In:
The Journal of Chemical Physics, AIP Publishing, Vol. 19, No. 10 ( 1951-10-01), p. 1247-1249
Abstract:
Ethylene, acetylene, and butadiene are the predominant gaseous products of the reaction of sodium vapor with vinyl iodide in the ``diffusion flame.'' From the experimental evidence it is likely that these are formed by the disproportionation and recombination of vinyl radicals. In the presence of hydrogen, ethylene is also formed by the reaction C2H3+H2=C2H4+H. More vinyl iodide than sodium is consumed in the reaction and a nonvolatile organic iodide is formed. This has an important bearing on the calculation of the rate constant of the primary process.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1951
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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