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  • AIP Publishing  (233)
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  • AIP Publishing  (233)
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  • 1
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 145, No. 12 ( 2016-09-28)
    Abstract: We present a joint experimental and theoretical study on the high-pressure behavior of bromine confined in the one-dimensional (1D) nanochannels of zeolite AlPO4-5 (AFI) single crystals. Raman scattering experiments indicate that loading bromine into AFI single crystals can lead to the formation of bromine molecular chains inside the nanochannels of the crystals. High-pressure Raman and X-ray diffraction studies demonstrate that high pressure can increase the length of the confined bromine molecular chains and modify the inter- and intramolecular interactions of the molecules. The confined bromine shows a considerably different high-pressure behavior to that of bulk bromine. The pressure-elongated bromine molecular chains can be preserved when the pressure is reduced to ambient pressure. Theoretical simulations explain the experimental results obtained from the Raman spectroscopy and X-ray diffraction studies. Furthermore, we find that the intermolecular distance between confined bromine molecules gradually becomes comparable to the intramolecular bond length in bromine molecules upon compression. This may result in the dissociation of the bromine molecules and the formation of 1D bromine atomic chains at pressures above 24 GPa. Our study suggests that the unique nanoconfinement has a considerable effect on the high-pressure behavior of bromine, and the confined bromine species concomitantly enhance the structural stability of the host AFI single crystals.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2016
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 2
    In: Journal of Applied Physics, AIP Publishing, Vol. 111, No. 11 ( 2012-06-01)
    Abstract: The structural stability of AlPO4-5 zeolite (AFI) has been studied as a function of pressure up to 34.4 GPa in a diamond anvil cell by using synchrotron x-ray diffraction. It is found that the AFI structural stability can be enhanced significantly when a mixture of silicone oil and liquid nitrogen is used as pressure transmission medium (PTM). In this case, the crystalline-to-amorphous transition pressure for AFI increased to be 15.9 GPa, much higher than that of 8.5 GPa observed in the experiment by using silicone oil as PTM. We found that the average distance of the interplanar crystal spacing along to most planes was expanded obviously when liquid nitrogen is used as one component in the PTM. The presence of liquid nitrogen in the PTM also affects the structural evolution of the AFI channel under pressure. The results demonstrated that nitrogen molecules can be inserted into the channels of porous zeolite AFI single crystals, exerting a supporting effect against the structure collapse of AFI and thus improving their structural stability.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 3
    In: Applied Physics Letters, AIP Publishing, Vol. 117, No. 6 ( 2020-08-10)
    Abstract: Current-induced spin-torques in two-dimensional (2D) heterostructures have attracted extensive attention due to their importance in understanding the underlying fundamental physics and developing low-power dissipation nanoelectronics. Here, the Permalloy/black phosphorus (BP) bilayer devices are fabricated, and spin-torque ferromagnetic resonance (ST-FMR) measurements are utilized to investigate the spin-torque effect in the heterostructure. An obvious out-of-plane antidamping torque is observed, which could be associated with the broken mirror symmetry of BP. These results show the possibility of manipulating magnetization by semiconductor field-effect devices based on 2D materials and provide a clear avenue for engineering spintronic devices based on 2D materials.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2016
    In:  Journal of Applied Physics Vol. 119, No. 9 ( 2016-03-07)
    In: Journal of Applied Physics, AIP Publishing, Vol. 119, No. 9 ( 2016-03-07)
    Abstract: In this study, an optical biosensor based on a porous silicon composite structure was fabricated using a simple method. This structure consists of a thin, porous silicon surface diffraction grating and a one-dimensional porous silicon photonic crystal. An angle-resolved diffraction efficiency spectrum was obtained by measuring the diffraction efficiency at a range of incident angles. The angle-resolved diffraction efficiency of the 2nd and 3rd orders was studied experimentally and theoretically. The device was sensitive to the change of refractive index in the presence of a biomolecule indicated by the shift of the diffraction efficiency spectrum. The sensitivity of this sensor was investigated through use of an 8 base pair antifreeze protein DNA hybridization. The shifts of the angle-resolved diffraction efficiency spectrum showed a relationship with the change of the refractive index, and the detection limit of the biosensor reached 41.7 nM. This optical device is highly sensitive, inexpensive, and simple to fabricate. Using shifts in diffraction efficiency spectrum to detect biological molecules has not yet been explored, so this study establishes a foundation for future work.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2016
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 5
    Online Resource
    Online Resource
    AIP Publishing ; 2017
    In:  Journal of Renewable and Sustainable Energy Vol. 9, No. 6 ( 2017-11-01)
    In: Journal of Renewable and Sustainable Energy, AIP Publishing, Vol. 9, No. 6 ( 2017-11-01)
    Abstract: Photovoltaic (PV) systems are playing a more and more important role as a renewable energy supplier. However, their large-scale applications is still limited by low conversion efficiency and high land-use requirement, especially for those areas where land and solar energy resources are more important for agriculture. In this paper, we suggest a dish-type high-concentration photovoltaic system, with which the competition between sunlight for crops' growth and PV application is solved by beam-splitting techniques. A purposely-designed beam filter acts as a solar spectrum splitter, and the most effective bands of solar spectrum for plant growth are transmitted down to plants while the other parts are all directed to the solar cell receiver. The spectral and spatial distribution of radiant intensity is investigated by ray tracing method, and the quantitative evaluation of the beam splitting effect on crop growth and PV power generation is provided in detail. The results show that, on one hand, the proposed system is superior to other natural and artificial light sources at driving the photosynthetic process (thus promoting crop growth); on the other hand, it generates PV power with high efficiency. Furthermore, the design can be optimized for certain kinds of plants and PV generation, both or independently. This spectral splitting scheme opens a promising future for PV applications in cooperation with precision farming.
    Type of Medium: Online Resource
    ISSN: 1941-7012
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2017
    detail.hit.zdb_id: 2444311-6
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  • 6
    Online Resource
    Online Resource
    AIP Publishing ; 2023
    In:  Physics of Fluids Vol. 35, No. 1 ( 2023-01-01)
    In: Physics of Fluids, AIP Publishing, Vol. 35, No. 1 ( 2023-01-01)
    Abstract: The geometric structure variation of the nonwetting phase (NWP) in porous media plays a critical role in numerous energy-related processes. This work conducted a series of gas/liquid displacements in three rock cores using high resolution x-ray microcomputed tomography (micro-CT), including two sandstones and a Berea core with different pore architectures. The morphological and topological characteristics of NWP were investigated at the pore scale in a full cycle of primary drainage (PD), main imbibition (MI), and main drainage (MD). It is found that roof and distal snap-off occurred during drainage, resulting in nonwetting (NW) singlets and ganglia. These NW bubbles occupied 10%–20% NWP volume. Both throat snap-off and pore snap-off were observed in MI, which generally occur at a single-pore scale. The effect of viscous force is significant even at a capillary dominant displacement. The trapped NWP during PD can be partially or totally displaced in MI through further snap-off events or viscous remobilization. Due to the temporal and spatial scale diversion in pore scale events, the amplitude of pressure drop fluctuations among PD, MI, and MD is different. The significant difference in NWP characteristics between PD and MD is connectivity, thus leading to hysteresis.
    Type of Medium: Online Resource
    ISSN: 1070-6631 , 1089-7666
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 1472743-2
    detail.hit.zdb_id: 241528-8
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  • 7
    In: Applied Physics Letters, AIP Publishing, Vol. 106, No. 9 ( 2015-03-02)
    Abstract: In this letter, the impact of stress time of pulse program operation on the resistance uniformity and endurance of resistive random access memory (RRAM) is investigated. A width-adjusting pulse operation (WAPO) method which can accurately setup and measure switching time is proposed for improving the uniformity and endurance of RRAM. Different from the traditional single pulse operation (TSPO) method in which only one wide pulse is applied in each switching cycle, WAPO method utilizes a series of pulses with the width increased gradually until a set or reset switching process is completely finished and no excessive stress is produced. Our program/erase (P/E) method can exactly control the switching time and the final resistance and can significantly improve the uniformity, stability, and endurance of RRAM device. Improving resistance uniformity by WAPO compared with TSPO method is explained through the interdependence between resistance state and switching time. The endurance improvement by WAPO operation stems from the effective avoidance of the overstress-induced progressive-breakdown and even hard-breakdown to the conductive soft-breakdown path.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2015
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 8
    Online Resource
    Online Resource
    AIP Publishing ; 2010
    In:  Chinese Journal of Chemical Physics Vol. 23, No. 5 ( 2010-10-01), p. 521-526
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 23, No. 5 ( 2010-10-01), p. 521-526
    Abstract: The quasi-classical trajectory calculations O++DH(v = 0, j = 0)→OD++H reactions on the RODRIGO potential energy surface have been carried out to study the isotope effect on stereo-dynamics at the collision energies of 1.0, 1.5, 2.0, and 2.5 eV. The distributions of dihedral angle P(φr) and the distributions of P(θr) are discussed. Furthermore, the angular distributions of the product rotational vectors in the form of polar plot in θr and φr are calculated. The differential cross section shows interesting phenomenon that the reaction is dominated by the direct reaction mechanism. Reaction probability and reaction cross section are also calculated. The calculations indicate that the stereo-dynamics properties of the title reactions are sensitive to the collision energy.
    Type of Medium: Online Resource
    ISSN: 1674-0068 , 2327-2244
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2010
    detail.hit.zdb_id: 2381472-X
    SSG: 6,25
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  • 9
    Online Resource
    Online Resource
    AIP Publishing ; 2022
    In:  The Journal of Chemical Physics Vol. 156, No. 1 ( 2022-01-07)
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 156, No. 1 ( 2022-01-07)
    Abstract: Crystal structure prediction has been a subject of topical interest but remains a substantial challenge especially for complex structures as it deals with the global minimization of the extremely rugged high-dimensional potential energy surface. In this paper, a symmetry-orientated divide-and-conquer scheme was proposed to construct a symmetry tree graph, where the entire search space is decomposed into a finite number of symmetry dependent subspaces. An artificial intelligence-based symmetry selection strategy was subsequently devised to select the low-lying subspaces with high symmetries for global exploration and in-depth exploitation. Our approach can significantly simplify the problem of crystal structure prediction by avoiding exploration of the most complex P1 subspace on the entire search space and has the advantage of preserving the crystal symmetry during structure evolution, making it well suitable for predicting the complex crystal structures. The effectiveness of the method has been validated by successful prediction of the candidate structures of binary Lennard-Jones mixtures and the high-pressure phase of ice, containing more than 100 atoms in the simulation cell. The work therefore opens up an opportunity toward achieving the long-sought goal of crystal structure prediction of complex systems.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 10
    In: Physics of Fluids, AIP Publishing, Vol. 34, No. 3 ( 2022-03-01)
    Abstract: We investigate the evolution and interaction mechanism of different vortex structures for the jet in crossflow by a high precision numerical method. To verify the accuracy of the numerical method, the numerical and experimental results are compared. Numerical results show a reasonable agreement with the experimental data. The typical vortex structures can be clearly identified in the flow field, including shear layer vortices, horseshoe vortices, counter rotating vortices pairs, and wake vortices. Through the analysis of spatial distribution of different vortex structures, the formation and interaction mechanisms of different vortices are discussed in detail. The results show that the shear layer rolling up appears due to the strong rotation, inducing the formation of the shear layer vortices. The influences of velocity ratios on the vortex structures are further investigated. At low velocity ratios, the rotation is weak along the windward of the jet. With the increase in the velocity ratios, the stronger rotation is formed near the jet exit hole, inducing the instability of interface and formation of the shear layer vortices to occur earlier. In the far flow field, as the shear layer vortices gradually break up into the fine-scale vortices, both the rotation and shear tend to become weaker at different velocity ratios.
    Type of Medium: Online Resource
    ISSN: 1070-6631 , 1089-7666
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2022
    detail.hit.zdb_id: 1472743-2
    detail.hit.zdb_id: 241528-8
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