °C for 8 h), respectively. To explain this typical change of ΔTc with annealing temperature, a full structural characterization by x-ray diffraction in the b*c* plane and by Laue photographs of the crystal as grown and after each annealing treatment was carried out. Apart from variations of the lattice parameters, it is noted that the smaller the ΔTc, the more highly oriented and structurally homogeneous the crystal. We explain the annealing effect on ΔTc by variations in crystallinity, structural homogeneity, and surface phase decomposition, and the changes in oxygen stoichiometry caused by the annealing process.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1996
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 2
    In: AIP Advances, AIP Publishing, Vol. 10, No. 3 ( 2020-03-01)
    Abstract: The balance of electrical and mechanical properties of conjugated polymers is extremely significant toward extending applications in wearable and implantable devices. Blending conjugated polymers with organic elastomers is a straightforward and facile way to improve the deformability of the materials. In this work, poly(3-hexylthiophene) (P3HT) nanowires were blended with a polydimethylsiloxane (PDMS) elastomer via spin-coating on two kinds of substrates, SiO2/Si and PDMS. Organic field-effect transistors based on P3HT/PDMS blending films were tested to evaluate the electronic properties of the films. The phase separation structures, surface morphologies, and the deformation under stretching were characterized by x-ray photoelectron spectroscopy, atomic force microscopy, and optical microscopy, respectively. A stratified structure with P3HT nanowires condensed at the interface formed on SiO2/Si, while an interpenetrating double networks structure yielded on the PDMS substrate. The double networks structure affords P3HT/PDMS blending films not only similar field-effect mobility in a wide range of P3HT content (≥5 wt. %) but also much enhanced stretching performance with respect to the net P3HT film. This double networks structure induced by polarity selection of the substrate might provide an efficient route to prepare flexible blending films with balanced mechanical and electrical behaviors.
    Type of Medium: Online Resource
    ISSN: 2158-3226
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2583909-3
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  • 3
    In: Applied Physics Letters, AIP Publishing, Vol. 104, No. 3 ( 2014-01-20)
    Abstract: The effect of gamma ray irradiation on silicon nanowires was investigated. Here, an additional defect emerged in the gamma-ray-irradiated silicon nanowires and was confirmed with electron spin resonance spectra. 29Si nuclear magnetic resonance spectroscopy showed that irradiation doses had influence on the Q4 unit structure. This phenomenon indicated that the unique core/shell structure of silicon nanowires might contribute to induce metastable defects under gamma ray irradiation, which served as a satisfactory model to investigate defects at the interface of Si/SiOx.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2014
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 4
    In: Applied Physics Letters, AIP Publishing, Vol. 106, No. 12 ( 2015-03-23)
    Abstract: In this letter, we report perovskite solar cells with thin dense Mg-doped TiO2 as hole-blocking layers (HBLs), which outperform cells using TiO2 HBLs in several ways: higher open-circuit voltage (Voc) (1.08 V), power conversion efficiency (12.28%), short-circuit current, and fill factor. These properties improvements are attributed to the better properties of Mg-modulated TiO2 as compared to TiO2 such as better optical transmission properties, upshifted conduction band minimum (CBM) and downshifted valence band maximum (VBM), better hole-blocking effect, and higher electron life time. The higher-lying CBM due to the modulation with wider band gap MgO and the formation of magnesium oxide and magnesium hydroxides together resulted in an increment of Voc. In addition, the Mg-modulated TiO2 with lower VBM played a better role in the hole-blocking. The HBL with modulated band position provided better electron transport and hole blocking effects within the device.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2015
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 5
    Online Resource
    Online Resource
    AIP Publishing ; 2020
    In:  Journal of Applied Physics Vol. 127, No. 24 ( 2020-06-28)
    In: Journal of Applied Physics, AIP Publishing, Vol. 127, No. 24 ( 2020-06-28)
    Abstract: The flow-induced crystallization (FIC) is commonly encountered in the polymer industry as more than 70% of commercial polymers are crystalline, which needs to be processed before the final application. The complicated external flow field, i.e., shear or extensional flow, results in a great challenge in understanding the FIC phenomenon from both general thermodynamics and detailed molecular level aspects. The current tutorial first describes the general phenomenon of FIC from the aspect of different morphologies and enhanced kinetics induced by the flow. Second, characterization methods for monitoring FIC are introduced. Here, the in situ synchrotron x-ray scattering and non-equilibrium molecular dynamics simulation are selected as typical examples. Then, the theoretical descriptions of FIC are summarized from the aspects of molecular origin and thermodynamics. The coil–stretch transition theory and later developed stretched network theory are highlighted, where the former mainly accounts for polymer dilute solution and the latter for highly entangled cases. Also, multi-step features for the formation of various intermediate states during flow-induced nucleation are depicted. Despite non-equilibrium nature, the FIC can still be treated by thermodynamics, especially under weak flow conditions. The classic entropy reduction model is introduced together with later modifications. In all, understanding the fundamental mechanism of FIC is crucial for optimizing external processing parameters and internal molecular characteristics, and useful to guide current or further applied techniques.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 6
    Online Resource
    Online Resource
    AIP Publishing ; 2022
    In:  Physics of Fluids Vol. 34, No. 7 ( 2022-07-01)
    In: Physics of Fluids, AIP Publishing, Vol. 34, No. 7 ( 2022-07-01)
    Abstract: Wettability determines the spreading or adherence behavior of fluids at the solid surface and significantly influences the displacement and entrapment of multiphase fluids in porous media. The present study sets out to determine how wettability controls the imbibition physics of oil and water in a matrix–fracture medium. The displacement and distribution characteristics of fluids, the types of flow regimes, and the fluid morphology under various conditions were revealed in depth. The influences of wettability on oil recovery and energy conversion were analyzed. Finally, the application of the conventional scaling model to simulated imbibition data was also discussed. Results show that the imbibition front is complete and stable in a water-wet medium with the one-end open boundary condition. There are three flow regimes occurring in countercurrent imbibition, depending on the wettability and Ca (capillary number) situations. Increasing θ (contact angle, the affinity of wetting phase to the solid) or Ca can shift the flow pattern from the capillary regime to the capillary-viscous regime to the viscous regime. Additionally, the imbibition oil recovery is greatly affected by wettability, and a more water-wet state does not signify a larger oil recovery. There is a power-law relationship between the oil recovery and the fractal dimension of the nonwetting phase. On the other hand, we performed the energy conversion analysis in the strongly water-wet condition. The external work is positive for both the capillary-viscous and viscous regimes and declines with the decreased Ca. Oil recovery could be linked to the surface energy ratio to some degree, which is relevant to Ca. For the capillary regime, oil recovery is proportional to the final reduced surface energy and does not have an evident relationship with the dissipation energy ratio. Through scaling the recovery factor data vs time via the linear, the power-law, and the conventional models, we find that the conventional scaling model can be used to fit the data point, and the fitting performance is good when Ca is relatively high. However, the linear model is more appropriate when scaling the data in low Ca. Overall, our pore-scale simulation study could pave the way for a further step toward investigating other influencing factors on imbibition behaviors of fluids in more complex media like natural rock materials, which exhibit strong heterogeneity of wettability and pore structure.
    Type of Medium: Online Resource
    ISSN: 1070-6631 , 1089-7666
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 1472743-2
    detail.hit.zdb_id: 241528-8
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