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  • AIP Publishing  (3)
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  • AIP Publishing  (3)
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  • 1
    Online Resource
    Online Resource
    AIP Publishing ; 1960
    In:  The Journal of Chemical Physics Vol. 33, No. 1 ( 1960-07-01), p. 56-64
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 33, No. 1 ( 1960-07-01), p. 56-64
    Abstract: Intensities of the absorption bands observed with a thin sample of polycrystalline benzene have been measured relative to the absorption of v20 at 1036 cm—1. The gas-phase-allowed fundamentals are much the strongest bands in the spectrum. The relative intensities of these fundamentals are considerably different from the relative intensities in the gas or liquid phase. The experimental errors are discussed in detail with the conclusion that the observed difference in relative intensities are well outside any conceivable experimental errors. As a result, it is concluded that existing theories of spectra in condensed phases must be modified to predict different behaviour for each fundamental vibration. Finally, attention is drawn towards some of the anomalies still existing in the assignment of vibrational frequencies in the benzene molecule.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1960
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 2
    In: Journal of Applied Physics, AIP Publishing, Vol. 128, No. 17 ( 2020-11-07)
    Abstract: REBa2Cu3Ox (REBCO) coated conductors are an enabling technology for & gt;1 GHz nuclear magnetic resonance spectrometers that need & gt;23.5 T solenoids, compact high-field fusion reactors beyond the International Thermonuclear Experimental Reactor, and 20 T class accelerator magnets. An in-depth understanding of stress and strain management is critically needed for these applications. Here, we report experimental data and an analysis of damages of REBCO-coated conductors in several scenarios relevant for their applications in high-field magnets and unique to their multi-layer thin film structure. The examined scenarios include failure induced by quench, failure induced by epoxy impregnation, and failure induced by a combination of epoxy impregnation and quench. The root cause is film blistering and peeling induced by thermally interfacial stresses characteristic of multilayered heteroepitaxial thin film structures on thick substrates utilized. The quantitative stress analysis is introduced using simple and easy to use formulas and clearly indicates how materials and structural characteristics affect the magnitude and the distribution of stresses and deflections. Finally, a simple method is introduced for removing degradation of REBCO coated conductors due to epoxy impregnation. Our data and analysis help our understanding of the practical limit of REBCO-coated conductors and can be utilized as a guidance for the physical design of REBCO coated conductors and high-current cables assembled from them and for minimizing damages.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 3
    Online Resource
    Online Resource
    AIP Publishing ; 1960
    In:  The Journal of Chemical Physics Vol. 33, No. 1 ( 1960-07-01), p. 233-236
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 33, No. 1 ( 1960-07-01), p. 233-236
    Abstract: The intensity of the absorption due to v20 at 1036 cm—1 in solid benzene at —170°C has been measured relative to the intensity of this band measured with the same benzene film in the liquid phase at 25°C. From this ratio and from the value for the absolute intensity of v20 in liquid benzene reported by Hisatsune and Jayadevappa, a value of 670±90 darks for the absolute intensity of v20 in solid benzene has been obtained. Using the relative intensity measurements reported earlier, the absolute intensities of all the gasphase-allowed fundamentals have been estimated. All the intensities in the crystal are lower than the values in the liquid phase, but the behavior of the bands at 1036 and 1480 cm—1 is not too abnormal. However, the intensities of the fundamentals at 687 and 3060 cm—1 decrease markedly from the gas-phase values, the former by a factor greater than two, the latter by a factor of seven. Thus, it is concluded that the interactions in the solid which cause the intensity to change are quite specifically limited to these two normal modes. Analysis of the data using the isotope intensity sum rules modified for use with crystals reveals that the intensity changes observed are much greater than those expected due to simple distortion of the norma coordinates by the crystal field.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1960
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
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